Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups
Yuriy Denisenko
1
,
V. V. Atuchin
3
,
A. A. Krylov
4
,
Maxim S. Molokeev
5, 6
,
N P Shestakov
4
,
O.V. Andreev
8
1
6
Krasnoyarsk 660041 Russia
|
Publication type: Journal Article
Publication date: 2018-12-01
scimago Q1
wos Q1
SJR: 1.121
CiteScore: 11.6
Impact factor: 6.0
ISSN: 1226086X, 1876794X
General Chemical Engineering
Abstract
Eu2(SO4)3 was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group С2/с. In the air environment, Eu2(SO4)3 is stable up to 670 °C. The sample of Eu2(SO4)3 was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of SO4 tetrahedra results in the appearance of the IR inactive ν1 mode around 1000 cm−1 and ν2 modes below 500 cm−1. The band intensities redistribution in the luminescent spectra of Eu3+ ions is analyzed in terms of the peculiarities of its local environment.
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42
Total citations:
42
Citations from 2024:
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(16%)
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Denisenko Y. et al. Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups // Journal of Industrial and Engineering Chemistry. 2018. Vol. 68. pp. 109-116.
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Denisenko Y., Aleksandrovsky A., Atuchin V. V., Krylov A. A., Molokeev M. S., Oreshonkov A. S., Shestakov N. P., Andreev O. Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups // Journal of Industrial and Engineering Chemistry. 2018. Vol. 68. pp. 109-116.
Cite this
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TY - JOUR
DO - 10.1016/j.jiec.2018.07.034
UR - https://linkinghub.elsevier.com/retrieve/pii/S1226086X18304180
TI - Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups
T2 - Journal of Industrial and Engineering Chemistry
AU - Denisenko, Yuriy
AU - Aleksandrovsky, Aleksandr
AU - Atuchin, V. V.
AU - Krylov, A. A.
AU - Molokeev, Maxim S.
AU - Oreshonkov, Aleksandr S.
AU - Shestakov, N P
AU - Andreev, O.V.
PY - 2018
DA - 2018/12/01
PB - Korean Society of Industrial Engineering Chemistry
SP - 109-116
VL - 68
SN - 1226-086X
SN - 1876-794X
ER -
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BibTex (up to 50 authors)
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@article{2018_Denisenko,
author = {Yuriy Denisenko and Aleksandr Aleksandrovsky and V. V. Atuchin and A. A. Krylov and Maxim S. Molokeev and Aleksandr S. Oreshonkov and N P Shestakov and O.V. Andreev},
title = {Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups},
journal = {Journal of Industrial and Engineering Chemistry},
year = {2018},
volume = {68},
publisher = {Korean Society of Industrial Engineering Chemistry},
month = {dec},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1226086X18304180},
pages = {109--116},
doi = {10.1016/j.jiec.2018.07.034}
}