Journal of Industrial and Engineering Chemistry, volume 71, pages 445-451

Fabrication and electrochemical characteristics of NCM-based all-solid lithium batteries using nano-grade garnet Al-LLZO powder

Da Hye Kim 1
Min Young Kim 1
Seung Hoon Yang 1
Hye-Min Ryu 1
Ha-Young Jung 1
Hee-Jung Ban 1
Sang-Jun Park 1
Jin Sub Lim 1
Ho-Sung Kim 1
Publication typeJournal Article
Publication date2019-03-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor6.1
ISSN1226086X
General Chemical Engineering
Abstract
Garnet-related Li6.25Al0.25La3Zr2O12 (Al-LLZO) powder was prepared by calcination the precursor synthesized a Couette–Taylor reactor. The powder comprised regular blocks (1–2 μm) and consisted of fine particles (average particle size: D50 = 600 nm, specific surface area: 2.42 m2 g−1) that adopted a highly crystalline nanoscale cubic structure (lattice parameter: a = 13.07769 A; crystallite size: 41.4 nm). A composite electrolyte (CE) sheet in which the Al-LLZO nanopowder was finely dispersed was prepared by casting a slurry comprising 70 wt% Al-LLZO, polyethylene oxide (PEO), and lithium salt (LiClO4). The total ionic conductivity of the CE sheet was 7.59 × 10−6 S cm−1 at 25 °C and 1.93 × 10−3 S cm−1 at 70 °C, compared with 3.03 × 10−4 S cm−1 at 25 °C for the Al-LLZO pellet. Cyclic voltammetry showed that the electrochemical potential of the CE sheet was superior to that of PEO sheet. For application of the CE in all-solid lithium batteries (ASLBs), a composite NCM-based cathode composed of Al-LLZO, PEO, Super-P, and VGCF was also prepared. The discharge capacity of the cell was ∼122 mAh g−1 at 0.1C & 70 °C in voltages of 3.0–4.1 V, and ∼80% of the initial capacity was maintained over 100 cycles with high rate characteristics.

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Kim D. H. et al. Fabrication and electrochemical characteristics of NCM-based all-solid lithium batteries using nano-grade garnet Al-LLZO powder // Journal of Industrial and Engineering Chemistry. 2019. Vol. 71. pp. 445-451.
GOST all authors (up to 50) Copy
Kim D. H., Kim M. Y., Yang S. H., Ryu H., Jung H., Ban H., Park S., Lim J. S., Kim H. Fabrication and electrochemical characteristics of NCM-based all-solid lithium batteries using nano-grade garnet Al-LLZO powder // Journal of Industrial and Engineering Chemistry. 2019. Vol. 71. pp. 445-451.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jiec.2018.12.001
UR - https://doi.org/10.1016/j.jiec.2018.12.001
TI - Fabrication and electrochemical characteristics of NCM-based all-solid lithium batteries using nano-grade garnet Al-LLZO powder
T2 - Journal of Industrial and Engineering Chemistry
AU - Kim, Da Hye
AU - Kim, Min Young
AU - Yang, Seung Hoon
AU - Ryu, Hye-Min
AU - Jung, Ha-Young
AU - Ban, Hee-Jung
AU - Park, Sang-Jun
AU - Lim, Jin Sub
AU - Kim, Ho-Sung
PY - 2019
DA - 2019/03/01 00:00:00
PB - Korean Society of Industrial Engineering Chemistry
SP - 445-451
VL - 71
SN - 1226-086X
ER -
BibTex
Cite this
BibTex Copy
@article{2019_Kim,
author = {Da Hye Kim and Min Young Kim and Seung Hoon Yang and Hye-Min Ryu and Ha-Young Jung and Hee-Jung Ban and Sang-Jun Park and Jin Sub Lim and Ho-Sung Kim},
title = {Fabrication and electrochemical characteristics of NCM-based all-solid lithium batteries using nano-grade garnet Al-LLZO powder},
journal = {Journal of Industrial and Engineering Chemistry},
year = {2019},
volume = {71},
publisher = {Korean Society of Industrial Engineering Chemistry},
month = {mar},
url = {https://doi.org/10.1016/j.jiec.2018.12.001},
pages = {445--451},
doi = {10.1016/j.jiec.2018.12.001}
}
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