Journal of Luminescence, volume 144, pages 34-40

Determination of atropine using Mn-doped ZnS quantum dots as novel luminescent sensitizers

Seyed Naser Azizi ¹

Mohammad Javad Chaichi ¹

Parmis Shakeri ¹

Ahmad Reza Bekhradnia ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Analytical Division, Faculty of Chemistry, University of Mazandaran, Babolsar 4741695447, Iran. |

Pharmaceutical Sciences Research Center Department of Medicinal Chemistry Mazandaran University of Medical Sciences, Sari Iran |

Publication type: Journal Article

Publication date: 2013-12-01

Elsevier

Journal: Journal of Luminescence

Quartile SCImago

Quartile WOS

Impact factor: 3.6

ISSN: 00222313

DOI: 10.1016/j.jlumin.2013.05.054

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General Chemistry

Biochemistry

Biophysics

Atomic and Molecular Physics, and Optics

Condensed Matter Physics

Abstract

A novel chemiluminescence (CL) method using water-soluble Mn-doped ZnS quantum dots (QDs) as sensitizers is proposed for the chemiluminometric determination of atropine in pharmaceutical formulation. Water-soluble Mn-doped ZnS QDs were synthesized by using l -cysteine as stabilizer in aqueous solutions. The nanoparticles were structurally and optically characterized by X-ray powder diffraction (XRD), dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), UV–vis absorption spectroscopy and photoluminescence (PL) emission spectroscopy. It was found that ZnS quantum dots acted as enhancers of the weak CL emission produced upon oxidation of sulfite by Ce(IV) in acidic medium. Trace amounts of atropine improved the sensitize effect of ZnS quantum dots yielding a significant chemiluminescence enhancement of the Ce(IV)–SO 3 2− –ZnS QD system. Therefore, a new CL analysis system was developed for the determination of atropine. Under the optimum conditions, there is a good linear relationship between the relative chemiluminescence intensity and the concentration of atropine in the range of 1×10 −9 –1×10 −6 M of atropine with a correlation coefficient ( R 2 ) of 0.9992. The limit of detection of this system was found to be 2.54×10 −10 M. This method is not only simple, sensitive and low cost, but also reliable for practical applications. • Mn-doped ZnS quantum dots could enhance the chemiluminescence (CL) of cerium(IV)–sodium sulfite system. • ZnS quantum dots were used as the nanocatalyst. • Trace amounts of atropine improved the sensitize effect of ZnS quantum dots. • This work is introduced as a new method for the determination of atropine commercial drugs. • Detection limit of atropine was obtained 2.54×10 −10 mol L −1 .

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Naser Azizi S. et al. Determination of atropine using Mn-doped ZnS quantum dots as novel luminescent sensitizers // Journal of Luminescence. 2013. Vol. 144. pp. 34-40.

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Naser Azizi S., Chaichi M. J., Shakeri P., Bekhradnia A. R. Determination of atropine using Mn-doped ZnS quantum dots as novel luminescent sensitizers // Journal of Luminescence. 2013. Vol. 144. pp. 34-40.

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RIS Copy

TY - JOUR

DO - 10.1016/j.jlumin.2013.05.054

UR - https://doi.org/10.1016/j.jlumin.2013.05.054

TI - Determination of atropine using Mn-doped ZnS quantum dots as novel luminescent sensitizers

T2 - Journal of Luminescence

AU - Naser Azizi, Seyed

AU - Chaichi, Mohammad Javad

AU - Shakeri, Parmis

AU - Bekhradnia, Ahmad Reza

PY - 2013

DA - 2013/12/01 00:00:00

PB - Elsevier

SP - 34-40

VL - 144

SN - 0022-2313

ER -

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BibTex Copy

@article{2013_Naser Azizi,

author = {Seyed Naser Azizi and Mohammad Javad Chaichi and Parmis Shakeri and Ahmad Reza Bekhradnia},

title = {Determination of atropine using Mn-doped ZnS quantum dots as novel luminescent sensitizers},

journal = {Journal of Luminescence},

year = {2013},

volume = {144},

publisher = {Elsevier},

month = {dec},

url = {https://doi.org/10.1016/j.jlumin.2013.05.054},

pages = {34--40},

doi = {10.1016/j.jlumin.2013.05.054}

}

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Publisher

Elsevier

Journal

Journal of Luminescence

Quartile SCImago

Quartile WOS

Impact factor

3.6

ISSN

00222313 (Print)