Journal of Luminescence, volume 170, pages 275-281

Influence of structural factors and the properties of the medium on the fluorescence of Zn(II) bis(dipyrrinate)s

Publication typeJournal Article
Publication date2016-02-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3.6
ISSN00222313
General Chemistry
Biochemistry
Biophysics
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Abstract
This paper presents the results of quantum-chemical and spectral studies on studying fluorescence of binuclear zinc(II)–bis(dipyrrinate)s [Zn2L2] in non-polar and polar environments and their binary mixtures. We studied the efficiency of the fluorescence quenching of fluorophores depending on of isomerism forming their bis(dipyrrine) ligands and an electron-donating ability of the solvent. Found that 3,3′-bis(dipyrrinato)zinc(II) demonstrates the highest sensitivity of the fluorescence to the presence of the electron-donor component compared with 2,3′- and 2,2′-analogs. The results obtained allow to offer helicates [Zn2L2] as new, highly sensitive and selective fluorescent sensors for the detection of N- and O-containing analytes.

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Ksenofontov A. A. et al. Influence of structural factors and the properties of the medium on the fluorescence of Zn(II) bis(dipyrrinate)s // Journal of Luminescence. 2016. Vol. 170. pp. 275-281.
GOST all authors (up to 50) Copy
Ksenofontov A. A., Guseva G. B., Antina E. V., Vyugin A. I. Influence of structural factors and the properties of the medium on the fluorescence of Zn(II) bis(dipyrrinate)s // Journal of Luminescence. 2016. Vol. 170. pp. 275-281.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jlumin.2015.10.064
UR - https://doi.org/10.1016%2Fj.jlumin.2015.10.064
TI - Influence of structural factors and the properties of the medium on the fluorescence of Zn(II) bis(dipyrrinate)s
T2 - Journal of Luminescence
AU - Vyugin, A I
AU - Ksenofontov, Alexander A
AU - Guseva, Galina B
AU - Antina, Elena V
PY - 2016
DA - 2016/02/01 00:00:00
PB - Elsevier
SP - 275-281
VL - 170
SN - 0022-2313
ER -
BibTex
Cite this
BibTex Copy
@article{2016_Ksenofontov,
author = {A I Vyugin and Alexander A Ksenofontov and Galina B Guseva and Elena V Antina},
title = {Influence of structural factors and the properties of the medium on the fluorescence of Zn(II) bis(dipyrrinate)s},
journal = {Journal of Luminescence},
year = {2016},
volume = {170},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016%2Fj.jlumin.2015.10.064},
pages = {275--281},
doi = {10.1016/j.jlumin.2015.10.064}
}
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