Journal of Luminescence, volume 177, pages 31-39
Effective electroluminescent materials for OLED applications based on lanthanide 1.3-diketonates bearing pyrazole moiety
Ilya V. Taydakov
1
,
A A Akkuzina
1
,
Roman Avetisov
1
,
Andrew V Khomyakov
1
,
Rasim R Saifutyarov
1
,
Publication type: Journal Article
Publication date: 2016-09-01
Journal:
Journal of Luminescence
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.6
ISSN: 00222313
General Chemistry
Biochemistry
Biophysics
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Abstract
A series of new pyrazole substituted 1.3-diketones bearing fluorinated alkyl groups were prepared and systematically explored as a ligands for the preparation of luminescent complexes with Eu(III) ion. First triplet levels energy values (T1) of above mentioned ligands were determined by low temperature (77K) phosphorescent spectra measurements of Gd(III) complexes. It was found that 4,4,5,5,6,6,6-heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)hexane-1,3-dione is a superior ligand for synthesis of highly luminescent Eu (III) complexes with 1.10-phenanthroline or similar Lewis bases as auxiliary ligands. The complexes are sufficiently thermal stable, transparent, volatile in high vacuum and soluble in common solvents which make possible to produce OLEDs by dry and wet technology. OLED structures fabricated on the base of the above Eu(III) complexes demonstrated the higher energy efficacy comparing to the standard Eu(TTA)3(Phen) phosphor.
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Citations by publishers
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1 publication, 1.52%
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- Statistics recalculated weekly.
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Taydakov I. V. et al. Effective electroluminescent materials for OLED applications based on lanthanide 1.3-diketonates bearing pyrazole moiety // Journal of Luminescence. 2016. Vol. 177. pp. 31-39.
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Taydakov I. V., Akkuzina A. A., Avetisov R., Khomyakov A. V., Saifutyarov R. R., Avetissov I. Effective electroluminescent materials for OLED applications based on lanthanide 1.3-diketonates bearing pyrazole moiety // Journal of Luminescence. 2016. Vol. 177. pp. 31-39.
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TY - JOUR
DO - 10.1016/j.jlumin.2016.04.017
UR - https://doi.org/10.1016/j.jlumin.2016.04.017
TI - Effective electroluminescent materials for OLED applications based on lanthanide 1.3-diketonates bearing pyrazole moiety
T2 - Journal of Luminescence
AU - Taydakov, Ilya V.
AU - Akkuzina, A A
AU - Avetisov, Roman
AU - Khomyakov, Andrew V
AU - Saifutyarov, Rasim R
AU - Avetissov, Igor
PY - 2016
DA - 2016/09/01 00:00:00
PB - Elsevier
SP - 31-39
VL - 177
SN - 0022-2313
ER -
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@article{2016_Taydakov,
author = {Ilya V. Taydakov and A A Akkuzina and Roman Avetisov and Andrew V Khomyakov and Rasim R Saifutyarov and Igor Avetissov},
title = {Effective electroluminescent materials for OLED applications based on lanthanide 1.3-diketonates bearing pyrazole moiety},
journal = {Journal of Luminescence},
year = {2016},
volume = {177},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.jlumin.2016.04.017},
pages = {31--39},
doi = {10.1016/j.jlumin.2016.04.017}
}
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