Journal of Magnetic Resonance, volume 244, pages 64-67
Remote sensing of sample temperatures in nuclear magnetic resonance using photoluminescence of semiconductor quantum dots
1
Laboratory of Chemical Physics, National Institute of Diabetes and Digestive and Kidney Diseases, National Institutes of Health, Bethesda, MD 20892-0520, United States
|
Publication type: Journal Article
Publication date: 2014-07-01
Journal:
Journal of Magnetic Resonance
Quartile SCImago
Q1
Quartile WOS
Q3
Impact factor: 2.2
ISSN: 10907807
Biochemistry
Biophysics
Condensed Matter Physics
Nuclear and High Energy Physics
Abstract
Knowledge of sample temperatures during nuclear magnetic resonance (NMR) measurements is important for acquisition of optimal NMR data and proper interpretation of the data. Sample temperatures can be difficult to measure accurately for a variety of reasons, especially because it is generally not possible to make direct contact to the NMR sample during the measurements. Here I show that sample temperatures during magic-angle spinning (MAS) NMR measurements can be determined from temperature-dependent photoluminescence signals of semiconductor quantum dots that are deposited in a thin film on the outer surface of the MAS rotor, using a simple optical fiber-based setup to excite and collect photoluminescence. The accuracy and precision of such temperature measurements can be better than ±5K over a temperature range that extends from approximately 50K (-223°C) to well above 310K (37°C). Importantly, quantum dot photoluminescence can be monitored continuously while NMR measurements are in progress. While this technique is likely to be particularly valuable in low-temperature MAS NMR experiments, including experiments involving dynamic nuclear polarization, it may also be useful in high-temperature MAS NMR and other forms of magnetic resonance.
Top-30
Citations by journals
|
1
2
|
|
|
Annual Reports on NMR Spectroscopy
2 publications, 25%
|
|
|
Methods and Applications in Fluorescence
1 publication, 12.5%
|
|
|
TrAC - Trends in Analytical Chemistry
1 publication, 12.5%
|
|
|
Journal of Magnetic Resonance
1 publication, 12.5%
|
|
|
Applied Optics
1 publication, 12.5%
|
|
|
Advanced Structured Materials
1 publication, 12.5%
|
|
|
Russian Chemical Reviews
1 publication, 12.5%
|
|
|
1
2
|
Citations by publishers
|
1
2
3
4
|
|
|
Elsevier
4 publications, 50%
|
|
|
IOP Publishing
1 publication, 12.5%
|
|
|
Optical Society of America
1 publication, 12.5%
|
|
|
Springer Nature
1 publication, 12.5%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 12.5%
|
|
|
1
2
3
4
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[1,1,1,0,1,2,0,0,0,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["12.5","12.5","12.5",0,"12.5","25",0,0,0,"25"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Annual Reports on NMR Spectroscopy","Methods and Applications in Fluorescence","TrAC - Trends in Analytical Chemistry","Journal of Magnetic Resonance","Applied Optics","Advanced Structured Materials","Russian Chemical Reviews"],"ids":[1666,9016,434,17454,7119,6520,23802],"codes":[0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bypZPcr6C4twKiQVCUCGc0GF4cH6aUWmpClD3hsH_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[2,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[25,12.5,12.5,12.5,12.5,12.5,12.5],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","IOP Publishing","Optical Society of America","Springer Nature","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,2075,375,8,9422],"codes":[0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/bypZPcr6C4twKiQVCUCGc0GF4cH6aUWmpClD3hsH_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[4,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[50,12.5,12.5,12.5,12.5],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,1,0,1,0,0,0,0,0],"percentage":["0","0","12.5","0","12.5","0","0","0","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[0,1,0,0,0,1,0,0,0,1],"percentage":["0","12.5","0","0","0","12.5","0","0","0","12.5"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,0,0,0,0,1,0,0,0,1],"percentage":["12.5","0","0","0","0","12.5","0","0","0","12.5"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,1,0,0,1,0,0,0,0],"percentage":["0","0","12.5","0","0","12.5","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,0,0,1,0,0,0,0,0],"percentage":["0","0","0","0","12.5","0","0","0","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[0,1,0,0,0,0,0,0,0,1],"percentage":["0","12.5","0","0","0","0","0","0","0","12.5"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,0,0,0,0,1,0,0,0,1],"percentage":["12.5","0","0","0","0","12.5","0","0","0","12.5"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Tycko R. Remote sensing of sample temperatures in nuclear magnetic resonance using photoluminescence of semiconductor quantum dots // Journal of Magnetic Resonance. 2014. Vol. 244. pp. 64-67.
GOST all authors (up to 50)
Copy
Tycko R. Remote sensing of sample temperatures in nuclear magnetic resonance using photoluminescence of semiconductor quantum dots // Journal of Magnetic Resonance. 2014. Vol. 244. pp. 64-67.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jmr.2014.04.021
UR - https://doi.org/10.1016/j.jmr.2014.04.021
TI - Remote sensing of sample temperatures in nuclear magnetic resonance using photoluminescence of semiconductor quantum dots
T2 - Journal of Magnetic Resonance
AU - Tycko, Robert
PY - 2014
DA - 2014/07/01 00:00:00
PB - Elsevier
SP - 64-67
VL - 244
SN - 1090-7807
ER -
Cite this
BibTex
Copy
@article{2014_Tycko,
author = {Robert Tycko},
title = {Remote sensing of sample temperatures in nuclear magnetic resonance using photoluminescence of semiconductor quantum dots},
journal = {Journal of Magnetic Resonance},
year = {2014},
volume = {244},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.jmr.2014.04.021},
pages = {64--67},
doi = {10.1016/j.jmr.2014.04.021}
}