The effect of trivalent iron on the properties of fluorochlorozirconate glass ceramics
Publication type: Journal Article
Publication date: 2018-03-01
scimago Q2
wos Q1
SJR: 0.716
CiteScore: 7.0
Impact factor: 3.5
ISSN: 00223093, 18734812
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Abstract
Heat treating fluorochlorozirconate (FCZ) glasses precipitates nanocrystals in the glass matrix, resulting in glass ceramics that have storage phosphor properties suitable for use as a medical imaging plate. As the temperature of heat treatment rises, the resulting FCZ glass ceramic becomes more turbid as the size of the orthorhombic phase BaCl2 nanocrystals grow. This cloudiness results in scattering of the stimulating laser light, negatively affecting spatial resolution in computed radiography applications. The effect of Fe3+ on the valence state of zirconium and overall glass quality was investigated. The addition of small amounts of FeCl3 (1–2% on a molecular weight basis) to a ZBLAN glass composition allows for the precipitation of orthorhombic phase BaCl2 crystals while maintaining transparency of the glass ceramic.
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JOHNSON J. C. et al. The effect of trivalent iron on the properties of fluorochlorozirconate glass ceramics // Journal of Non-Crystalline Solids. 2018. Vol. 484. pp. 8-13.
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JOHNSON J. C., Leonard R. L., Gray S. K., KING J. E., Lubinsky A. R., Johnson J. A. The effect of trivalent iron on the properties of fluorochlorozirconate glass ceramics // Journal of Non-Crystalline Solids. 2018. Vol. 484. pp. 8-13.
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TY - JOUR
DO - 10.1016/j.jnoncrysol.2018.01.015
UR - https://doi.org/10.1016/j.jnoncrysol.2018.01.015
TI - The effect of trivalent iron on the properties of fluorochlorozirconate glass ceramics
T2 - Journal of Non-Crystalline Solids
AU - JOHNSON, JACQUELINE C.
AU - Leonard, R L
AU - Gray, S. K.
AU - KING, J. E.
AU - Lubinsky, A. R.
AU - Johnson, J. A.
PY - 2018
DA - 2018/03/01
PB - Elsevier
SP - 8-13
VL - 484
SN - 0022-3093
SN - 1873-4812
ER -
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@article{2018_JOHNSON,
author = {JACQUELINE C. JOHNSON and R L Leonard and S. K. Gray and J. E. KING and A. R. Lubinsky and J. A. Johnson},
title = {The effect of trivalent iron on the properties of fluorochlorozirconate glass ceramics},
journal = {Journal of Non-Crystalline Solids},
year = {2018},
volume = {484},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.jnoncrysol.2018.01.015},
pages = {8--13},
doi = {10.1016/j.jnoncrysol.2018.01.015}
}