Journal of Non-Crystalline Solids, volume 527, pages 119708

Effect of Li2O–Al2O3–GeO2–P2O5 glass crystallization on stability versus molten lithium

Publication typeJournal Article
Publication date2020-01-01
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor3.5
ISSN00223093, 00223093
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Abstract
Glass and glass-ceramic NASICON-type electrolytes of Li1.5Al0.5Ge1.5(PO4)3 composition were obtained by melt quenching and glass crystallization, respectively. The stability of the solid electrolytes to molten metallic Li was studied by immersing the samples and holding them at 230 °C for 72 h. Li|glass|Li and Li|glass-ceramics|Li electrochemical cells were assembled and their resistance was measured by impedance spectroscopy at 200 °C for 9 days. It was established that, unlike the glass, the glass-ceramics did not change in its phase composition and molecular structure after the tests. It is shown that Li1.5Al0.5Ge1.5(PO4)3 glass-ceramics is chemically stable in contact with metallic Li.

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Svetlana P. et al. Effect of Li2O–Al2O3–GeO2–P2O5 glass crystallization on stability versus molten lithium // Journal of Non-Crystalline Solids. 2020. Vol. 527. p. 119708.
GOST all authors (up to 50) Copy
Svetlana P., Il’ina E. A., Druzhinin K. V., Farlenkov A. S. Effect of Li2O–Al2O3–GeO2–P2O5 glass crystallization on stability versus molten lithium // Journal of Non-Crystalline Solids. 2020. Vol. 527. p. 119708.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jnoncrysol.2019.119708
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022309319305794
TI - Effect of Li2O–Al2O3–GeO2–P2O5 glass crystallization on stability versus molten lithium
T2 - Journal of Non-Crystalline Solids
AU - Svetlana, Pershina
AU - Il’ina, E. A.
AU - Druzhinin, K. V.
AU - Farlenkov, A S
PY - 2020
DA - 2020/01/01 00:00:00
PB - Elsevier
SP - 119708
VL - 527
SN - 0022-3093
SN - 0022-3093
ER -
BibTex
Cite this
BibTex Copy
@article{2020_Svetlana,
author = {Pershina Svetlana and E. A. Il’ina and K. V. Druzhinin and A S Farlenkov},
title = {Effect of Li2O–Al2O3–GeO2–P2O5 glass crystallization on stability versus molten lithium},
journal = {Journal of Non-Crystalline Solids},
year = {2020},
volume = {527},
publisher = {Elsevier},
month = {jan},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022309319305794},
pages = {119708},
doi = {10.1016/j.jnoncrysol.2019.119708}
}
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