Journal of Organometallic Chemistry, volume 693, issue 12, pages 2200-2203

Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis

Publication typeJournal Article
Publication date2008-06-01
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor2.3
ISSN0022328X
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of sulfur chelated dormant ruthenium olefin metathesis catalysts is presented. The catalysts prepared were shown to possess the uncommon cis-dichloro arrangement and were mostly inactive at room temperature. By systematically modifying the size of the substituent groups at the chelating sulfur atom, catalyst activity at different temperatures was significantly affected; more bulky substituents fomented activity at lower temperatures. The catalysts were also shown to be stable in solution and retained their catalytic activity even after being exposed to air for two weeks.

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GOST |
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GOST Copy
Kost T. et al. Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis // Journal of Organometallic Chemistry. 2008. Vol. 693. No. 12. pp. 2200-2203.
GOST all authors (up to 50) Copy
Kost T., Sigalov M., Goldberg I., Ben-Asuly A., Lemcoff N. G. Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis // Journal of Organometallic Chemistry. 2008. Vol. 693. No. 12. pp. 2200-2203.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2008.03.028
UR - https://doi.org/10.1016/j.jorganchem.2008.03.028
TI - Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis
T2 - Journal of Organometallic Chemistry
AU - Kost, Tamar
AU - Sigalov, Mark
AU - Goldberg, Israel
AU - Ben-Asuly, Amos
AU - Lemcoff, N Gabriel
PY - 2008
DA - 2008/06/01 00:00:00
PB - Elsevier
SP - 2200-2203
IS - 12
VL - 693
SN - 0022-328X
ER -
BibTex |
Cite this
BibTex Copy
@article{2008_Kost,
author = {Tamar Kost and Mark Sigalov and Israel Goldberg and Amos Ben-Asuly and N Gabriel Lemcoff},
title = {Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis},
journal = {Journal of Organometallic Chemistry},
year = {2008},
volume = {693},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.jorganchem.2008.03.028},
number = {12},
pages = {2200--2203},
doi = {10.1016/j.jorganchem.2008.03.028}
}
MLA
Cite this
MLA Copy
Kost, Tamar, et al. “Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis.” Journal of Organometallic Chemistry, vol. 693, no. 12, Jun. 2008, pp. 2200-2203. https://doi.org/10.1016/j.jorganchem.2008.03.028.
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