Regio- and stereo-specific addition of organotellurium trihalides to ferrocenylacetylene: Molecular and crystal structure of (Z)-halovinyl organotellurium dihalides
Publication type: Journal Article
Publication date: 2010-05-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Organotellurium(IV) trihalides RTeX3 (X = Br, I) reacts readily with ferrocenylacetylene to give (Z)-products of electrophilic addition to C–C triple bond: (Z)-FcXC = CTeX2R (R = Ph, X = Br (1) or I (2); R = trans-8-ethoxy-4-cyclooctenyl, X = Br (3)). In case of PhTeX3 (X = Br or I) the room temperature reaction is spontaneous and the structure of the product does not depends on the polarity of the solvent used; this is in contrast to the reaction of aryl-acetylenes with RTeBr3 which were reported to afford (E)-bromovinyl aryltellurium dibromides in methanol and its (Z)-isomer in benzene. Molecular and crystal structures of new compounds and effect of bulky and electron-rich ferrocenyl substituent on the reactivity of acetylene moiety are discussed in this paper.
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Torubaev Y. V. et al. Regio- and stereo-specific addition of organotellurium trihalides to ferrocenylacetylene: Molecular and crystal structure of (Z)-halovinyl organotellurium dihalides // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 9. pp. 1300-1306.
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Torubaev Y. V., Mathur P., Pasynskii A. A. Regio- and stereo-specific addition of organotellurium trihalides to ferrocenylacetylene: Molecular and crystal structure of (Z)-halovinyl organotellurium dihalides // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 9. pp. 1300-1306.
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TY - JOUR
DO - 10.1016/j.jorganchem.2010.02.017
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X10001099
TI - Regio- and stereo-specific addition of organotellurium trihalides to ferrocenylacetylene: Molecular and crystal structure of (Z)-halovinyl organotellurium dihalides
T2 - Journal of Organometallic Chemistry
AU - Torubaev, Yu. V.
AU - Mathur, P.
AU - Pasynskii, A. A.
PY - 2010
DA - 2010/05/01
PB - Elsevier
SP - 1300-1306
IS - 9
VL - 695
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{2010_Torubaev,
author = {Yu. V. Torubaev and P. Mathur and A. A. Pasynskii},
title = {Regio- and stereo-specific addition of organotellurium trihalides to ferrocenylacetylene: Molecular and crystal structure of (Z)-halovinyl organotellurium dihalides},
journal = {Journal of Organometallic Chemistry},
year = {2010},
volume = {695},
publisher = {Elsevier},
month = {may},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X10001099},
number = {9},
pages = {1300--1306},
doi = {10.1016/j.jorganchem.2010.02.017}
}
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MLA
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Torubaev, Yu. V., et al. “Regio- and stereo-specific addition of organotellurium trihalides to ferrocenylacetylene: Molecular and crystal structure of (Z)-halovinyl organotellurium dihalides.” Journal of Organometallic Chemistry, vol. 695, no. 9, May. 2010, pp. 1300-1306. https://linkinghub.elsevier.com/retrieve/pii/S0022328X10001099.