The substitution of arene by alkenes in linear trinuclear palladium complex Pd3 (NO)2 (μ-CF3 CO2 ) 4 (η2-C6 H5 CH3 ) 2 . X-ray structure of Pd3 (NO)2 (μ-CF 3 CO2 )4 (η2-CH2 CHPh) 2
Publication type: Journal Article
Publication date: 2010-08-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract An interaction of Pd3(NO)2(μ-CF3CO2)4(η2-C6H5Me)2 (I) with alkenes has been studied. A replacement of η2-coordinated arene by various olefins has been found to result in complexes of different nuclearity, Pd3(NO)2(μ-CF3CO2)4(η2-L)2 (L = Me3CCH CH2 (III), CH2CHPh (IV)), Pd4(μ-NO)2(μ-CF3CO2)4(η2-CH2CHPh)4 (V). Complexes IV and V have been characterized by an X-ray diffraction analysis. Molecule IV is constituted of a linear trinuclear metal core bearing η2-coordinated molecules of styrene, terminal nitrosyl and bridging carboxylate groups, whereas, complex V has a tetrahedral core, with η2-coordinated styrene molecules and half-bridging nitrosyl and carboxylate groups. Complex V represents a new type of nitrosyl carboxylate tetrahedral palladium cluster.
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Podobedov R. E. et al. The substitution of arene by alkenes in linear trinuclear palladium complex Pd3(NO)2(μ-CF3CO2) 4(η2-C6H5CH3) 2. X-ray structure of Pd3(NO)2(μ-CF 3CO2)4(η2-CH2CHPh) 2 // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 18. pp. 2083-2088.
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Podobedov R. E., Stromnova T. A., Churakov A. V., Kuz'mina L. G., Efimenko I. A. The substitution of arene by alkenes in linear trinuclear palladium complex Pd3(NO)2(μ-CF3CO2) 4(η2-C6H5CH3) 2. X-ray structure of Pd3(NO)2(μ-CF 3CO2)4(η2-CH2CHPh) 2 // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 18. pp. 2083-2088.
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TY - JOUR
DO - 10.1016/j.jorganchem.2010.05.019
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X10002664
TI - The substitution of arene by alkenes in linear trinuclear palladium complex Pd3(NO)2(μ-CF3CO2) 4(η2-C6H5CH3) 2. X-ray structure of Pd3(NO)2(μ-CF 3CO2)4(η2-CH2CHPh) 2
T2 - Journal of Organometallic Chemistry
AU - Podobedov, Roman E
AU - Stromnova, Tatiana A
AU - Churakov, Andrei V.
AU - Kuz'mina, Lyudmila G.
AU - Efimenko, Inessa A
PY - 2010
DA - 2010/08/01
PB - Elsevier
SP - 2083-2088
IS - 18
VL - 695
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{2010_Podobedov,
author = {Roman E Podobedov and Tatiana A Stromnova and Andrei V. Churakov and Lyudmila G. Kuz'mina and Inessa A Efimenko},
title = {The substitution of arene by alkenes in linear trinuclear palladium complex Pd3(NO)2(μ-CF3CO2) 4(η2-C6H5CH3) 2. X-ray structure of Pd3(NO)2(μ-CF 3CO2)4(η2-CH2CHPh) 2},
journal = {Journal of Organometallic Chemistry},
year = {2010},
volume = {695},
publisher = {Elsevier},
month = {aug},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X10002664},
number = {18},
pages = {2083--2088},
doi = {10.1016/j.jorganchem.2010.05.019}
}
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Podobedov, Roman E., et al. “The substitution of arene by alkenes in linear trinuclear palladium complex Pd3(NO)2(μ-CF3CO2) 4(η2-C6H5CH3) 2. X-ray structure of Pd3(NO)2(μ-CF 3CO2)4(η2-CH2CHPh) 2.” Journal of Organometallic Chemistry, vol. 695, no. 18, Aug. 2010, pp. 2083-2088. https://linkinghub.elsevier.com/retrieve/pii/S0022328X10002664.
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