Synthesis and molecular structure of [((CO)3 RuBr 2 )2 (μ-SePh)2 Ru(CO)4 ] cluster with a Ru3 Se2 chain core
Publication type: Journal Article
Publication date: 2011-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Treatment of ruthenium carbonyl, [Ru3(CO)12] with phenylseleno tribromide PhSeBr3 afforded a new triruthenium cluster, [(CO)10Br4Ru3(μ-SePh)2] (1). Its molecular structure was determined by single crystal XRD method (P21/c; a = 10.514(3) A; b = 10.814(3) A; c = 19.063(5) A; β = 105.064(4)°; V = 2093.1(10) A3) and shown to have two lateral Ru(CO)3Br2 units attached via two PhSe bridges to a Ru(CO)4 center forming a chain-like Ru–Se–Ru–Se–Ru cluster core. This is in contrast with a recently reported reaction of PhTeBr3 with [Ru3(CO)12] which formed a monomeric complex of ruthenium-dicarbonyl-dibromo fragment coordinating two PhTeBr ligands, [(CO)2RuBr2(PhTeBr)2].
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Torubaev Y. V. et al. Synthesis and molecular structure of [((CO)3RuBr 2)2(μ-SePh)2Ru(CO)4] cluster with a Ru3Se2 chain core // Journal of Organometallic Chemistry. 2011. Vol. 696. No. 4. pp. 832-834.
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Torubaev Y. V., Mathur P., Pasynskii A. A. Synthesis and molecular structure of [((CO)3RuBr 2)2(μ-SePh)2Ru(CO)4] cluster with a Ru3Se2 chain core // Journal of Organometallic Chemistry. 2011. Vol. 696. No. 4. pp. 832-834.
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TY - JOUR
DO - 10.1016/j.jorganchem.2010.10.036
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X10006613
TI - Synthesis and molecular structure of [((CO)3RuBr 2)2(μ-SePh)2Ru(CO)4] cluster with a Ru3Se2 chain core
T2 - Journal of Organometallic Chemistry
AU - Torubaev, Yu. V.
AU - Mathur, P.
AU - Pasynskii, A. A.
PY - 2011
DA - 2011/02/01
PB - Elsevier
SP - 832-834
IS - 4
VL - 696
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2011_Torubaev,
author = {Yu. V. Torubaev and P. Mathur and A. A. Pasynskii},
title = {Synthesis and molecular structure of [((CO)3RuBr 2)2(μ-SePh)2Ru(CO)4] cluster with a Ru3Se2 chain core},
journal = {Journal of Organometallic Chemistry},
year = {2011},
volume = {696},
publisher = {Elsevier},
month = {feb},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X10006613},
number = {4},
pages = {832--834},
doi = {10.1016/j.jorganchem.2010.10.036}
}
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Torubaev, Yu. V., et al. “Synthesis and molecular structure of [((CO)3RuBr 2)2(μ-SePh)2Ru(CO)4] cluster with a Ru3Se2 chain core.” Journal of Organometallic Chemistry, vol. 696, no. 4, Feb. 2011, pp. 832-834. https://linkinghub.elsevier.com/retrieve/pii/S0022328X10006613.