Journal of Organometallic Chemistry, volume 696, issue 11-12, pages 2466-2470
Olefin metathesis catalyst bearing a chelating phosphine ligand
Publication type: Journal Article
Publication date: 2011-06-01
Journal:
Journal of Organometallic Chemistry
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor: 2.3
ISSN: 0022328X
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
An improved synthetic procedure for the complex (SPY-5-34)-dichloro-(κ 2 (C,P)-diphenyl-(2-benzylidene)-phosphine)-(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydro-imidazol-2-ylidene)-ruthenium ( 2 ) was elaborated and the title compound was tested as latent initiator in Ring Opening Metathesis Polymerization (ROMP) and as catalyst for Ring-Closing Metathesis (RCM) at elevated temperatures. While not particularly suited as latent initiator for ROMP, exhibiting a switching temperature of only 42 °C in the polymerization of a typical norbornene derivative, 2 shows an appealing performance in RCM of α,ω-dienes at higher temperatures. The title compound was tested as latent initiator in Ring Opening Metathesis Polymerization (ROMP) and as catalyst for Ring-Closing Metathesis (RCM) at elevated temperatures. ► Chelating carbene ligand with phosphine group. ► Thermally triggered olefin metathesis reactions. ► Solvent influence on olefin metathesis reactions.
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Citations by publishers
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17 publications, 44.74%
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1 publication, 2.63%
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1 publication, 2.63%
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- We do not take into account publications without a DOI.
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Lexer C. et al. Olefin metathesis catalyst bearing a chelating phosphine ligand // Journal of Organometallic Chemistry. 2011. Vol. 696. No. 11-12. pp. 2466-2470.
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Lexer C., Burtscher D., Perner B., Tzur E., Lemcoff N. G., Slugovc C. Olefin metathesis catalyst bearing a chelating phosphine ligand // Journal of Organometallic Chemistry. 2011. Vol. 696. No. 11-12. pp. 2466-2470.
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TY - JOUR
DO - 10.1016/j.jorganchem.2011.03.005
UR - https://doi.org/10.1016/j.jorganchem.2011.03.005
TI - Olefin metathesis catalyst bearing a chelating phosphine ligand
T2 - Journal of Organometallic Chemistry
AU - Lexer, Christina
AU - Burtscher, Daniel
AU - Perner, Bernhard
AU - Tzur, Eyal
AU - Lemcoff, N Gabriel
AU - Slugovc, Christian
PY - 2011
DA - 2011/06/01 00:00:00
PB - Elsevier
SP - 2466-2470
IS - 11-12
VL - 696
SN - 0022-328X
ER -
Cite this
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@article{2011_Lexer,
author = {Christina Lexer and Daniel Burtscher and Bernhard Perner and Eyal Tzur and N Gabriel Lemcoff and Christian Slugovc},
title = {Olefin metathesis catalyst bearing a chelating phosphine ligand},
journal = {Journal of Organometallic Chemistry},
year = {2011},
volume = {696},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.jorganchem.2011.03.005},
number = {11-12},
pages = {2466--2470},
doi = {10.1016/j.jorganchem.2011.03.005}
}
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MLA
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Lexer, Christina, et al. “Olefin metathesis catalyst bearing a chelating phosphine ligand.” Journal of Organometallic Chemistry, vol. 696, no. 11-12, Jun. 2011, pp. 2466-2470. https://doi.org/10.1016/j.jorganchem.2011.03.005.