Reaction of germanes and digermanes with triflic acid: The route to novel organooligogermanes
Andrey A Kapranov
1
,
Yuri F. Oprunenko
1
,
Judith A. Howard
3
,
B.N. Tarasevich
1
,
Sergey S. Karlov
1
,
Galina S. Zaitseva
1
Publication type: Journal Article
Publication date: 2012-03-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Novel germanium containing triflates were prepared from the reactions of trifluoromethanesulfonic acid with tetraphenylgermane ( 1 ) and digermanes (Ph 3 GeGeMe 3 ( 4 ), Ph 3 GeGePh 3 ( 5 )). The improved procedures for synthesis of known organogermanium compounds (Ph 4 Ge ( 1 ), Ph 3 GeCl ( 2 ), Ph 3 GeGeMe 3 ( 4 ), Ph 3 GeGePh 3 ( 5 )) were also presented. The crystal structure of Ph 3 GeOTf ( 6 ) and Ph 2 Ge(OTf)Ge(OTf)Ph 2 ( 7 ) was studied by X-ray analysis. In 7 each germanium atom is pentacoordinated due to intramolecular interaction with O atom of the neighboring triflate group.
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38
Total citations:
38
Citations from 2024:
5
(13%)
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GOST
Copy
Zaitsev K. V. et al. Reaction of germanes and digermanes with triflic acid: The route to novel organooligogermanes // Journal of Organometallic Chemistry. 2012. Vol. 700. pp. 207-213.
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Zaitsev K. V., Kapranov A. A., Oprunenko Y. F., Churakov A. V., Howard J. A., Tarasevich B., Karlov S. S., Zaitseva G. S. Reaction of germanes and digermanes with triflic acid: The route to novel organooligogermanes // Journal of Organometallic Chemistry. 2012. Vol. 700. pp. 207-213.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2011.11.021
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X11007376
TI - Reaction of germanes and digermanes with triflic acid: The route to novel organooligogermanes
T2 - Journal of Organometallic Chemistry
AU - Zaitsev, Kirill V.
AU - Kapranov, Andrey A
AU - Oprunenko, Yuri F.
AU - Churakov, Andrei V.
AU - Howard, Judith A.
AU - Tarasevich, B.N.
AU - Karlov, Sergey S.
AU - Zaitseva, Galina S.
PY - 2012
DA - 2012/03/01
PB - Elsevier
SP - 207-213
VL - 700
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Zaitsev,
author = {Kirill V. Zaitsev and Andrey A Kapranov and Yuri F. Oprunenko and Andrei V. Churakov and Judith A. Howard and B.N. Tarasevich and Sergey S. Karlov and Galina S. Zaitseva},
title = {Reaction of germanes and digermanes with triflic acid: The route to novel organooligogermanes},
journal = {Journal of Organometallic Chemistry},
year = {2012},
volume = {700},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X11007376},
pages = {207--213},
doi = {10.1016/j.jorganchem.2011.11.021}
}