Stabilized germylenes based on dialkanolamines: Synthesis, structure, chemical properties
Meng-Meng Huang
1
,
Marina M. Kireenko
1
,
Yuri F. Oprunenko
1
,
Judith A. Howard
3
,
Maxim V Zabalov
4
,
Elmira Kh. Lermontova
5, 6
,
Jörg Sundermeyer
7
,
Thomas Linder
7
,
Sergey S. Karlov
1
,
Galina S. Zaitseva
1
4
N.N. Semenov Chem. Phys. Inst., Russian Acad. Sci., Kosygin st. 4, 119991 Moscow, Russia
|
Publication type: Journal Article
Publication date: 2012-06-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of novel low valent germanium compounds RN(CHR 2 CR 1 R 3 O)(CHR 4 CHR 5 O)Ge 1 – 13 ( R = Me, Ph, Bn; R 1 , R 2 , R 3 , R 4 , R 5 = H, Me, Ph, (CH 2 ) 3 , (CH 2 ) 4 , CH 2 (C 6 H 4 )) was obtained via the reaction between Ge[N(SiMe 3 ) 2 ] 2 and various dialkanolamines. All new compounds were characterized by elemental analysis, 1 H and 13 C NMR spectroscopy and in several cases by X-ray diffraction analysis ( 1 , 3 , 8 , 10 ). The compounds 1 , 3 , 8 are dimeric in the solid state due to the formation of intermolecular Ge–O bonds, the complex 10 is monomeric, all compounds possess a transannular Ge–N bond. The reactivity of the germylenes synthesized was investigated in reactions of oxidative insertion (with halogenation reagents, MeI, disulfides), [1 + 4]-cycloaddition, oxidation and in reactions with water and acetic anhydride. Some reactions were investigated by DFT calculations.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
|
|
|
European Journal of Inorganic Chemistry
5 publications, 18.52%
|
|
|
Russian Chemical Bulletin
3 publications, 11.11%
|
|
|
Inorganica Chimica Acta
2 publications, 7.41%
|
|
|
Dalton Transactions
2 publications, 7.41%
|
|
|
Journal of Organometallic Chemistry
2 publications, 7.41%
|
|
|
Monatshefte fur Chemie
1 publication, 3.7%
|
|
|
Mendeleev Communications
1 publication, 3.7%
|
|
|
Organometallics
1 publication, 3.7%
|
|
|
Chemistry - A European Journal
1 publication, 3.7%
|
|
|
ChemistrySelect
1 publication, 3.7%
|
|
|
Inorganic Chemistry
1 publication, 3.7%
|
|
|
International Journal of Molecular Sciences
1 publication, 3.7%
|
|
|
1
2
3
4
5
|
Publishers
|
2
4
6
8
10
12
|
|
|
Wiley
11 publications, 40.74%
|
|
|
Elsevier
7 publications, 25.93%
|
|
|
Springer Nature
4 publications, 14.81%
|
|
|
Royal Society of Chemistry (RSC)
2 publications, 7.41%
|
|
|
American Chemical Society (ACS)
2 publications, 7.41%
|
|
|
MDPI
1 publication, 3.7%
|
|
|
2
4
6
8
10
12
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
27
Total citations:
27
Citations from 2024:
0
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Huang M. et al. Stabilized germylenes based on dialkanolamines: Synthesis, structure, chemical properties // Journal of Organometallic Chemistry. 2012. Vol. 706-707. pp. 66-83.
GOST all authors (up to 50)
Copy
Huang M., Kireenko M. M., Zaitsev K. V., Oprunenko Y. F., Churakov A. V., Howard J. A., Zabalov M. V., Lermontova E. K., Sundermeyer J., Linder T., Karlov S. S., Zaitseva G. S. Stabilized germylenes based on dialkanolamines: Synthesis, structure, chemical properties // Journal of Organometallic Chemistry. 2012. Vol. 706-707. pp. 66-83.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2012.01.018
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X12000551
TI - Stabilized germylenes based on dialkanolamines: Synthesis, structure, chemical properties
T2 - Journal of Organometallic Chemistry
AU - Huang, Meng-Meng
AU - Kireenko, Marina M.
AU - Zaitsev, Kirill V.
AU - Oprunenko, Yuri F.
AU - Churakov, Andrei V.
AU - Howard, Judith A.
AU - Zabalov, Maxim V
AU - Lermontova, Elmira Kh.
AU - Sundermeyer, Jörg
AU - Linder, Thomas
AU - Karlov, Sergey S.
AU - Zaitseva, Galina S.
PY - 2012
DA - 2012/06/01
PB - Elsevier
SP - 66-83
VL - 706-707
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Huang,
author = {Meng-Meng Huang and Marina M. Kireenko and Kirill V. Zaitsev and Yuri F. Oprunenko and Andrei V. Churakov and Judith A. Howard and Maxim V Zabalov and Elmira Kh. Lermontova and Jörg Sundermeyer and Thomas Linder and Sergey S. Karlov and Galina S. Zaitseva},
title = {Stabilized germylenes based on dialkanolamines: Synthesis, structure, chemical properties},
journal = {Journal of Organometallic Chemistry},
year = {2012},
volume = {706-707},
publisher = {Elsevier},
month = {jun},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X12000551},
pages = {66--83},
doi = {10.1016/j.jorganchem.2012.01.018}
}