Synthesis, characterization and the Suzuki–Miyaura coupling reactions of N-heterocyclic carbene–Pd(II)–pyridine (PEPPSI) complexes
1
Publication type: Journal Article
Publication date: 2015-01-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
N -heterocyclic carbenes (NHCs) are a significant and powerful class of ligands for transition metals. A new series of air and moisture-stable NHC–PdCl 2 -pyridine complexes, ( 2a – f ), have been described. With the development of a more efficient catalytic system for the cross-coupling of aryl halides in mind, the catalytic performance of the NHC–PdCl 2 -pyridine complexes for Suzuki cross-coupling under mild conditions in aqueous N , N -dimethylformamide (DMF) was investigated. Electron-rich and electron-poor aryl chlorides were facilely coupled with boronic acids by NHC–PdCl 2 -pyridine complexes.
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70
Total citations:
70
Citations from 2025:
2
(2.86%)
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Yaşar S. et al. Synthesis, characterization and the Suzuki–Miyaura coupling reactions of N-heterocyclic carbene–Pd(II)–pyridine (PEPPSI) complexes // Journal of Organometallic Chemistry. 2015. Vol. 776. pp. 107-112.
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Yaşar S., Sahin C., Arslan M., Özdemir İ. Synthesis, characterization and the Suzuki–Miyaura coupling reactions of N-heterocyclic carbene–Pd(II)–pyridine (PEPPSI) complexes // Journal of Organometallic Chemistry. 2015. Vol. 776. pp. 107-112.
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TY - JOUR
DO - 10.1016/j.jorganchem.2014.10.047
UR - https://doi.org/10.1016/j.jorganchem.2014.10.047
TI - Synthesis, characterization and the Suzuki–Miyaura coupling reactions of N-heterocyclic carbene–Pd(II)–pyridine (PEPPSI) complexes
T2 - Journal of Organometallic Chemistry
AU - Yaşar, Sedat
AU - Sahin, Caglar
AU - Arslan, Murat
AU - Özdemir, İlker
PY - 2015
DA - 2015/01/01
PB - Elsevier
SP - 107-112
VL - 776
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2015_Yaşar,
author = {Sedat Yaşar and Caglar Sahin and Murat Arslan and İlker Özdemir},
title = {Synthesis, characterization and the Suzuki–Miyaura coupling reactions of N-heterocyclic carbene–Pd(II)–pyridine (PEPPSI) complexes},
journal = {Journal of Organometallic Chemistry},
year = {2015},
volume = {776},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.jorganchem.2014.10.047},
pages = {107--112},
doi = {10.1016/j.jorganchem.2014.10.047}
}