Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc2 Te2 )Fe(CO)3 I2 [(CO)3 IFe(μ-TeFc)]2 , CpFe(CO)2 TeFc, CpFe(CO)2 TeX2 Fc (X = Br, I) and CpFe(CO)2 (μ-TeFc)Fe(CO)3 I2
Yu. V. Torubaev
1
,
A. A. Pasynskii
1
,
Alina V Pavlova
1
,
Mohd Tauqeer
2
,
R. H. Herber
3
,
Israel Nowik
3
,
Ivan V Skabitskii
1
,
Gleb L Denisov
1
,
Vitaly A Grinberg
4
,
P. Mathur
5
,
Suman Mukhopadhyay
5
,
Publication type: Journal Article
Publication date: 2015-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Depending on the ratio of the starting reagents, the interaction of [FcTeI] with Fe(CO)5 gave complex (Fc2Te2)Fe(CO)3I2 (1) bearing an Fc2Te2 ligand, or a dimeric complex [(CO)3IFe(μ-TeFc)]2 (2). An interaction of equimolar amounts of [CpFe(CO)2]2 and Fc2Te2 under the thermal conditions in toluene afforded CpFe(CO)2TeFc (3). Complex 3 can be easily halogenated at the Te center by elemental bromine and iodine to give monomeric CpFe(CO)2TeX2Fc (X = Br (4), I (5)). Complex 5 can be prepared alternatively via formal insertion of [FcTeI] into Fc–I bond of CpFe(CO)2I. Complex 3 readily substitutes one carbonyl in Fe(CO)4I2 to give the adduct CpFe(CO)2(μ-TeFc)Fe(CO)3I2 (6).
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Total citations:
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Citations from 2024:
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Torubaev Y. V. et al. Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc2Te2)Fe(CO)3I2 [(CO)3IFe(μ-TeFc)]2, CpFe(CO)2TeFc, CpFe(CO)2TeX2Fc (X = Br, I) and CpFe(CO)2(μ-TeFc)Fe(CO)3I2 // Journal of Organometallic Chemistry. 2015. Vol. 777. pp. 88-95.
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Torubaev Y. V., Pasynskii A. A., Pavlova A. V., Tauqeer M., Herber R. H., Nowik I., Skabitskii I. V., Denisov G. L., Grinberg V. A., Mathur P., Mukhopadhyay S., Kumar Lahiri G. Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc2Te2)Fe(CO)3I2 [(CO)3IFe(μ-TeFc)]2, CpFe(CO)2TeFc, CpFe(CO)2TeX2Fc (X = Br, I) and CpFe(CO)2(μ-TeFc)Fe(CO)3I2 // Journal of Organometallic Chemistry. 2015. Vol. 777. pp. 88-95.
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TY - JOUR
DO - 10.1016/j.jorganchem.2014.11.025
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X14005841
TI - Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc2Te2)Fe(CO)3I2 [(CO)3IFe(μ-TeFc)]2, CpFe(CO)2TeFc, CpFe(CO)2TeX2Fc (X = Br, I) and CpFe(CO)2(μ-TeFc)Fe(CO)3I2
T2 - Journal of Organometallic Chemistry
AU - Torubaev, Yu. V.
AU - Pasynskii, A. A.
AU - Pavlova, Alina V
AU - Tauqeer, Mohd
AU - Herber, R. H.
AU - Nowik, Israel
AU - Skabitskii, Ivan V
AU - Denisov, Gleb L
AU - Grinberg, Vitaly A
AU - Mathur, P.
AU - Mukhopadhyay, Suman
AU - Kumar Lahiri, Goutam
PY - 2015
DA - 2015/02/01
PB - Elsevier
SP - 88-95
VL - 777
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2015_Torubaev,
author = {Yu. V. Torubaev and A. A. Pasynskii and Alina V Pavlova and Mohd Tauqeer and R. H. Herber and Israel Nowik and Ivan V Skabitskii and Gleb L Denisov and Vitaly A Grinberg and P. Mathur and Suman Mukhopadhyay and Goutam Kumar Lahiri},
title = {Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc2Te2)Fe(CO)3I2 [(CO)3IFe(μ-TeFc)]2, CpFe(CO)2TeFc, CpFe(CO)2TeX2Fc (X = Br, I) and CpFe(CO)2(μ-TeFc)Fe(CO)3I2},
journal = {Journal of Organometallic Chemistry},
year = {2015},
volume = {777},
publisher = {Elsevier},
month = {feb},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X14005841},
pages = {88--95},
doi = {10.1016/j.jorganchem.2014.11.025}
}