Triarylantimony(V) catecholates – Derivatives of 4,5-difluoro-3,6-di-tert-butyl-o-benzoquinone
Publication type: Journal Article
Publication date: 2016-12-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
New triarylantimony(V) 4,5-difluoro-3,6-di-tert-butylcatecholates of (4,5-F2-3,6-Cat)SbAr3 type, where Ar is p-fluorophenyl (1), p-chlorophenyl (2), phenyl (3), have been synthesized and characterized in details. The electrochemical properties of complexes 1–3 were investigated by means of cyclic voltammetry in comparison with the redox properties of related triarylantimony(V) 4-chloro-3,6-di-tert-butylcatecholates (4-Cl-3,6-Cat)SbAr3 (complexes 4–6). The electrochemical oxidation of complexes proceeds as two successive one-electron steps leading to monocations of [(SQ)SbAr3]+ type and dications [(Q)SbAr3]2+. The presence of two fluorine substituents in redox-active ligand in 1–3 leads to the increase of the stability of monocationic derivatives. The molecular structures of (4,5-F2-3,6-Cat)SbPh3 (3) and related 4-chlorosubstituted catecholato (4-Cl-3,6-Cat)SbPh3 (6) in crystal were determined by single-crystal X-ray analysis. In crystal form, catecholates 3 and 6 form hexamolecular cycles (CatSbPh3)6 due to the intermolecular Hphenyl ⋯ Sb interactions.
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Total citations:
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Poddel'sky A. I. et al. Triarylantimony(V) catecholates – Derivatives of 4,5-difluoro-3,6-di-tert-butyl-o-benzoquinone // Journal of Organometallic Chemistry. 2016. Vol. 824. pp. 1-6.
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Poddel'sky A. I., Smolyaninov I. V., Fukin G. K., Berberova N. T., Cherkasov V. K., Abakumov G. A. Triarylantimony(V) catecholates – Derivatives of 4,5-difluoro-3,6-di-tert-butyl-o-benzoquinone // Journal of Organometallic Chemistry. 2016. Vol. 824. pp. 1-6.
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TY - JOUR
DO - 10.1016/j.jorganchem.2016.09.021
UR - https://doi.org/10.1016/j.jorganchem.2016.09.021
TI - Triarylantimony(V) catecholates – Derivatives of 4,5-difluoro-3,6-di-tert-butyl-o-benzoquinone
T2 - Journal of Organometallic Chemistry
AU - Poddel'sky, Andrey I.
AU - Smolyaninov, Ivan V.
AU - Fukin, Georgy K.
AU - Berberova, N. T.
AU - Cherkasov, Vladimir Kuzmich
AU - Abakumov, Gleb A.
PY - 2016
DA - 2016/12/01
PB - Elsevier
SP - 1-6
VL - 824
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{2016_Poddel'sky,
author = {Andrey I. Poddel'sky and Ivan V. Smolyaninov and Georgy K. Fukin and N. T. Berberova and Vladimir Kuzmich Cherkasov and Gleb A. Abakumov},
title = {Triarylantimony(V) catecholates – Derivatives of 4,5-difluoro-3,6-di-tert-butyl-o-benzoquinone},
journal = {Journal of Organometallic Chemistry},
year = {2016},
volume = {824},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.jorganchem.2016.09.021},
pages = {1--6},
doi = {10.1016/j.jorganchem.2016.09.021}
}
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