Donor-acceptor molecular oligogermanes: Novel properties and structural aspects
Kevin Lam
2
,
Zhaisan Zhanabil
3
,
Guldana Issabayeva
3
,
Yuri F. Oprunenko
1
,
Galina S. Zaitseva
1
,
Sergey S. Karlov
1
3
Publication type: Journal Article
Publication date: 2018-07-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The linear oligogermyl amide 2, Ph3GeGeMe2NMe2, was obtained by reacting Ph3GeLi with 1, Me2Ge(Cl)NMe2. The amide 2 was used for the synthesis of molecular oligogermanes 3, Ph3GeGeMe2Ge(C6F5)3, and 4, [Ph3GeGeMe2]2Ge(C6F5)2, containing electron donor (Me, Ph) and acceptor (C6F5) groups, by using a hydrogermolysis reaction in n-hexane. The molecular structures of 3 and 4 were studied by XRD. It was shown that in a crystal 3 forms wide channels, in which the solvated nonpolar n-hexane molecule is present. The NMR (1H, 13C and 19F), optical (UV/vis absorption, luminescence) and electrochemical (cyclic voltammetry) properties of both compounds were also studied. The impact of the substitution type by the electron withdrawing groups (at the terminal position, such as in 3, or within the compound, such as in 5), on the physical properties was also studied.
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Total citations:
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Zaitsev K. V. et al. Donor-acceptor molecular oligogermanes: Novel properties and structural aspects // Journal of Organometallic Chemistry. 2018. Vol. 867. pp. 228-237.
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Zaitsev K. V., Kharcheva A. V., Lam K., Zhanabil Z., Issabayeva G., Oprunenko Y. F., Churakov A. V., Zaitseva G. S., Karlov S. S. Donor-acceptor molecular oligogermanes: Novel properties and structural aspects // Journal of Organometallic Chemistry. 2018. Vol. 867. pp. 228-237.
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TY - JOUR
DO - 10.1016/j.jorganchem.2017.11.029
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X17306782
TI - Donor-acceptor molecular oligogermanes: Novel properties and structural aspects
T2 - Journal of Organometallic Chemistry
AU - Zaitsev, Kirill V.
AU - Kharcheva, Anastasia V
AU - Lam, Kevin
AU - Zhanabil, Zhaisan
AU - Issabayeva, Guldana
AU - Oprunenko, Yuri F.
AU - Churakov, Andrei V.
AU - Zaitseva, Galina S.
AU - Karlov, Sergey S.
PY - 2018
DA - 2018/07/01
PB - Elsevier
SP - 228-237
VL - 867
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{2018_Zaitsev,
author = {Kirill V. Zaitsev and Anastasia V Kharcheva and Kevin Lam and Zhaisan Zhanabil and Guldana Issabayeva and Yuri F. Oprunenko and Andrei V. Churakov and Galina S. Zaitseva and Sergey S. Karlov},
title = {Donor-acceptor molecular oligogermanes: Novel properties and structural aspects},
journal = {Journal of Organometallic Chemistry},
year = {2018},
volume = {867},
publisher = {Elsevier},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X17306782},
pages = {228--237},
doi = {10.1016/j.jorganchem.2017.11.029}
}