том 867 страницы 220-223

Novel preparation method for bis-(alkoxysilylmethyl)carboranes from bis-(bromomagnesiummethyl)carboranes

Тип публикацииJournal Article
Дата публикации2018-07-01
scimago Q3
wos Q2
БС2
SJR0.385
CiteScore4.1
Impact factor2.4
ISSN0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The reactions of bis-(bromomagnesiummethyl)carboranes with dimethyldimethoxysilane were studied. It has been shown that interaction of 1,2-bis-(bromomagnesium)-o-carborane with an excess of dimethyldimethoxysilane gives the mixture of 1,2-(methoxydimethylsilylmethyl)-o-carborane and exocyclic 1,2-(o-carboranyleno)-4,6-bis-(dimethylsilyl)-5-oxa-cycloheptane. In the case of 1,7-bis-(bromomagnesiummethyl)-m-carborane, only 1,7-bis-(methoxydimethyl-silylmethyl)-m-carborane is formed. The possibility of obtaining Grignard reagents from 1,2 (7)-(bromomethyl)-o(m)-carboranes has been established.
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Izmaylov B. A. et al. Novel preparation method for bis-(alkoxysilylmethyl)carboranes from bis-(bromomagnesiummethyl)carboranes // Journal of Organometallic Chemistry. 2018. Vol. 867. pp. 220-223.
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Izmaylov B. A., Bai Y., Vasnev V. A., Markova G. D. Novel preparation method for bis-(alkoxysilylmethyl)carboranes from bis-(bromomagnesiummethyl)carboranes // Journal of Organometallic Chemistry. 2018. Vol. 867. pp. 220-223.
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TY - JOUR
DO - 10.1016/j.jorganchem.2017.12.012
UR - https://doi.org/10.1016/j.jorganchem.2017.12.012
TI - Novel preparation method for bis-(alkoxysilylmethyl)carboranes from bis-(bromomagnesiummethyl)carboranes
T2 - Journal of Organometallic Chemistry
AU - Izmaylov, Boris A
AU - Bai, Yong-Ping
AU - Vasnev, Valerii A
AU - Markova, Galy D
PY - 2018
DA - 2018/07/01
PB - Elsevier
SP - 220-223
VL - 867
SN - 0022-328X
SN - 1872-8561
ER -
BibTex
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@article{2018_Izmaylov,
author = {Boris A Izmaylov and Yong-Ping Bai and Valerii A Vasnev and Galy D Markova},
title = {Novel preparation method for bis-(alkoxysilylmethyl)carboranes from bis-(bromomagnesiummethyl)carboranes},
journal = {Journal of Organometallic Chemistry},
year = {2018},
volume = {867},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.jorganchem.2017.12.012},
pages = {220--223},
doi = {10.1016/j.jorganchem.2017.12.012}
}