Electrophilicity of aliphatic nitrilium closo -decaborate clusters: Hyperconjugation provides an unexpected inverse reactivity order
Publication type: Journal Article
Publication date: 2018-09-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The nucleophilic addition of 2-pyridyl carbamidoxime to the C≡N group of the aliphatic nitrilium closo-decaborate clusters (PhCH2PPh3)[B10H9NCR] (R = Me, Et, and iPr) proceeds to give 2-iminium closo-decaborates (68–88% isolated yields). A systematic kinetic and theoretical study of the nucleophilic addition indicates that the reactivity of the nitrile ligand at the boron cluster unexpectedly increases in the order of R: Me
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Mikherdov A. et al. Electrophilicity of aliphatic nitrilium closo -decaborate clusters: Hyperconjugation provides an unexpected inverse reactivity order // Journal of Organometallic Chemistry. 2018. Vol. 870. pp. 97-103.
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Burianova V. K., Mikherdov A., Venter G. J. S., Novikov A. S., Mokolokolo P. P., Boyarskiy V. P., Zhdanov A. P., Zhizhin K. Y., Kuznetsov N. T., Suslonov V. V., Roodt A. Electrophilicity of aliphatic nitrilium closo -decaborate clusters: Hyperconjugation provides an unexpected inverse reactivity order // Journal of Organometallic Chemistry. 2018. Vol. 870. pp. 97-103.
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TY - JOUR
DO - 10.1016/j.jorganchem.2018.06.017
UR - https://doi.org/10.1016/j.jorganchem.2018.06.017
TI - Electrophilicity of aliphatic nitrilium closo -decaborate clusters: Hyperconjugation provides an unexpected inverse reactivity order
T2 - Journal of Organometallic Chemistry
AU - Burianova, Valeria K
AU - Mikherdov, Alexander
AU - Venter, Gertruida J. S.
AU - Novikov, Alexander S.
AU - Mokolokolo, Pennie Petrus
AU - Boyarskiy, Vadim P
AU - Zhdanov, Andrey P.
AU - Zhizhin, Konstantin Yu.
AU - Kuznetsov, Nikolay T.
AU - Suslonov, Vitalii V
AU - Roodt, Andreas
PY - 2018
DA - 2018/09/01
PB - Elsevier
SP - 97-103
VL - 870
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2018_Mikherdov,
author = {Valeria K Burianova and Alexander Mikherdov and Gertruida J. S. Venter and Alexander S. Novikov and Pennie Petrus Mokolokolo and Vadim P Boyarskiy and Andrey P. Zhdanov and Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov and Vitalii V Suslonov and Andreas Roodt},
title = {Electrophilicity of aliphatic nitrilium closo -decaborate clusters: Hyperconjugation provides an unexpected inverse reactivity order},
journal = {Journal of Organometallic Chemistry},
year = {2018},
volume = {870},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.jorganchem.2018.06.017},
pages = {97--103},
doi = {10.1016/j.jorganchem.2018.06.017}
}