Elsevier
Journal of Organometallic Chemistry
,  volume 896 ,  pages 77-82

Halogen bridged mixed-metal complexes based on a trimethylplatinum fragment

Publication type: Journal Article
Publication date: 2019-09-01
Elsevier
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract By the reaction of tetramer [Me3Pt(μ3-Cl)]4 with RhCl3 and [PPN]Cl (PPN = Ph3P = N=PPh3+) in a acetone-DCM mixture under the influence of ultrasound a heterometallic ionic complex [PPN][Me3Pt(μ-Cl)3Rh(μ-Cl)3PtMe3] (I) have been prepared. Tetranuclear complex [PPN]2 [(Me3Pt)2Ru2(μ-O)(μ-Cl)6Cl4]2- (II) have been obtained in a small yield starting from RuCl3 in similar conditions. Complex II has also been prepared purposefully in higher yield by the action of Me3Pt(Me2CO)3][PF6] on [PPN]4[Ru2OCl10]. Both complexes were characterized by elemental analysis, 1H, 13C, and 195Pt NMR spectroscopy, and their structures were determined by single crystal X-ray diffraction.
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Skabitsky I. V. et al. Halogen bridged mixed-metal complexes based on a trimethylplatinum fragment // Journal of Organometallic Chemistry. 2019. Vol. 896. pp. 77-82.
GOST all authors (up to 50) Copy
Skabitsky I. V., Romadina E., Sakharov S. G., Pasynsky A. A. Halogen bridged mixed-metal complexes based on a trimethylplatinum fragment // Journal of Organometallic Chemistry. 2019. Vol. 896. pp. 77-82.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2019.05.008
UR - https://doi.org/10.1016/j.jorganchem.2019.05.008
TI - Halogen bridged mixed-metal complexes based on a trimethylplatinum fragment
T2 - Journal of Organometallic Chemistry
AU - Skabitsky, I. V.
AU - Romadina, Elena
AU - Sakharov, S G
AU - Pasynsky, A A
PY - 2019
DA - 2019/09/01
PB - Elsevier
SP - 77-82
VL - 896
SN - 0022-328X
SN - 1872-8561
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Skabitsky,
author = {I. V. Skabitsky and Elena Romadina and S G Sakharov and A A Pasynsky},
title = {Halogen bridged mixed-metal complexes based on a trimethylplatinum fragment},
journal = {Journal of Organometallic Chemistry},
year = {2019},
volume = {896},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.jorganchem.2019.05.008},
pages = {77--82},
doi = {10.1016/j.jorganchem.2019.05.008}
}