Journal of Organometallic Chemistry, volume 918, pages 121276

Making the family portrait complete: Synthesis of Electron Withdrawing Group activated Hoveyda-Grubbs catalysts bearing sulfone and ketone functionalities

Michał Bieniek 1
Robert Bujok 2
Dieter Arlt 4
1
 
Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland
2
 
Institute of Organic Chemistry Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw (Poland).
4
 
Ligand Chemie GmbH Papenhauser Strausse 10, Lemgo D, 32657, Germany
Publication typeJournal Article
Publication date2020-07-01
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor2.3
ISSN0022328X
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Synthesis of five Electron Withdrawing Group (EWG) activated Hoveyda-Grubbs’ catalysts containing thioperfluoroalkyl, sulfone and ketone functions is reported. The catalytic activity of these catalysts was well correlated with the σp values of the Hammett constants for the respective EWGs. Importantly, one of new catalysts gave good results in synthesis of a macrocyclic precursor of anti-HCV agent BILN2061.

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Bieniek M. et al. Making the family portrait complete: Synthesis of Electron Withdrawing Group activated Hoveyda-Grubbs catalysts bearing sulfone and ketone functionalities // Journal of Organometallic Chemistry. 2020. Vol. 918. p. 121276.
GOST all authors (up to 50) Copy
Bieniek M., Bujok R., Milewski M., Arlt D., Kajetanowicz A., Grela K. Making the family portrait complete: Synthesis of Electron Withdrawing Group activated Hoveyda-Grubbs catalysts bearing sulfone and ketone functionalities // Journal of Organometallic Chemistry. 2020. Vol. 918. p. 121276.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2020.121276
UR - https://doi.org/10.1016/j.jorganchem.2020.121276
TI - Making the family portrait complete: Synthesis of Electron Withdrawing Group activated Hoveyda-Grubbs catalysts bearing sulfone and ketone functionalities
T2 - Journal of Organometallic Chemistry
AU - Bieniek, Michał
AU - Bujok, Robert
AU - Milewski, Mariusz
AU - Arlt, Dieter
AU - Kajetanowicz, Anna
AU - Grela, Karol
PY - 2020
DA - 2020/07/01 00:00:00
PB - Elsevier
SP - 121276
VL - 918
SN - 0022-328X
ER -
BibTex
Cite this
BibTex Copy
@article{2020_Bieniek,
author = {Michał Bieniek and Robert Bujok and Mariusz Milewski and Dieter Arlt and Anna Kajetanowicz and Karol Grela},
title = {Making the family portrait complete: Synthesis of Electron Withdrawing Group activated Hoveyda-Grubbs catalysts bearing sulfone and ketone functionalities},
journal = {Journal of Organometallic Chemistry},
year = {2020},
volume = {918},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.jorganchem.2020.121276},
pages = {121276},
doi = {10.1016/j.jorganchem.2020.121276}
}
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