Water-soluble stable polymer nanocomposites with AuNPs based on the functional poly(1-vinyl-1,2,4-triazole-co-N-vinylpyrrolidone)
Publication type: Journal Article
Publication date: 2020-09-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
New water-soluble polymer nanocomposites with gold nanoparticles (AuNPs) were synthesized using functional copolymer of 1-vinyl-1,2,4-triazole with N-vinylpyrrolidone (poly(VT-co-VP)) as a stabilizing matrix. The polymer AuNPs nanocomposites were studied by transmission electron microscopy, scanning electron microscopy, ultraviolet–visible spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction, atomic absorption and thermogravimetric analysis. The gold content in nanocomposites ranged from 4.4 to 25.7%wt (the gold content depends on the ratio of poly(VT-co-VP):Au (III)). The obtained polymer nanocomposites consist of isolated gold nanoparticles with a diameter of 1–12 nm having a predominately spherical shape, which are uniformly distributed throughout the bulk of the polymer matrix. Nanocomposites contain AuNPs of various sizes, which is determined by the ability of the polymer matrix to stabilize the different metal contents. The resulting AuNPs nanocomposites are promising materials for the design of novel hydrophilic antiseptics and antimicrobial components for medical purposes.
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Pozdnyakov A. S. et al. Water-soluble stable polymer nanocomposites with AuNPs based on the functional poly(1-vinyl-1,2,4-triazole-co-N-vinylpyrrolidone) // Journal of Organometallic Chemistry. 2020. Vol. 922. p. 121352.
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Pozdnyakov A. S., Ivanova A., Emel’yanov A. M., Bolgova Yu. I., Trofimova O., Prozorova G. F. Water-soluble stable polymer nanocomposites with AuNPs based on the functional poly(1-vinyl-1,2,4-triazole-co-N-vinylpyrrolidone) // Journal of Organometallic Chemistry. 2020. Vol. 922. p. 121352.
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TY - JOUR
DO - 10.1016/j.jorganchem.2020.121352
UR - https://doi.org/10.1016/j.jorganchem.2020.121352
TI - Water-soluble stable polymer nanocomposites with AuNPs based on the functional poly(1-vinyl-1,2,4-triazole-co-N-vinylpyrrolidone)
T2 - Journal of Organometallic Chemistry
AU - Pozdnyakov, Alexander S.
AU - Ivanova, Anastasia
AU - Emel’yanov, Artem M.
AU - Bolgova, Yu I
AU - Trofimova, O.M
AU - Prozorova, Galina F
PY - 2020
DA - 2020/09/01
PB - Elsevier
SP - 121352
VL - 922
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2020_Pozdnyakov,
author = {Alexander S. Pozdnyakov and Anastasia Ivanova and Artem M. Emel’yanov and Yu I Bolgova and O.M Trofimova and Galina F Prozorova},
title = {Water-soluble stable polymer nanocomposites with AuNPs based on the functional poly(1-vinyl-1,2,4-triazole-co-N-vinylpyrrolidone)},
journal = {Journal of Organometallic Chemistry},
year = {2020},
volume = {922},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.jorganchem.2020.121352},
pages = {121352},
doi = {10.1016/j.jorganchem.2020.121352}
}