Joule, volume 3, issue 6, pages 1510-1522
Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating
Publication type: Journal Article
Publication date: 2019-06-01
General Energy
Abstract
Summary Solid-state Li-metal batteries are promising to improve both safety and energy density compared to conventional Li-ion batteries. However, various high-performance and low-cost solid electrolytes are incompatible with Li, which is indispensable for enhancing energy density. Here, we utilize a chemically inert and mechanically robust boron nitride (BN) film as the interfacial protection to preclude the reduction of Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolyte by Li, which is validated by in situ transmission electron microscopy. When combined with ∼1–2 μm PEO polymer electrolyte at the Li/BN interface, Li/Li symmetric cells show a cycle life of over 500 h at 0.3 mA·cm−2. In contrast, the same configuration with bare LATP dies after 81 h. The LiFePO4/LATP/BN/PEO/Li solid-state batteries show high capacity retention of 96.6% after 500 cycles. This study offers a general strategy to protect solid electrolytes that are unstable against Li and opens possibilities for adopting them in solid-state Li-metal batteries.
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Qian C. et al. Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating // Joule. 2019. Vol. 3. No. 6. pp. 1510-1522.
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Qian C., Li A., Li N., Li S., Zangiabadi A., Li T. D., Huang W., Li A. C., Jin T., Song Q., Xu W., Ni N., Zhai H., Dontigny M., Zaghib K., Chuan X., Su D., Yan K., Yang Y. Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating // Joule. 2019. Vol. 3. No. 6. pp. 1510-1522.
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TY - JOUR
DO - 10.1016/j.joule.2019.03.022
UR - https://doi.org/10.1016/j.joule.2019.03.022
TI - Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating
T2 - Joule
AU - Qian, Cheng
AU - Li, Aijun
AU - Li, Na
AU - Li, Shuang
AU - Zangiabadi, Amirali
AU - Li, Tai De
AU - Huang, Wenlong
AU - Li, Alex Ceng
AU - Jin, Tianwei
AU - Song, Qingquan
AU - Xu, Weiheng
AU - Ni, Nan
AU - Zhai, Haowei
AU - Dontigny, Martin
AU - Zaghib, Karim
AU - Chuan, Xiuyun
AU - Su, Dong
AU - Yan, Kai
AU - Yang, Yuan
PY - 2019
DA - 2019/06/01 00:00:00
PB - Elsevier
SP - 1510-1522
IS - 6
VL - 3
SN - 2542-4351
SN - 2542-4351
ER -
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@article{2019_Qian,
author = {Cheng Qian and Aijun Li and Na Li and Shuang Li and Amirali Zangiabadi and Tai De Li and Wenlong Huang and Alex Ceng Li and Tianwei Jin and Qingquan Song and Weiheng Xu and Nan Ni and Haowei Zhai and Martin Dontigny and Karim Zaghib and Xiuyun Chuan and Dong Su and Kai Yan and Yuan Yang},
title = {Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating},
journal = {Joule},
year = {2019},
volume = {3},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.joule.2019.03.022},
number = {6},
pages = {1510--1522},
doi = {10.1016/j.joule.2019.03.022}
}
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Qian, Cheng, et al. “Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating.” Joule, vol. 3, no. 6, Jun. 2019, pp. 1510-1522. https://doi.org/10.1016/j.joule.2019.03.022.