Journal of Physics and Chemistry of Solids, volume 68, issue 2, pages 264-271
Synthesis of nanoparticles in microwave hydrolysis of Zr (IV) salt solutions—Ionic conductivity of PVdF-co-HFP-based polymer electrolyte by the inclusion of nanoparticles
Publication type: Journal Article
Publication date: 2007-02-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 4
ISSN: 00223697, 00223697
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Nanocrystalline ZrO 2 particles have been prepared by microwave hydrolysis of Zr(IV) salt solutions at 400 ∘ C for 6 h. The paper describes the PVdF - co - HFP - ZrO 2 -based NCPEMs prepared by a simple solvent casting technique. The incorporation of ZrO 2 nanoparticles in the PVdF-co-HFP matrix, improved the ionic conductivity due to the availability of a large amount of oxygen vacancies on ZrO 2 surface which may act as the active Lewis acidic site that interact with ClO 4 - ions. On the other hand, a high concentration of ZrO 2 [10 wt(%)] leads to depression in ionic conductivity due to the formation of more crystalline phase in the PVdF-co-HFP matrix. DSC, XRD, SEM and DC-polarization studies were carried out. This paper also explores and proposes a structure–conductivity correlation in the PVdF - co - HFP - LiClO 4 – ZrO 2 -based NCPEMs system. The proposed correlation is derived from the interpretation of DSC, XRD and AC-impedance measurements. The temperature dependence of the ionic conductivity of NCPEMs follows the Arrhenius behaviour. Finally, the LSV experiment has been carried out to investigate the electrochemical stability in the polymer electrolytes.
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Citations by publishers
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Elsevier
13 publications, 41.94%
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Springer Nature
5 publications, 16.13%
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Taylor & Francis
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 3.23%
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IOP Publishing
1 publication, 3.23%
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Wiley
1 publication, 3.23%
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1 publication, 3.23%
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Trans Tech Publications
1 publication, 3.23%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 3.23%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kalyana Sundaram N. T., Vasudevan T., Dai K. Synthesis of nanoparticles in microwave hydrolysis of Zr (IV) salt solutions—Ionic conductivity of PVdF-co-HFP-based polymer electrolyte by the inclusion of nanoparticles // Journal of Physics and Chemistry of Solids. 2007. Vol. 68. No. 2. pp. 264-271.
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Kalyana Sundaram N. T., Vasudevan T., Dai K. Synthesis of nanoparticles in microwave hydrolysis of Zr (IV) salt solutions—Ionic conductivity of PVdF-co-HFP-based polymer electrolyte by the inclusion of nanoparticles // Journal of Physics and Chemistry of Solids. 2007. Vol. 68. No. 2. pp. 264-271.
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TY - JOUR
DO - 10.1016/j.jpcs.2006.11.005
UR - https://doi.org/10.1016/j.jpcs.2006.11.005
TI - Synthesis of nanoparticles in microwave hydrolysis of Zr (IV) salt solutions—Ionic conductivity of PVdF-co-HFP-based polymer electrolyte by the inclusion of nanoparticles
T2 - Journal of Physics and Chemistry of Solids
AU - Kalyana Sundaram, N T
AU - Vasudevan, T.
AU - Dai, Kun
PY - 2007
DA - 2007/02/01 00:00:00
PB - Elsevier
SP - 264-271
IS - 2
VL - 68
SN - 0022-3697
SN - 0022-3697
ER -
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@article{2007_Kalyana Sundaram,
author = {N T Kalyana Sundaram and T. Vasudevan and Kun Dai},
title = {Synthesis of nanoparticles in microwave hydrolysis of Zr (IV) salt solutions—Ionic conductivity of PVdF-co-HFP-based polymer electrolyte by the inclusion of nanoparticles},
journal = {Journal of Physics and Chemistry of Solids},
year = {2007},
volume = {68},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.jpcs.2006.11.005},
number = {2},
pages = {264--271},
doi = {10.1016/j.jpcs.2006.11.005}
}
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MLA
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Kalyana Sundaram, N. T., et al. “Synthesis of nanoparticles in microwave hydrolysis of Zr (IV) salt solutions—Ionic conductivity of PVdF-co-HFP-based polymer electrolyte by the inclusion of nanoparticles.” Journal of Physics and Chemistry of Solids, vol. 68, no. 2, Feb. 2007, pp. 264-271. https://doi.org/10.1016/j.jpcs.2006.11.005.