Photochemical reaction of 2-chlorobiphenyl with N(III) (H2ONO+/HONO/NO2−) in acidic environment studied by using co-linear laser flash photolysis
Publication type: Journal Article
Publication date: 2013-09-01
scimago Q2
wos Q2
SJR: 0.694
CiteScore: 7.8
Impact factor: 4.7
ISSN: 10106030, 18732666
General Chemistry
General Chemical Engineering
General Physics and Astronomy
Abstract
Photo-induced transformation in the presence of N(III) is an important pathway for pollutants conversion in atmospheric condensed phase. In this study, the photochemical reaction between 2-chlorobiphenyl and N(III) was investigated in acidic environment by using co-linear laser flash photolysis technique. The photo-induced conversion of 2-PCB is initiated from its rapid oxidation by OH, a primary product from the photolysis of N(III). The second-order rate constant for the reaction between 2-PCB and OH was determined to be (8.9 ± 1.2) × 10 9 M −1 s −1 . HONO and NO 2 − were found to be more important than H 2 ONO + with respect to the photochemical transformation of pollutants in atmospheric hydrometeors. The complicated photochemical conversion pathways and their significance in the atmosphere were discussed as well in this paper.
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13
Total citations:
13
Citations from 2024:
1
(8.33%)
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Huang L. et al. Photochemical reaction of 2-chlorobiphenyl with N(III) (H2ONO+/HONO/NO2−) in acidic environment studied by using co-linear laser flash photolysis // Journal of Photochemistry and Photobiology A: Chemistry. 2013. Vol. 268. pp. 44-49.
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Huang L., Dong W., Hou H. Photochemical reaction of 2-chlorobiphenyl with N(III) (H2ONO+/HONO/NO2−) in acidic environment studied by using co-linear laser flash photolysis // Journal of Photochemistry and Photobiology A: Chemistry. 2013. Vol. 268. pp. 44-49.
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TY - JOUR
DO - 10.1016/j.jphotochem.2013.06.016
UR - https://doi.org/10.1016/j.jphotochem.2013.06.016
TI - Photochemical reaction of 2-chlorobiphenyl with N(III) (H2ONO+/HONO/NO2−) in acidic environment studied by using co-linear laser flash photolysis
T2 - Journal of Photochemistry and Photobiology A: Chemistry
AU - Huang, Li
AU - Dong, Wenbo
AU - Hou, Huiqi
PY - 2013
DA - 2013/09/01
PB - Elsevier
SP - 44-49
VL - 268
SN - 1010-6030
SN - 1873-2666
ER -
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@article{2013_Huang,
author = {Li Huang and Wenbo Dong and Huiqi Hou},
title = {Photochemical reaction of 2-chlorobiphenyl with N(III) (H2ONO+/HONO/NO2−) in acidic environment studied by using co-linear laser flash photolysis},
journal = {Journal of Photochemistry and Photobiology A: Chemistry},
year = {2013},
volume = {268},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.jphotochem.2013.06.016},
pages = {44--49},
doi = {10.1016/j.jphotochem.2013.06.016}
}