Primary photochemical processes for PtCl62− complex in acetonitrile solutions
Svetlana G Matveeva
1
,
Ivan P. Pozdnyakov
1, 2
,
Vjacheslav P. Grivin
1
,
Victor F. Plyusnin
1, 2
,
Alexey Melnikov
4
,
Sergei V Chekalin
4
,
Evgeni M Glebov
1, 2
Publication type: Journal Article
Publication date: 2016-07-01
scimago Q2
wos Q2
SJR: 0.694
CiteScore: 7.8
Impact factor: 4.7
ISSN: 10106030, 18732666
General Chemistry
General Chemical Engineering
General Physics and Astronomy
Abstract
Photosolvation of hexachloroplatinate(IV) in acetonitrile with the formation of the PtIVCl5(CH3CN)− complex was studied in the time range from hundreds of femtoseconds to seconds. The primary Pt(III) intermediate was recorded and interpreted as the primary Adamson radical pair [PtIIICl52‐(C4v)⋯Cl ], which then accepts an electron from a solvent molecule. Two successive Pt(III) intermediates recorded in time range from microseconds to tens of milliseconds were interpreted as PtIIICl52−(C4V) and PtIIICl4− complexes. PtIIICl4− was proposed to be a chain carrier in the chain photosolvation process. Dependencies of quantum yield of photosolvation on the initial complex concentration and excited light intensity were fitted in the framework of the proposed chain mechanism. Rate constants of the reactions of intermediates were determined.
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Matveeva S. G. et al. Primary photochemical processes for PtCl62− complex in acetonitrile solutions // Journal of Photochemistry and Photobiology A: Chemistry. 2016. Vol. 325. pp. 13-21.
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Matveeva S. G., Pozdnyakov I. P., Grivin V. P., Plyusnin V. F., Mereshchenko A. S., Melnikov A., Chekalin S. V., Glebov E. M. Primary photochemical processes for PtCl62− complex in acetonitrile solutions // Journal of Photochemistry and Photobiology A: Chemistry. 2016. Vol. 325. pp. 13-21.
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RIS
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TY - JOUR
DO - 10.1016/j.jphotochem.2016.03.027
UR - https://doi.org/10.1016/j.jphotochem.2016.03.027
TI - Primary photochemical processes for PtCl62− complex in acetonitrile solutions
T2 - Journal of Photochemistry and Photobiology A: Chemistry
AU - Matveeva, Svetlana G
AU - Pozdnyakov, Ivan P.
AU - Grivin, Vjacheslav P.
AU - Plyusnin, Victor F.
AU - Mereshchenko, A. S.
AU - Melnikov, Alexey
AU - Chekalin, Sergei V
AU - Glebov, Evgeni M
PY - 2016
DA - 2016/07/01
PB - Elsevier
SP - 13-21
VL - 325
SN - 1010-6030
SN - 1873-2666
ER -
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BibTex (up to 50 authors)
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@article{2016_Matveeva,
author = {Svetlana G Matveeva and Ivan P. Pozdnyakov and Vjacheslav P. Grivin and Victor F. Plyusnin and A. S. Mereshchenko and Alexey Melnikov and Sergei V Chekalin and Evgeni M Glebov},
title = {Primary photochemical processes for PtCl62− complex in acetonitrile solutions},
journal = {Journal of Photochemistry and Photobiology A: Chemistry},
year = {2016},
volume = {325},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.jphotochem.2016.03.027},
pages = {13--21},
doi = {10.1016/j.jphotochem.2016.03.027}
}
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