Journal of Photochemistry and Photobiology A: Chemistry, volume 354, pages 181-186

Effect of solvents on photocatalytic reduction of CO2 mediated by cobalt complex

Publication typeJournal Article
Publication date2018-03-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor4.3
ISSN10106030, 18732666
General Chemistry
General Chemical Engineering
General Physics and Astronomy
Abstract
Conversion of CO 2 into value-added chemicals by solar energy is one of the most promising pathways to partially address both energy crisis and global warming effect. The properties of reaction medium play a key role in determining the efficiency of CO 2 photoreduction and modulating the distribution of reaction products. Herein, we report the detailed investigation of solvent effects on the performance of photocatalytic CO 2 reduction by means of photo-/electro-chemical and spectroscopy techniques. The relationship between photochemical CO 2 performance and solvent properties (e.g., viscosity, solubility, and electrochemical behaviors) are systematically explored. The active intermediates for CO 2 photoreduction catalysis are examined by UV–vis absorption spectra. Moreover, a possible reaction pathway involving photoexcited charge transfers and intermediate species transformations in various solvents is proposed.

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GOST Copy
Lin J., Qin B., Zhao G. Effect of solvents on photocatalytic reduction of CO2 mediated by cobalt complex // Journal of Photochemistry and Photobiology A: Chemistry. 2018. Vol. 354. pp. 181-186.
GOST all authors (up to 50) Copy
Lin J., Qin B., Zhao G. Effect of solvents on photocatalytic reduction of CO2 mediated by cobalt complex // Journal of Photochemistry and Photobiology A: Chemistry. 2018. Vol. 354. pp. 181-186.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jphotochem.2017.09.019
UR - https://doi.org/10.1016/j.jphotochem.2017.09.019
TI - Effect of solvents on photocatalytic reduction of CO2 mediated by cobalt complex
T2 - Journal of Photochemistry and Photobiology A: Chemistry
AU - Lin, Jinliang
AU - Qin, Biao
AU - Zhao, Guanglian
PY - 2018
DA - 2018/03/01 00:00:00
PB - Elsevier
SP - 181-186
VL - 354
SN - 1010-6030
SN - 1873-2666
ER -
BibTex
Cite this
BibTex Copy
@article{2018_Lin,
author = {Jinliang Lin and Biao Qin and Guanglian Zhao},
title = {Effect of solvents on photocatalytic reduction of CO2 mediated by cobalt complex},
journal = {Journal of Photochemistry and Photobiology A: Chemistry},
year = {2018},
volume = {354},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.jphotochem.2017.09.019},
pages = {181--186},
doi = {10.1016/j.jphotochem.2017.09.019}
}
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