Plastic crystalline phases of crown ether:salt complexes and their utilization in lithium-metal batteries
Тип публикации: Journal Article
Дата публикации: 2007-12-01
scimago Q1
wos Q1
БС1
SJR: 1.784
CiteScore: 14.9
Impact factor: 7.9
ISSN: 03787753, 18732755
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Краткое описание
We have shown that crown ether complexes with the lithium salt, lithium bis-(trifluoromethanesulphonyl) imide (LiTFSI), are plastic crystals as evidenced by DSC and their mechanical properties. The conductivity of the complexes was measured and found to vary as a function of crown ether:salt molar ratio. Our study of the (18-Crown-6)–LiTFSI (1/1) solid complex showed that it has a high conductivity reaching ∼10 −4 S cm −1 at 50 °C and an electrochemical stability of over 4 V enabling its use in a lithium-metal battery. A lithium battery with 1:1 (18-Crown-6)–LiTFSI as electrolyte was assembled, tested, and found to exhibit reversible Li + transport.
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ГОСТ
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Abouimrane A. et al. Plastic crystalline phases of crown ether:salt complexes and their utilization in lithium-metal batteries // Journal of Power Sources. 2007. Vol. 174. No. 2. pp. 1193-1196.
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Abouimrane A., Alarco P., Abu-Lebdeh Y., Davidson I., Armand M. Plastic crystalline phases of crown ether:salt complexes and their utilization in lithium-metal batteries // Journal of Power Sources. 2007. Vol. 174. No. 2. pp. 1193-1196.
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TY - JOUR
DO - 10.1016/j.jpowsour.2007.06.044
UR - https://doi.org/10.1016/j.jpowsour.2007.06.044
TI - Plastic crystalline phases of crown ether:salt complexes and their utilization in lithium-metal batteries
T2 - Journal of Power Sources
AU - Abouimrane, Ali
AU - Alarco, Pierre-Jean
AU - Abu-Lebdeh, Yaser
AU - Davidson, Isobel
AU - Armand, Michel
PY - 2007
DA - 2007/12/01
PB - Elsevier
SP - 1193-1196
IS - 2
VL - 174
SN - 0378-7753
SN - 1873-2755
ER -
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@article{2007_Abouimrane,
author = {Ali Abouimrane and Pierre-Jean Alarco and Yaser Abu-Lebdeh and Isobel Davidson and Michel Armand},
title = {Plastic crystalline phases of crown ether:salt complexes and their utilization in lithium-metal batteries},
journal = {Journal of Power Sources},
year = {2007},
volume = {174},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.jpowsour.2007.06.044},
number = {2},
pages = {1193--1196},
doi = {10.1016/j.jpowsour.2007.06.044}
}
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MLA
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Abouimrane, Ali, et al. “Plastic crystalline phases of crown ether:salt complexes and their utilization in lithium-metal batteries.” Journal of Power Sources, vol. 174, no. 2, Dec. 2007, pp. 1193-1196. https://doi.org/10.1016/j.jpowsour.2007.06.044.