Mixed layered Ni–Mn–Co hydroxides: Crystal structure, electronic state of ions, and thermal decomposition
Тип публикации: Journal Article
Дата публикации: 2007-12-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.598
CiteScore: 12.2
Impact factor: 8.4
ISSN: 03787753, 18732755
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Краткое описание
It has been shown that varying conditions of co-precipitation processes, two types of mixed Ni–Mn–Co hydroxides: either brucite, or hydrotalcite-like (LDHs)—with different Ni/Mn/Co ratio can be prepared. According to XPS study, these hydroxides are mixed-valence materials: Ni ions present in 2+ oxidation state, whereas Mn and Co ions are in 3+/4+ and 2+/3+ state, respectively; their oxidation state increases with an increase of their content in hydroxides. For Ni-rich hydroxides, a strong effect of nickel segregation is observed indicating that chemistry of the surface and of the bulk is different. Mixed Ni–Mn–Co hydroxides decompose in two steps resulting in formation of NiO bunsenite and (Ni,Co,Mn)3O4 spinel.
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Kosova N. V., Devyatkina E. T., Kaichev V. Mixed layered Ni–Mn–Co hydroxides: Crystal structure, electronic state of ions, and thermal decomposition // Journal of Power Sources. 2007. Vol. 174. No. 2. pp. 735-740.
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Kosova N. V., Devyatkina E. T., Kaichev V. Mixed layered Ni–Mn–Co hydroxides: Crystal structure, electronic state of ions, and thermal decomposition // Journal of Power Sources. 2007. Vol. 174. No. 2. pp. 735-740.
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TY - JOUR
DO - 10.1016/j.jpowsour.2007.06.109
UR - https://doi.org/10.1016/j.jpowsour.2007.06.109
TI - Mixed layered Ni–Mn–Co hydroxides: Crystal structure, electronic state of ions, and thermal decomposition
T2 - Journal of Power Sources
AU - Kosova, Nina V.
AU - Devyatkina, E. T.
AU - Kaichev, Vasily
PY - 2007
DA - 2007/12/01
PB - Elsevier
SP - 735-740
IS - 2
VL - 174
SN - 0378-7753
SN - 1873-2755
ER -
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@article{2007_Kosova,
author = {Nina V. Kosova and E. T. Devyatkina and Vasily Kaichev},
title = {Mixed layered Ni–Mn–Co hydroxides: Crystal structure, electronic state of ions, and thermal decomposition},
journal = {Journal of Power Sources},
year = {2007},
volume = {174},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.jpowsour.2007.06.109},
number = {2},
pages = {735--740},
doi = {10.1016/j.jpowsour.2007.06.109}
}
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MLA
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Kosova, Nina V., et al. “Mixed layered Ni–Mn–Co hydroxides: Crystal structure, electronic state of ions, and thermal decomposition.” Journal of Power Sources, vol. 174, no. 2, Dec. 2007, pp. 735-740. https://doi.org/10.1016/j.jpowsour.2007.06.109.
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