Journal of Power Sources, volume 196, issue 6, pages 3342-3345

High lithium ionic conductivity in the garnet-type oxide Li7−X La3(Zr2−X, NbX)O12 (X=0–2)

Shingo Ohta ¹

Tetsuro KOBAYASHI ¹

Takahiko Asaoka ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Toyota Central R&D Labs. Inc., Battery & Cells Div., 41-1 Yokomichi, Nagakute, Aichi 480-1192, Japan |

Publication type: Journal Article

Publication date: 2011-03-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2010.11.089

Copy DOI

Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Lithium garnet-type oxides Li7−XLa3(Zr2−X, NbX)O12 (X = 0–2) were synthesized by a solid-state reaction, and their lithium ion conductivity was measured using an AC impedance method at temperatures ranging from 25 to 150 °C in air. The lithium ion conductivity increased with increasing Nb content, and reached a maximum of ∼0.8 mS cm−1 at 25 °C. By contrast, the activation energy reached a minimum of ∼30 kJ mol−1 at the same point with X = 0.25. The potential window was examined by cyclic voltammetry (CV), which showed lithium deposition and dissolution peaks around 0 V vs. Li+/Li, but showed no evidence of other reactions up to 9 V vs. Li+/Li.

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	5 10 15 20 25 30 35 40 45
Solid State Ionics	Solid State Ionics, 44, 8.04% Solid State Ionics 44 publications, 8.04%
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Journal of Power Sources	Journal of Power Sources, 33, 6.03% Journal of Power Sources 33 publications, 6.03%
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Chemistry of Materials	Chemistry of Materials, 17, 3.11% Chemistry of Materials 17 publications, 3.11%
ACS applied materials & interfaces	ACS applied materials & interfaces, 17, 3.11% ACS applied materials & interfaces 17 publications, 3.11%
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ACS Applied Energy Materials	ACS Applied Energy Materials, 14, 2.56% ACS Applied Energy Materials 14 publications, 2.56%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 12, 2.19% Journal of the Electrochemical Society 12 publications, 2.19%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 9, 1.65% Journal of Alloys and Compounds 9 publications, 1.65%
Electrochimica Acta	Electrochimica Acta, 9, 1.65% Electrochimica Acta 9 publications, 1.65%
Journal of the American Ceramic Society	Journal of the American Ceramic Society, 8, 1.46% Journal of the American Ceramic Society 8 publications, 1.46%
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Journal of the Ceramic Society of Japan	Journal of the Ceramic Society of Japan, 7, 1.28% Journal of the Ceramic Society of Japan 7 publications, 1.28%
Scientific Reports	Scientific Reports, 7, 1.28% Scientific Reports 7 publications, 1.28%
Chemical Engineering Journal	Chemical Engineering Journal, 7, 1.28% Chemical Engineering Journal 7 publications, 1.28%
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Advanced Materials	Advanced Materials, 6, 1.1% Advanced Materials 6 publications, 1.1%
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Journal of Physical Chemistry C	Journal of Physical Chemistry C, 6, 1.1% Journal of Physical Chemistry C 6 publications, 1.1%
ACS Energy Letters	ACS Energy Letters, 6, 1.1% ACS Energy Letters 6 publications, 1.1%
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Electrochemistry	Electrochemistry, 5, 0.91% Electrochemistry 5 publications, 0.91%
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Inorganic Chemistry	Inorganic Chemistry, 5, 0.91% Inorganic Chemistry 5 publications, 0.91%
Dalton Transactions	Dalton Transactions, 5, 0.91% Dalton Transactions 5 publications, 0.91%
Journal of the American Chemical Society	Journal of the American Chemical Society, 4, 0.73% Journal of the American Chemical Society 4 publications, 0.73%
Journal of the European Ceramic Society	Journal of the European Ceramic Society, 4, 0.73% Journal of the European Ceramic Society 4 publications, 0.73%
Batteries	Batteries, 4, 0.73% Batteries 4 publications, 0.73%
	5 10 15 20 25 30 35 40 45

Citations by publishers

	20 40 60 80 100 120 140 160 180
Elsevier	Elsevier, 176, 32.18% Elsevier 176 publications, 32.18%
American Chemical Society (ACS)	American Chemical Society (ACS), 83, 15.17% American Chemical Society (ACS) 83 publications, 15.17%
Wiley	Wiley, 71, 12.98% Wiley 71 publications, 12.98%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 61, 11.15% Royal Society of Chemistry (RSC) 61 publications, 11.15%
Springer Nature	Springer Nature, 52, 9.51% Springer Nature 52 publications, 9.51%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 13, 2.38% Multidisciplinary Digital Publishing Institute (MDPI) 13 publications, 2.38%
The Electrochemical Society	The Electrochemical Society, 13, 2.38% The Electrochemical Society 13 publications, 2.38%
IOP Publishing	IOP Publishing, 10, 1.83% IOP Publishing 10 publications, 1.83%
Ceramic Society of Japan	Ceramic Society of Japan, 7, 1.28% Ceramic Society of Japan 7 publications, 1.28%
Frontiers Media S.A.	Frontiers Media S.A., 6, 1.1% Frontiers Media S.A. 6 publications, 1.1%
American Physical Society (APS)	American Physical Society (APS), 5, 0.91% American Physical Society (APS) 5 publications, 0.91%
The Electrochemical Society of Japan	The Electrochemical Society of Japan, 5, 0.91% The Electrochemical Society of Japan 5 publications, 0.91%
Taylor & Francis	Taylor & Francis, 4, 0.73% Taylor & Francis 4 publications, 0.73%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 4, 0.73% American Institute of Physics (AIP) 4 publications, 0.73%
Walter de Gruyter	Walter de Gruyter, 3, 0.55% Walter de Gruyter 3 publications, 0.55%
World Scientific	World Scientific, 2, 0.37% World Scientific 2 publications, 0.37%
Japan Society of Applied Physics	Japan Society of Applied Physics, 2, 0.37% Japan Society of Applied Physics 2 publications, 0.37%
Pleiades Publishing	Pleiades Publishing, 2, 0.37% Pleiades Publishing 2 publications, 0.37%
Chinese Physical Society	Chinese Physical Society, 2, 0.37% Chinese Physical Society 2 publications, 0.37%
ASME	ASME, 1, 0.18% ASME 1 publication, 0.18%
American Vacuum Society	American Vacuum Society, 1, 0.18% American Vacuum Society 1 publication, 0.18%
Canadian Science Publishing	Canadian Science Publishing, 1, 0.18% Canadian Science Publishing 1 publication, 0.18%
Physical Society of Japan	Physical Society of Japan, 1, 0.18% Physical Society of Japan 1 publication, 0.18%
Shanghai Institute of Ceramics	Shanghai Institute of Ceramics, 1, 0.18% Shanghai Institute of Ceramics 1 publication, 0.18%
Tsinghua University Press	Tsinghua University Press, 1, 0.18% Tsinghua University Press 1 publication, 0.18%
Higher Education Press	Higher Education Press, 1, 0.18% Higher Education Press 1 publication, 0.18%
Chinese Ceramic Society	Chinese Ceramic Society, 1, 0.18% Chinese Ceramic Society 1 publication, 0.18%
Korean Society of Industrial Engineering Chemistry	Korean Society of Industrial Engineering Chemistry, 1, 0.18% Korean Society of Industrial Engineering Chemistry 1 publication, 0.18%
Japan Radioisotope Association	Japan Radioisotope Association, 1, 0.18% Japan Radioisotope Association 1 publication, 0.18%
	20 40 60 80 100 120 140 160 180

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

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Ohta S., KOBAYASHI T., Asaoka T. High lithium ionic conductivity in the garnet-type oxide Li7−X La3(Zr2−X, NbX)O12 (X=0–2) // Journal of Power Sources. 2011. Vol. 196. No. 6. pp. 3342-3345.

GOST all authors (up to 50) Copy

Ohta S., KOBAYASHI T., Asaoka T. High lithium ionic conductivity in the garnet-type oxide Li7−X La3(Zr2−X, NbX)O12 (X=0–2) // Journal of Power Sources. 2011. Vol. 196. No. 6. pp. 3342-3345.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2010.11.089

UR - https://linkinghub.elsevier.com/retrieve/pii/S037877531002080X

TI - High lithium ionic conductivity in the garnet-type oxide Li7−X La3(Zr2−X, NbX)O12 (X=0–2)

T2 - Journal of Power Sources

AU - Ohta, Shingo

AU - KOBAYASHI, Tetsuro

AU - Asaoka, Takahiko

PY - 2011

DA - 2011/03/01 00:00:00

PB - Elsevier

SP - 3342-3345

IS - 6

VL - 196

SN - 0378-7753

ER -

BibTex |

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BibTex Copy

@article{2011_Ohta,

author = {Shingo Ohta and Tetsuro KOBAYASHI and Takahiko Asaoka},

title = {High lithium ionic conductivity in the garnet-type oxide Li7−X La3(Zr2−X, NbX)O12 (X=0–2)},

journal = {Journal of Power Sources},

year = {2011},

volume = {196},

publisher = {Elsevier},

month = {mar},

url = {https://linkinghub.elsevier.com/retrieve/pii/S037877531002080X},

number = {6},

pages = {3342--3345},

doi = {10.1016/j.jpowsour.2010.11.089}

}

MLA

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MLA Copy

Ohta, Shingo, et al. “High lithium ionic conductivity in the garnet-type oxide Li7−X La3(Zr2−X, NbX)O12 (X=0–2).” Journal of Power Sources, vol. 196, no. 6, Mar. 2011, pp. 3342-3345. https://linkinghub.elsevier.com/retrieve/pii/S037877531002080X.

Found error?

Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)