Journal of Power Sources, volume 244, pages 707-710

Preparation and ionic conductivities of (100 − x)(0.75Li2S·0.25P2S5)·xLiBH4 glass electrolytes

Publication typeJournal Article
Publication date2013-12-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor9.2
ISSN03787753
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
(100 −  x )(0.75Li 2 S·0.25P 2 S 5 )· x LiBH 4 (0 ≤  x (mol%) ≤ 33) glass electrolytes were prepared from 75Li 2 S·25P 2 S 5 (mol%) glass and LiBH 4 crystal by a mechanical milling technique. The effects of the addition of LiBH 4 on the structures and properties of the glass electrolytes were examined. The DSC curves of the prepared glasses with LiBH 4 did not have the endothermic peak attributable to the phase transition of LiBH 4 crystal. The Raman spectra of the glasses indicated that the glasses included PS 4 3− and BH 4 − ions. The conductivities of the glasses increased with increasing the LiBH 4 content. The glass at the composition of x  = 33 showed the highest lithium-ion conductivity of 1.6 × 10 −3  S cm −1 at room temperature. The glass had a wide electrochemical window up to 5 V vs. Li + /Li. An all-solid-state Li/TiS 2 cell using the glass as an electrolyte successfully operated as a secondary battery at 25 °C.

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Yamauchi A. et al. Preparation and ionic conductivities of (100 − x)(0.75Li2S·0.25P2S5)·xLiBH4 glass electrolytes // Journal of Power Sources. 2013. Vol. 244. pp. 707-710.
GOST all authors (up to 50) Copy
Yamauchi A., Sakuda A., Hayashi A., Tatsumisago M. Preparation and ionic conductivities of (100 − x)(0.75Li2S·0.25P2S5)·xLiBH4 glass electrolytes // Journal of Power Sources. 2013. Vol. 244. pp. 707-710.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jpowsour.2012.12.001
UR - https://doi.org/10.1016/j.jpowsour.2012.12.001
TI - Preparation and ionic conductivities of (100 − x)(0.75Li2S·0.25P2S5)·xLiBH4 glass electrolytes
T2 - Journal of Power Sources
AU - Yamauchi, Akihiro
AU - Sakuda, Atsushi
AU - Hayashi, Akitoshi
AU - Tatsumisago, Masahiro
PY - 2013
DA - 2013/12/01 00:00:00
PB - Elsevier
SP - 707-710
VL - 244
SN - 0378-7753
ER -
BibTex
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BibTex Copy
@article{2013_Yamauchi,
author = {Akihiro Yamauchi and Atsushi Sakuda and Akitoshi Hayashi and Masahiro Tatsumisago},
title = {Preparation and ionic conductivities of (100 − x)(0.75Li2S·0.25P2S5)·xLiBH4 glass electrolytes},
journal = {Journal of Power Sources},
year = {2013},
volume = {244},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.jpowsour.2012.12.001},
pages = {707--710},
doi = {10.1016/j.jpowsour.2012.12.001}
}
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