Journal of Power Sources, volume 240, pages 18-25
Lithium ion transport properties of high conductive tellurium substituted Li7La3Zr2O12 cubic lithium garnets
Publication type: Journal Article
Publication date: 2013-10-01
Journal:
Journal of Power Sources
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.2
ISSN: 03787753
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
In this paper synthesis, structure and Li + transport process of Li 7−2 x La 3 Zr 2− x Te x O 12 ( x = 0.125 and 0.25) lithium garnets are reported. Preparation of high Li + conductive Li 7 La 3 Zr 2 O 12 (LLZ) in cubic phase by conventional solid state method demands sintering it around 1200 °C for 36 h in Al 2 O 3 crucible. Cubic phase lithium garnet is successfully obtained at lower sintering temperature around 750 °C with the substitution of Zr 4+ by Te 6+ in the garnet lattice over the investigated composition range. Among the investigated compounds Li 6.5 La 3 Zr 1.75 Te 0.25 O 12 sintered at 1100 °C exhibits a maximum room temperature total (bulk + grain boundary) ionic conductivity of 1.02 × 10 −3 S cm −1 . The present studies reveal the stabilization of the cubic garnet phase relatively at lower sintering temperature along with an enhancement in Li + conductivity with lithium content lesser than 7 by suitable doping in Li 7 La 3 Zr 2 O 12 .
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Citations by publishers
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Deviannapoorani C. et al. Lithium ion transport properties of high conductive tellurium substituted Li7La3Zr2O12 cubic lithium garnets // Journal of Power Sources. 2013. Vol. 240. pp. 18-25.
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Deviannapoorani C., Dhivya L., Ramakumar S., Murugan R. Lithium ion transport properties of high conductive tellurium substituted Li7La3Zr2O12 cubic lithium garnets // Journal of Power Sources. 2013. Vol. 240. pp. 18-25.
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TY - JOUR
DO - 10.1016/j.jpowsour.2013.03.166
UR - https://linkinghub.elsevier.com/retrieve/pii/S0378775313005600
TI - Lithium ion transport properties of high conductive tellurium substituted Li7La3Zr2O12 cubic lithium garnets
T2 - Journal of Power Sources
AU - Deviannapoorani, C
AU - Dhivya, L
AU - Ramakumar, S.
AU - Murugan, Ramaswamy
PY - 2013
DA - 2013/10/01 00:00:00
PB - Elsevier
SP - 18-25
VL - 240
SN - 0378-7753
ER -
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@article{2013_Deviannapoorani,
author = {C Deviannapoorani and L Dhivya and S. Ramakumar and Ramaswamy Murugan},
title = {Lithium ion transport properties of high conductive tellurium substituted Li7La3Zr2O12 cubic lithium garnets},
journal = {Journal of Power Sources},
year = {2013},
volume = {240},
publisher = {Elsevier},
month = {oct},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0378775313005600},
pages = {18--25},
doi = {10.1016/j.jpowsour.2013.03.166}
}