Journal of Power Sources, volume 329, pages 530-535
Li 10 Si 0.3 Sn 0.7 P 2 S 12 – A low-cost and low-grain-boundary-resistance lithium superionic conductor
Publication type: Journal Article
Publication date: 2016-10-01
Journal:
Journal of Power Sources
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.2
ISSN: 03787753
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
Despite remarkable recent advances in the field of solid electrolytes for lithium ion batteries, there is still considerable room for improvements with respect to ionic conductivity, cost and electrochemical stability. This study tests systematically how much Sn in the superionic conductor Li 10 SnP 2 S 12 can be replaced by Si or Al, while retaining its tetragonal structure. For comparison, also the known superionic conductors Li 10 SnP 2 S 12 , Li 10 GeP 2 S 12 , and Li 10 SiP 2 S 12 are synthesized and characterized with respect to their grain and grain boundary resistances. The results show that due to the negligible grain boundary resistance of the new compound Li 10 Si 0.3 Sn 0.7 P 2 S 12 , its total Li + ion conductivity is only 10–20% lower than that of the expensive superionic conductor Li 10 GeP 2 S 12 and about four times higher than that of Li 10 SiP 2 S 12 .
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Citations by publishers
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Bron P., Dehnen S., Roling B. Li 10 Si 0.3 Sn 0.7 P 2 S 12 – A low-cost and low-grain-boundary-resistance lithium superionic conductor // Journal of Power Sources. 2016. Vol. 329. pp. 530-535.
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Bron P., Dehnen S., Roling B. Li 10 Si 0.3 Sn 0.7 P 2 S 12 – A low-cost and low-grain-boundary-resistance lithium superionic conductor // Journal of Power Sources. 2016. Vol. 329. pp. 530-535.
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TY - JOUR
DO - 10.1016/j.jpowsour.2016.08.115
UR - https://doi.org/10.1016/j.jpowsour.2016.08.115
TI - Li 10 Si 0.3 Sn 0.7 P 2 S 12 – A low-cost and low-grain-boundary-resistance lithium superionic conductor
T2 - Journal of Power Sources
AU - Bron, Philipp
AU - Dehnen, Stefanie
AU - Roling, Bernhard
PY - 2016
DA - 2016/10/01 00:00:00
PB - Elsevier
SP - 530-535
VL - 329
SN - 0378-7753
ER -
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@article{2016_Bron,
author = {Philipp Bron and Stefanie Dehnen and Bernhard Roling},
title = {Li 10 Si 0.3 Sn 0.7 P 2 S 12 – A low-cost and low-grain-boundary-resistance lithium superionic conductor},
journal = {Journal of Power Sources},
year = {2016},
volume = {329},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.jpowsour.2016.08.115},
pages = {530--535},
doi = {10.1016/j.jpowsour.2016.08.115}
}