Journal of Power Sources, volume 396, pages 824-830

Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte

Carolina Vinado ^{1, 2, 3}

Shanyu Wang

Shan-Yu Wang ^{1, 2, 3}

Yang Hao Chen He ⁴

Yang He

Xingcheng Xiao ⁵

Yun Li

Yun Li ^{1, 2, 3}

Chongmin Wang

ChunSheng Wang ⁴

Jihui Yang

Jiong Yang ^{1, 2, 3}

Hide authors affiliations Show authors affiliations: 5 affiliations

Seattle WA 98195 USA |

University of washington |

Materials Science and Engineering Department

⁴

Pacific Northwest National Laboratory, Environmental Molecular Science Laboratory, Richland, WA, 99354, USA |

⁵

Chemical Sciences and Materials Systems Lab, General Motors R&D Center, Warren, MI, 48090, USA |

Publication type: Journal Article

Publication date: 2018-08-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2018.06.038

Copy DOI

Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Thio-Lithium Superionic Conductor (Thio-LISICON) Li10GeP2S12 equivalent Li10SnP2S12 (LSPS) is comparable in ionic conductivity yet with a lower cost as an electrolyte for all solid-state batteries (ASSBs). ASSBs with LSPS solid electrolyte (SE), lithium-indium alloy anode, and LiCoO2 (LCO) cathode were successfully fabricated and their electrochemical performance at 60 °C was examined. Atomic layer deposition of Li3NbO4 on LCO was conducted to improve the interfacial stability. The Li3NbO4 coating effectively improves the cycle stability of the ASSB. Electrochemical impedance spectroscopy tests indicate a rapid growth of charge transfer resistance upon cycling for the cell with the uncoated LCO, primarily due to the surface instability and build-up of a space charge layer. However, the ASSBs with Li3NbO4 coated LCO show a more stable interface with a negligible impedance increase upon cycling, attributable to the buffering and passivating roles of the Li3NbO4 coating. The interfacial microstructure was analyzed to elucidate at the underlying reasons for the impedance increase and the pivotal role of the Li3NbO4 coating.

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Citations by journals

	1 2 3 4 5
Journal of Power Sources	Journal of Power Sources, 5, 9.43% Journal of Power Sources 5 publications, 9.43%
ACS applied materials & interfaces	ACS applied materials & interfaces, 5, 9.43% ACS applied materials & interfaces 5 publications, 9.43%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 2, 3.77% Journal of the Electrochemical Society 2 publications, 3.77%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 2, 3.77% Journal of Alloys and Compounds 2 publications, 3.77%
Electrochimica Acta	Electrochimica Acta, 2, 3.77% Electrochimica Acta 2 publications, 3.77%
Advanced Energy Materials	Advanced Energy Materials, 2, 3.77% Advanced Energy Materials 2 publications, 3.77%
ACS Sustainable Chemistry and Engineering	ACS Sustainable Chemistry and Engineering, 2, 3.77% ACS Sustainable Chemistry and Engineering 2 publications, 3.77%
Energy and Environmental Science	Energy and Environmental Science, 2, 3.77% Energy and Environmental Science 2 publications, 3.77%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 1.89% ACS Applied Energy Materials 1 publication, 1.89%
Materials	Materials, 1, 1.89% Materials 1 publication, 1.89%
Applied Sciences (Switzerland)	Applied Sciences (Switzerland), 1, 1.89% Applied Sciences (Switzerland) 1 publication, 1.89%
Nature Communications	Nature Communications, 1, 1.89% Nature Communications 1 publication, 1.89%
Current Opinion in Solid State and Materials Science	Current Opinion in Solid State and Materials Science, 1, 1.89% Current Opinion in Solid State and Materials Science 1 publication, 1.89%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 1.89% Journal of Colloid and Interface Science 1 publication, 1.89%
Applied Surface Science	Applied Surface Science, 1, 1.89% Applied Surface Science 1 publication, 1.89%
Ceramics International	Ceramics International, 1, 1.89% Ceramics International 1 publication, 1.89%
Current Applied Physics	Current Applied Physics, 1, 1.89% Current Applied Physics 1 publication, 1.89%
Journal of Membrane Science	Journal of Membrane Science, 1, 1.89% Journal of Membrane Science 1 publication, 1.89%
Energy Storage Materials	Energy Storage Materials, 1, 1.89% Energy Storage Materials 1 publication, 1.89%
Zeitschrift fur Anorganische und Allgemeine Chemie	Zeitschrift fur Anorganische und Allgemeine Chemie, 1, 1.89% Zeitschrift fur Anorganische und Allgemeine Chemie 1 publication, 1.89%
Advanced Materials	Advanced Materials, 1, 1.89% Advanced Materials 1 publication, 1.89%
Advanced Materials Interfaces	Advanced Materials Interfaces, 1, 1.89% Advanced Materials Interfaces 1 publication, 1.89%
Journal of the American Ceramic Society	Journal of the American Ceramic Society, 1, 1.89% Journal of the American Ceramic Society 1 publication, 1.89%
Advanced Energy and Sustainability Research	Advanced Energy and Sustainability Research, 1, 1.89% Advanced Energy and Sustainability Research 1 publication, 1.89%
Nano Letters	Nano Letters, 1, 1.89% Nano Letters 1 publication, 1.89%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 1.89% Electrochemical Energy Reviews 1 publication, 1.89%
Chemistry of Materials	Chemistry of Materials, 1, 1.89% Chemistry of Materials 1 publication, 1.89%
Materials Horizons	Materials Horizons, 1, 1.89% Materials Horizons 1 publication, 1.89%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 1, 1.89% Journal of Materials Chemistry A 1 publication, 1.89%
	1 2 3 4 5

Citations by publishers

	2 4 6 8 10 12 14 16 18 20
Elsevier	Elsevier, 19, 35.85% Elsevier 19 publications, 35.85%
American Chemical Society (ACS)	American Chemical Society (ACS), 11, 20.75% American Chemical Society (ACS) 11 publications, 20.75%
Wiley	Wiley, 7, 13.21% Wiley 7 publications, 13.21%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 5, 9.43% Royal Society of Chemistry (RSC) 5 publications, 9.43%
The Electrochemical Society	The Electrochemical Society, 2, 3.77% The Electrochemical Society 2 publications, 3.77%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 3.77% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 3.77%
Springer Nature	Springer Nature, 2, 3.77% Springer Nature 2 publications, 3.77%
Walter de Gruyter	Walter de Gruyter, 1, 1.89% Walter de Gruyter 1 publication, 1.89%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.89% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.89%
	2 4 6 8 10 12 14 16 18 20

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Vinado C. et al. Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte // Journal of Power Sources. 2018. Vol. 396. pp. 824-830.

GOST all authors (up to 50) Copy

Vinado C., Wang S., Wang S., He Y., He Y. H. C., Xiao X., Li Y., Li Y., Wang C., Wang C., Yang J., Yang J. Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte // Journal of Power Sources. 2018. Vol. 396. pp. 824-830.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2018.06.038

UR - https://doi.org/10.1016/j.jpowsour.2018.06.038

TI - Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte

T2 - Journal of Power Sources

AU - Vinado, Carolina

AU - Wang, Shanyu

AU - He, Yang

AU - Xiao, Xingcheng

AU - Li, Yun

AU - Wang, Chongmin

AU - Yang, Jihui

AU - Wang, Shan-Yu

AU - He, Yang Hao Chen

AU - Li, Yun

AU - Wang, ChunSheng

AU - Yang, Jiong

PY - 2018

DA - 2018/08/01 00:00:00

PB - Elsevier

SP - 824-830

VL - 396

SN - 0378-7753

ER -

BibTex

Cite this

BibTex Copy

@article{2018_Vinado,

author = {Carolina Vinado and Shanyu Wang and Yang He and Xingcheng Xiao and Yun Li and Chongmin Wang and Jihui Yang and Shan-Yu Wang and Yang Hao Chen He and Yun Li and ChunSheng Wang and Jiong Yang},

title = {Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte},

journal = {Journal of Power Sources},

year = {2018},

volume = {396},

publisher = {Elsevier},

month = {aug},

url = {https://doi.org/10.1016/j.jpowsour.2018.06.038},

pages = {824--830},

doi = {10.1016/j.jpowsour.2018.06.038}

}

Found error?

Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)