Journal of Power Sources, volume 407, pages 31-43

A review of structural properties and synthesis methods of solid electrolyte materials in the Li2S − P2S5 binary system

Ömer Ulaş Kudu 1, 2
Theodosios Famprikis 1, 3, 4
Benoit Fleutot 1, 2
Marc-David Braida 5
Thierry Le Mercier 5
Md. Saiful Islam 4
1
 
Laboratoire de Réactivité et de Chimie des Solides (UMR CNRS 7314), Université de Picardie Jules Verne, 33 rue Saint Leu, 80039, Amiens Cedex, France
2
 
Réseau sur le Stockage Électrochimique de l’Énergie (RS2E), FR CNRS 3459, 80039, Amiens, France
3
 
ALISTORE European Research Institute, FR CNRS 3104, 80039, Amiens Cedex, France
4
 
Department of Chemistry, University of Bath, Bath BA2 7AY, United Kingdom
5
 
Solvay R&I, 52 rue de la Haie Coq, 93306, Aubervilliers, France
6
 
Laboratoire de Réactivité et de Chimie des Solides (UMR CNRS 7314), Université de Picardie Jules Verne, 33 rue Saint Leu, 80039 Amiens Cedex, France
7
 
Réseau sur le Stockage Électrochimique de l’Énergie (RS2E), FR CNRS 3459, 80039 Amiens, France
Publication typeJournal Article
Publication date2018-12-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor9.2
ISSN03787753
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
All-solid-state-batteries (ASSBs) are one of the most promising post-lithium-ion technologies that can increase the specific energy density and safety of secondary lithium batteries. Solid sulfide electrolytes are considered as promising candidates to be used in ASSBs owing to high ionic conductivities. In particular, solid electrolytes in the Li2S − P2S5 binary system have attracted considerable attention as they are composed of low-cost elements and they provide ionic conductivity values comparable to those of liquid electrolytes (>10−4 Scm−1). In this review, the structural properties and synthesis methods of materials in the binary system are summarized. Distinctions in local structures and Li-ion conduction properties between glassy, glass-ceramic, and crystalline materials are highlighted. Possible mechanisms are proposed for the fast ionic conduction observed in glass-ceramics. Important parameters of each synthesis method are suggested and the relationships between structure, synthesis and material properties are discussed. The goals of this review are to provide greater understanding of the state-of-the-art in the field, and to point out the overlooked aspects for application.

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Kudu Ö. U. et al. A review of structural properties and synthesis methods of solid electrolyte materials in the Li2S − P2S5 binary system // Journal of Power Sources. 2018. Vol. 407. pp. 31-43.
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Kudu Ö. U., Famprikis T., Fleutot B., Braida M., Le Mercier T., Islam M. S., Masquelier C. A review of structural properties and synthesis methods of solid electrolyte materials in the Li2S − P2S5 binary system // Journal of Power Sources. 2018. Vol. 407. pp. 31-43.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jpowsour.2018.10.037
UR - https://doi.org/10.1016/j.jpowsour.2018.10.037
TI - A review of structural properties and synthesis methods of solid electrolyte materials in the Li2S − P2S5 binary system
T2 - Journal of Power Sources
AU - Kudu, Ömer Ulaş
AU - Famprikis, Theodosios
AU - Fleutot, Benoit
AU - Braida, Marc-David
AU - Le Mercier, Thierry
AU - Islam, Md. Saiful
AU - Masquelier, Christian
PY - 2018
DA - 2018/12/01 00:00:00
PB - Elsevier
SP - 31-43
VL - 407
SN - 0378-7753
ER -
BibTex
Cite this
BibTex Copy
@article{2018_Kudu,
author = {Ömer Ulaş Kudu and Theodosios Famprikis and Benoit Fleutot and Marc-David Braida and Thierry Le Mercier and Md. Saiful Islam and Christian Masquelier},
title = {A review of structural properties and synthesis methods of solid electrolyte materials in the Li2S − P2S5 binary system},
journal = {Journal of Power Sources},
year = {2018},
volume = {407},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.jpowsour.2018.10.037},
pages = {31--43},
doi = {10.1016/j.jpowsour.2018.10.037}
}
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