Journal of Power Sources, volume 412, pages 78-85

Poly(ethylene oxide) reinforced Li6PS5Cl composite solid electrolyte for all-solid-state lithium battery: Enhanced electrochemical performance, mechanical property and interfacial stability

Jun Zhang ^{1, 2, 3}

Chao Zheng ^{1, 2, 3}

Jiatao Lou ^{1, 2, 3}

Yang Xia ^{1, 2, 3}

Chu Liang ^{1, 2, 3}

Hui Huang ^{1, 2, 3}

Yongping Gan ^{1, 2, 3}

Xinyong Tao ^{1, 2, 3}

Wenkui Zhang ^{1, 2, 3}

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Zhejiang university of Technology |

College of Materials Science and Engineering

Hangzhou, China |

Publication type: Journal Article

Publication date: 2019-02-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2018.11.036

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Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Argyrodite Li6PS5Cl is a promising solid electrolyte in all-solid-state lithium batteries owing to its high ionic conductivity. However, the poor mechanical property and undesirable interfacial property restrict its application. In order to solve these issues, we fabricate Li6PS5Cl/poly(ethylene oxide) composite solid electrolytes with enhanced mechanical property and stable lithium/electrolyte interface. By adding 5 to 20 wt% poly(ethylene oxide), the proportional limit of composite solid electrolytes is enhanced by ∼150%, reaching a value up to 60 MPa. With 5 wt% poly(ethylene oxide), the as-assembled sandwich-type LiNi0·8Co0·1Mn0·1O2/composite solid electrolytes/Li battery exhibits enhanced cycling performance with a capacity retention rate of 91% over 200 cycles at 0.05C and 30 °C. Ex situ characterizations reveal that by adding suitable poly(ethylene oxide) content in Li6PS5Cl, the interfacial reactions and lithium dendrite growth can be effectively inhibited, resulting in much improved cycling performance of all-solid-state lithium batteries.

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Citations by journals

	2 4 6 8 10 12 14 16
Journal of Power Sources	Journal of Power Sources, 16, 10.67% Journal of Power Sources 16 publications, 10.67%
ACS applied materials & interfaces	ACS applied materials & interfaces, 11, 7.33% ACS applied materials & interfaces 11 publications, 7.33%
ACS Applied Energy Materials	ACS Applied Energy Materials, 9, 6% ACS Applied Energy Materials 9 publications, 6%
Electrochimica Acta	Electrochimica Acta, 9, 6% Electrochimica Acta 9 publications, 6%
Chemical Engineering Journal	Chemical Engineering Journal, 7, 4.67% Chemical Engineering Journal 7 publications, 4.67%
Energy Storage Materials	Energy Storage Materials, 7, 4.67% Energy Storage Materials 7 publications, 4.67%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 5, 3.33% Journal of Alloys and Compounds 5 publications, 3.33%
Nanotechnology	Nanotechnology, 5, 3.33% Nanotechnology 5 publications, 3.33%
Advanced Materials	Advanced Materials, 5, 3.33% Advanced Materials 5 publications, 3.33%
Advanced Energy Materials	Advanced Energy Materials, 4, 2.67% Advanced Energy Materials 4 publications, 2.67%
Batteries & Supercaps	Batteries & Supercaps, 3, 2% Batteries & Supercaps 3 publications, 2%
Energy Technology	Energy Technology, 2, 1.33% Energy Technology 2 publications, 1.33%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 2, 1.33% Journal of the Electrochemical Society 2 publications, 1.33%
Materials	Materials, 2, 1.33% Materials 2 publications, 1.33%
Frontiers in Energy Research	Frontiers in Energy Research, 2, 1.33% Frontiers in Energy Research 2 publications, 1.33%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 2, 1.33% Journal of Solid State Electrochemistry 2 publications, 1.33%
Nano Energy	Nano Energy, 2, 1.33% Nano Energy 2 publications, 1.33%
Journal of Energy Chemistry	Journal of Energy Chemistry, 2, 1.33% Journal of Energy Chemistry 2 publications, 1.33%
Materials Chemistry and Physics	Materials Chemistry and Physics, 2, 1.33% Materials Chemistry and Physics 2 publications, 1.33%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 2, 1.33% Journal of Colloid and Interface Science 2 publications, 1.33%
Advanced Functional Materials	Advanced Functional Materials, 2, 1.33% Advanced Functional Materials 2 publications, 1.33%
Energy & Environmental Materials	Energy & Environmental Materials, 2, 1.33% Energy & Environmental Materials 2 publications, 1.33%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 2, 1.33% Journal of Materials Chemistry A 2 publications, 1.33%
Nano-Micro Letters	Nano-Micro Letters, 1, 0.67% Nano-Micro Letters 1 publication, 0.67%
EcoMat	EcoMat, 1, 0.67% EcoMat 1 publication, 0.67%
Nanomaterials	Nanomaterials, 1, 0.67% Nanomaterials 1 publication, 0.67%
Frontiers in Chemistry	Frontiers in Chemistry, 1, 0.67% Frontiers in Chemistry 1 publication, 0.67%
Energies	Energies, 1, 0.67% Energies 1 publication, 0.67%
International Journal of Minerals, Metallurgy and Materials	International Journal of Minerals, Metallurgy and Materials, 1, 0.67% International Journal of Minerals, Metallurgy and Materials 1 publication, 0.67%
Colloids and Surfaces A: Physicochemical and Engineering Aspects	Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1, 0.67% Colloids and Surfaces A: Physicochemical and Engineering Aspects 1 publication, 0.67%
	2 4 6 8 10 12 14 16

Citations by publishers

	10 20 30 40 50 60 70
Elsevier	Elsevier, 65, 43.33% Elsevier 65 publications, 43.33%
Wiley	Wiley, 26, 17.33% Wiley 26 publications, 17.33%
American Chemical Society (ACS)	American Chemical Society (ACS), 23, 15.33% American Chemical Society (ACS) 23 publications, 15.33%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 10, 6.67% Royal Society of Chemistry (RSC) 10 publications, 6.67%
IOP Publishing	IOP Publishing, 6, 4% IOP Publishing 6 publications, 4%
Springer Nature	Springer Nature, 5, 3.33% Springer Nature 5 publications, 3.33%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 4, 2.67% Multidisciplinary Digital Publishing Institute (MDPI) 4 publications, 2.67%
Frontiers Media S.A.	Frontiers Media S.A., 3, 2% Frontiers Media S.A. 3 publications, 2%
The Electrochemical Society	The Electrochemical Society, 2, 1.33% The Electrochemical Society 2 publications, 1.33%
University of Science and Technology Beijing	University of Science and Technology Beijing, 1, 0.67% University of Science and Technology Beijing 1 publication, 0.67%
Chinese Ceramic Society	Chinese Ceramic Society, 1, 0.67% Chinese Ceramic Society 1 publication, 0.67%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 0.67% American Association for the Advancement of Science (AAAS) 1 publication, 0.67%
Hans Publishers	Hans Publishers, 1, 0.67% Hans Publishers 1 publication, 0.67%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 0.67% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 0.67%
	10 20 30 40 50 60 70

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Zhang J. et al. Poly(ethylene oxide) reinforced Li6PS5Cl composite solid electrolyte for all-solid-state lithium battery: Enhanced electrochemical performance, mechanical property and interfacial stability // Journal of Power Sources. 2019. Vol. 412. pp. 78-85.

GOST all authors (up to 50) Copy

Zhang J., Zheng C., Lou J., Xia Y., Liang C., Huang H., Gan Y., Tao X., Zhang W. Poly(ethylene oxide) reinforced Li6PS5Cl composite solid electrolyte for all-solid-state lithium battery: Enhanced electrochemical performance, mechanical property and interfacial stability // Journal of Power Sources. 2019. Vol. 412. pp. 78-85.

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2018.11.036

UR - https://doi.org/10.1016/j.jpowsour.2018.11.036

TI - Poly(ethylene oxide) reinforced Li6PS5Cl composite solid electrolyte for all-solid-state lithium battery: Enhanced electrochemical performance, mechanical property and interfacial stability

T2 - Journal of Power Sources

AU - Zhang, Jun

AU - Zheng, Chao

AU - Lou, Jiatao

AU - Xia, Yang

AU - Liang, Chu

AU - Huang, Hui

AU - Gan, Yongping

AU - Tao, Xinyong

AU - Zhang, Wenkui

PY - 2019

DA - 2019/02/01 00:00:00

PB - Elsevier

SP - 78-85

VL - 412

SN - 0378-7753

ER -

BibTex

Cite this

BibTex Copy

@article{2019_Zhang,

author = {Jun Zhang and Chao Zheng and Jiatao Lou and Yang Xia and Chu Liang and Hui Huang and Yongping Gan and Xinyong Tao and Wenkui Zhang},

title = {Poly(ethylene oxide) reinforced Li6PS5Cl composite solid electrolyte for all-solid-state lithium battery: Enhanced electrochemical performance, mechanical property and interfacial stability},

journal = {Journal of Power Sources},

year = {2019},

volume = {412},

publisher = {Elsevier},

month = {feb},

url = {https://doi.org/10.1016/j.jpowsour.2018.11.036},

pages = {78--85},

doi = {10.1016/j.jpowsour.2018.11.036}

}

Found error?

Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)