Journal of Power Sources, volume 460, pages 228125

Interface engineering of Li1.3Al0.3Ti1.7(PO4)3 ceramic electrolyte via multifunctional interfacial layer for all-solid-state lithium batteries

Yingmin Jin ¹

Chaojun Liu ¹

Zong Xin ¹

D Li ¹

Mengyu Fu ¹

Siping Tan ²

Yueping Xiong ¹

Junhua Wei ³

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MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, PR China |

MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, PR China |

State Key Laboratory of Advanced Chemical Power Sources, Guizhou Meiling Power Sources Co. Ltd., Zunyi, Guizhou, 563003, PR China |

Publication type: Journal Article

Publication date: 2020-06-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2020.228125

Copy DOI

Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Li1.3Al0.3Ti1.7(PO4)3 (LATP) suffers from high interfacial resistance and instability with Li which hinder its application in all-solid-state lithium batteries. Herein, we propose an effective method to overcome these obstacles by introducing a LATP nanoparticle-reinforced composite polymer electrolyte (CPE) at LATP/Li interface. The multifunctional CPE interfacial layer can not only avoid side reactions between LATP and Li, but also ensure intimate contact at LATP/Li interface to reduce interfacial resistance. Moreover, the soft CPE layer can mitigate the large volume change of Li anode during cycling due to its high viscosity and flexible features. With the assistance of LATP fillers, the CPE interfacial layer can inhibit the formation and penetration of Li dendrites with enhanced mechanical strength and uniform Li deposition. After the modification of CPE interfacial layer, solid-state electrolyte with the sandwiched structure of CPE/LATP/CPE possesses satisfactory features such as high ionic conductivity, high interfacial stability and wide electrochemical window. Symmetric Li cell exhibits significant reduction in interfacial resistance (from 2852 Ω cm2 to 505 Ω cm2) and overpotential (from 2.03 V to 0.04 V), which ensures a stable galvanostatic cycle for more than 400 h at 0.05 mA cm−2. Solid-state LiFePO4/LATP/CPE/Li batteries deliver remarkable cycling ability and high coulombic efficiency.

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Citations by journals

	1 2 3 4 5 6 7 8
Journal of Power Sources	Journal of Power Sources, 8, 12.7% Journal of Power Sources 8 publications, 12.7%
Energy Storage Materials	Energy Storage Materials, 5, 7.94% Energy Storage Materials 5 publications, 7.94%
Ionics	Ionics, 5, 7.94% Ionics 5 publications, 7.94%
Journal of Energy Chemistry	Journal of Energy Chemistry, 4, 6.35% Journal of Energy Chemistry 4 publications, 6.35%
ACS applied materials & interfaces	ACS applied materials & interfaces, 3, 4.76% ACS applied materials & interfaces 3 publications, 4.76%
Nanomaterials	Nanomaterials, 2, 3.17% Nanomaterials 2 publications, 3.17%
Polymers	Polymers, 2, 3.17% Polymers 2 publications, 3.17%
Surface and Coatings Technology	Surface and Coatings Technology, 2, 3.17% Surface and Coatings Technology 2 publications, 3.17%
Materials Today Energy	Materials Today Energy, 2, 3.17% Materials Today Energy 2 publications, 3.17%
International Journal of Electrochemical Science	International Journal of Electrochemical Science, 2, 3.17% International Journal of Electrochemical Science 2 publications, 3.17%
Small	Small, 1, 1.59% Small 1 publication, 1.59%
Cell Reports Physical Science	Cell Reports Physical Science, 1, 1.59% Cell Reports Physical Science 1 publication, 1.59%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 1.59% Chemical Engineering Journal 1 publication, 1.59%
Electrochimica Acta	Electrochimica Acta, 1, 1.59% Electrochimica Acta 1 publication, 1.59%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 1.59% Journal of Alloys and Compounds 1 publication, 1.59%
Journal of Membrane Science	Journal of Membrane Science, 1, 1.59% Journal of Membrane Science 1 publication, 1.59%
InfoMat	InfoMat, 1, 1.59% InfoMat 1 publication, 1.59%
Advanced Functional Materials	Advanced Functional Materials, 1, 1.59% Advanced Functional Materials 1 publication, 1.59%
EcoMat	EcoMat, 1, 1.59% EcoMat 1 publication, 1.59%
ACS Omega	ACS Omega, 1, 1.59% ACS Omega 1 publication, 1.59%
Energy & Environmental Materials	Energy & Environmental Materials, 1, 1.59% Energy & Environmental Materials 1 publication, 1.59%
ACS Energy Letters	ACS Energy Letters, 1, 1.59% ACS Energy Letters 1 publication, 1.59%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 1.59% Journal of Physical Chemistry C 1 publication, 1.59%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 1, 1.59% Materials Chemistry Frontiers 1 publication, 1.59%
Energy and Environmental Science	Energy and Environmental Science, 1, 1.59% Energy and Environmental Science 1 publication, 1.59%
Nanoscale Advances	Nanoscale Advances, 1, 1.59% Nanoscale Advances 1 publication, 1.59%
Energy Advances	Energy Advances, 1, 1.59% Energy Advances 1 publication, 1.59%
Materials Advances	Materials Advances, 1, 1.59% Materials Advances 1 publication, 1.59%
Advanced Energy Materials	Advanced Energy Materials, 1, 1.59% Advanced Energy Materials 1 publication, 1.59%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 1.59% Journal of Colloid and Interface Science 1 publication, 1.59%
	1 2 3 4 5 6 7 8

Citations by publishers

	5 10 15 20 25 30
Elsevier	Elsevier, 30, 47.62% Elsevier 30 publications, 47.62%
Wiley	Wiley, 9, 14.29% Wiley 9 publications, 14.29%
American Chemical Society (ACS)	American Chemical Society (ACS), 6, 9.52% American Chemical Society (ACS) 6 publications, 9.52%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 6, 9.52% Royal Society of Chemistry (RSC) 6 publications, 9.52%
Springer Nature	Springer Nature, 5, 7.94% Springer Nature 5 publications, 7.94%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 4, 6.35% Multidisciplinary Digital Publishing Institute (MDPI) 4 publications, 6.35%
Electrochemical Science Group, University of Belgrade	Electrochemical Science Group, University of Belgrade, 1, 1.59% Electrochemical Science Group, University of Belgrade 1 publication, 1.59%
The Electrochemical Society	The Electrochemical Society, 1, 1.59% The Electrochemical Society 1 publication, 1.59%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.59% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.59%
	5 10 15 20 25 30

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Jin Y. et al. Interface engineering of Li1.3Al0.3Ti1.7(PO4)3 ceramic electrolyte via multifunctional interfacial layer for all-solid-state lithium batteries // Journal of Power Sources. 2020. Vol. 460. p. 228125.

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Jin Y., Liu C., Xin Z., Li D., Fu M., Tan S., Xiong Y., Wei J. Interface engineering of Li1.3Al0.3Ti1.7(PO4)3 ceramic electrolyte via multifunctional interfacial layer for all-solid-state lithium batteries // Journal of Power Sources. 2020. Vol. 460. p. 228125.

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2020.228125

UR - https://doi.org/10.1016/j.jpowsour.2020.228125

TI - Interface engineering of Li1.3Al0.3Ti1.7(PO4)3 ceramic electrolyte via multifunctional interfacial layer for all-solid-state lithium batteries

T2 - Journal of Power Sources

AU - Jin, Yingmin

AU - Liu, Chaojun

AU - Xin, Zong

AU - Li, D

AU - Fu, Mengyu

AU - Tan, Siping

AU - Xiong, Yueping

AU - Wei, Junhua

PY - 2020

DA - 2020/06/01 00:00:00

PB - Elsevier

SP - 228125

VL - 460

SN - 0378-7753

ER -

BibTex

Cite this

BibTex Copy

@article{2020_Jin,

author = {Yingmin Jin and Chaojun Liu and Zong Xin and D Li and Mengyu Fu and Siping Tan and Yueping Xiong and Junhua Wei},

title = {Interface engineering of Li1.3Al0.3Ti1.7(PO4)3 ceramic electrolyte via multifunctional interfacial layer for all-solid-state lithium batteries},

journal = {Journal of Power Sources},

year = {2020},

volume = {460},

publisher = {Elsevier},

month = {jun},

url = {https://doi.org/10.1016/j.jpowsour.2020.228125},

pages = {228125},

doi = {10.1016/j.jpowsour.2020.228125}

}

Found error?

Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)