Journal of Power Sources, volume 485, pages 229325

A high energy and power all-solid-state lithium battery enabled by modified sulfide electrolyte film

Shuting Luo ¹

Zhenyu Wang ²

Aoran Fan ¹

Xinyu Liu ²

Haidong Wang ¹

Wei Gang ¹

Ling-Yun Zhu ²

Xing Zhang ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Key Laboratory for Thermal Science and Power Engineering of Ministry of Education Department of Engineering Mechanics Tsinghua University Beijing 100084 China |

Guilin Electrical Equipment Scientific Research Institute Co. Ltd., Guilin, 541004, Guangxi, China |

Publication type: Journal Article

Publication date: 2021-02-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2020.229325

Copy DOI

Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

In recent decades, all-solid-state lithium batteries have gained enormous attention due to the improved safety performance and high specific energy. However, the brittle nature of sulfide-based solid electrolytes and poor interface compatibility limit the long-cycle stability and high rate performance of ASSLBs. The utilization of a thick solid electrolyte further reduces the cell-level energy and power. Herein, we prepare a thin sulfide electrolyte film (65 μm) using modified Li 6 PS 5 Cl and poly (ethylene oxide) (PEO). Under a high loading of 4.46 mA h cm −2 , the assembled cell employing this electrolyte film with LiNi 0.7 Co 0.2 Mn 0.1 O 2 cathode and lithium-indium alloy anode maintains a 1000 stable cycles with 74% capacity retention and average 99.85% coulombic efficiency at 60 °C. The cell-level energy and power are increased by an order of magnitude compared with traditionally prepared solid-state batteries. An excellent specific power of 374.7 W kg −1 is delivered at the initial cycle. This modified electrolyte film is expected to be commercially produced in the near future. • A thin sulfide electrolyte film (65 μm) is prepared using modified Li 6 PS 5 Cl and PEO. • The Li 6 PS 5 Cl powder is modified in an oxygen-containing atmosphere. • The full cell achieves a 1000 stable cycles with 74% capacity retention at 60 °C. • The cell delivers a high cell-level specific power of 374.7 W kg −1 at the initial cycle.

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Top-30

Citations by journals

	1 2 3 4
Journal of Power Sources	Journal of Power Sources, 4, 9.3% Journal of Power Sources 4 publications, 9.3%
ACS applied materials & interfaces	ACS applied materials & interfaces, 4, 9.3% ACS applied materials & interfaces 4 publications, 9.3%
Advanced Materials	Advanced Materials, 3, 6.98% Advanced Materials 3 publications, 6.98%
Advanced Energy Materials	Advanced Energy Materials, 2, 4.65% Advanced Energy Materials 2 publications, 4.65%
Energy & Environmental Materials	Energy & Environmental Materials, 2, 4.65% Energy & Environmental Materials 2 publications, 4.65%
Nano-Micro Letters	Nano-Micro Letters, 1, 2.33% Nano-Micro Letters 1 publication, 2.33%
Frontiers in Chemistry	Frontiers in Chemistry, 1, 2.33% Frontiers in Chemistry 1 publication, 2.33%
Ionics	Ionics, 1, 2.33% Ionics 1 publication, 2.33%
Electrochimica Acta	Electrochimica Acta, 1, 2.33% Electrochimica Acta 1 publication, 2.33%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 2.33% Chemical Engineering Journal 1 publication, 2.33%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 2.33% Journal of Colloid and Interface Science 1 publication, 2.33%
International Journal of Heat and Mass Transfer	International Journal of Heat and Mass Transfer, 1, 2.33% International Journal of Heat and Mass Transfer 1 publication, 2.33%
Energy & Fuels	Energy & Fuels, 1, 2.33% Energy & Fuels 1 publication, 2.33%
InfoMat	InfoMat, 1, 2.33% InfoMat 1 publication, 2.33%
ACS Energy Letters	ACS Energy Letters, 1, 2.33% ACS Energy Letters 1 publication, 2.33%
Angewandte Chemie	Angewandte Chemie, 1, 2.33% Angewandte Chemie 1 publication, 2.33%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 2.33% Angewandte Chemie - International Edition 1 publication, 2.33%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 2.33% ACS Applied Energy Materials 1 publication, 2.33%
Energy Material Advances	Energy Material Advances, 1, 2.33% Energy Material Advances 1 publication, 2.33%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 1, 2.33% Materials Chemistry Frontiers 1 publication, 2.33%
Journal of Applied Electrochemistry	Journal of Applied Electrochemistry, 1, 2.33% Journal of Applied Electrochemistry 1 publication, 2.33%
Batteries	Batteries, 1, 2.33% Batteries 1 publication, 2.33%
Applied Sciences (Switzerland)	Applied Sciences (Switzerland), 1, 2.33% Applied Sciences (Switzerland) 1 publication, 2.33%
Progress in Materials Science	Progress in Materials Science, 1, 2.33% Progress in Materials Science 1 publication, 2.33%
Energy Storage Materials	Energy Storage Materials, 1, 2.33% Energy Storage Materials 1 publication, 2.33%
Small	Small, 1, 2.33% Small 1 publication, 2.33%
Communications Materials	Communications Materials, 1, 2.33% Communications Materials 1 publication, 2.33%
International Journal of Applied Ceramic Technology	International Journal of Applied Ceramic Technology, 1, 2.33% International Journal of Applied Ceramic Technology 1 publication, 2.33%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 2.33% Russian Chemical Reviews 1 publication, 2.33%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12
Wiley	Wiley, 12, 27.91% Wiley 12 publications, 27.91%
Elsevier	Elsevier, 10, 23.26% Elsevier 10 publications, 23.26%
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 16.28% American Chemical Society (ACS) 7 publications, 16.28%
Springer Nature	Springer Nature, 4, 9.3% Springer Nature 4 publications, 9.3%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 3, 6.98% Multidisciplinary Digital Publishing Institute (MDPI) 3 publications, 6.98%
Frontiers Media S.A.	Frontiers Media S.A., 1, 2.33% Frontiers Media S.A. 1 publication, 2.33%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 2.33% American Association for the Advancement of Science (AAAS) 1 publication, 2.33%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 2.33% Royal Society of Chemistry (RSC) 1 publication, 2.33%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.33% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.33%
	2 4 6 8 10 12

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Luo S. et al. A high energy and power all-solid-state lithium battery enabled by modified sulfide electrolyte film // Journal of Power Sources. 2021. Vol. 485. p. 229325.

GOST all authors (up to 50) Copy

Luo S., Wang Z., Fan A., Liu X., Wang H., Gang W., Zhu L., Zhang X. A high energy and power all-solid-state lithium battery enabled by modified sulfide electrolyte film // Journal of Power Sources. 2021. Vol. 485. p. 229325.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2020.229325

UR - https://doi.org/10.1016/j.jpowsour.2020.229325

TI - A high energy and power all-solid-state lithium battery enabled by modified sulfide electrolyte film

T2 - Journal of Power Sources

AU - Luo, Shuting

AU - Wang, Zhenyu

AU - Fan, Aoran

AU - Liu, Xinyu

AU - Wang, Haidong

AU - Gang, Wei

AU - Zhu, Ling-Yun

AU - Zhang, Xing

PY - 2021

DA - 2021/02/01 00:00:00

PB - Elsevier

SP - 229325

VL - 485

SN - 0378-7753

ER -

BibTex

Cite this

BibTex Copy

@article{2021_Luo,

author = {Shuting Luo and Zhenyu Wang and Aoran Fan and Xinyu Liu and Haidong Wang and Wei Gang and Ling-Yun Zhu and Xing Zhang},

title = {A high energy and power all-solid-state lithium battery enabled by modified sulfide electrolyte film},

journal = {Journal of Power Sources},

year = {2021},

volume = {485},

publisher = {Elsevier},

month = {feb},

url = {https://doi.org/10.1016/j.jpowsour.2020.229325},

pages = {229325},

doi = {10.1016/j.jpowsour.2020.229325}

}

Found error?

Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)