Journal of Power Sources, volume 501, pages 230027

Interface regulation enabling three-dimensional Li1.3Al0.3Ti1.7(PO4)3-reinforced composite solid electrolyte for high-performance lithium batteries

Yingmin Jin ¹

Xin Zong ¹

Xuebai Zhang ¹

Chaojun Liu ¹

Dong Li ¹

Zhenggang Jia ¹

Gen Li Gen Li ¹

Xuanguang Zhou ¹

Junhua Wei ²

Yueping Xiong ¹

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MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, PR China |

State Key Laboratory of Advanced Chemical Power Sources, Guizhou Meiling Power Sources Co. Ltd., Zunyi, Guizhou, 563003, PR China |

Publication type: Journal Article

Publication date: 2021-07-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2021.230027

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Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Composite solid electrolyte (CSE) consisting of Li+ conductive fillers and polymer matrix has become attractive for high energy-density lithium batteries. Current researches focus on the “ceramic in polymer”-type CSE due to the severe agglomeration of ceramic particles. Consequently, the destroyed percolation network impedes the further improvement in ionic conductivity. In this work, we report a novel structural design of ceramic-enriched CSE consisting of three-dimensional (3D) interconnected Li1.3Al0.3Ti1.7(PO4)3 (LATP), polyvinylidene fluoride (PVDF) and LiN(SO2)2(CF3)2 (LiTFSI). The 3D LATP network is constructed through the surface functionalization of LATP particles by polymethyl methacrylate (PMMA). Owing to the intermolecular interaction between PMMA and PVDF, the incorporation of PMMA-coated LATP (denoted as LATP@PMMA) enables the uniform distribution of ceramic phase and generates interconnected LATP network. Noticeably, such an electrolyte maximizes the utilization of inorganic fillers through the facile treatment of zero-dimensional materials, which is comparable to those 3D template-derived fillers. Furthermore, continuous Li+ conduction pathways through LATP framework and LATP/PVDF interphase are guaranteed by the enhanced affinity of LATP towards PVDF matrix and the intrinsic Li+ complexation capability of PMMA. Remarkable cycling performances of the LiNi0.5Co0.2Mn0.3O2/LATP@PMMA-PVDF/Li batteries confirm the feasibility of 3D ceramic-enriched composite electrolyte in the application of solid-state lithium batteries.

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Citations by journals

	1 2 3 4
Chemical Engineering Journal	Chemical Engineering Journal, 4, 8.89% Chemical Engineering Journal 4 publications, 8.89%
ACS applied materials & interfaces	ACS applied materials & interfaces, 4, 8.89% ACS applied materials & interfaces 4 publications, 8.89%
Journal of Power Sources	Journal of Power Sources, 4, 8.89% Journal of Power Sources 4 publications, 8.89%
Energy Storage Materials	Energy Storage Materials, 2, 4.44% Energy Storage Materials 2 publications, 4.44%
Polymers	Polymers, 2, 4.44% Polymers 2 publications, 4.44%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 2, 4.44% Journal of Colloid and Interface Science 2 publications, 4.44%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 2, 4.44% Journal of Alloys and Compounds 2 publications, 4.44%
Small	Small, 2, 4.44% Small 2 publications, 4.44%
Journal of Energy Storage	Journal of Energy Storage, 2, 4.44% Journal of Energy Storage 2 publications, 4.44%
Nano-Micro Letters	Nano-Micro Letters, 1, 2.22% Nano-Micro Letters 1 publication, 2.22%
Coatings	Coatings, 1, 2.22% Coatings 1 publication, 2.22%
Rare Metals	Rare Metals, 1, 2.22% Rare Metals 1 publication, 2.22%
Ionics	Ionics, 1, 2.22% Ionics 1 publication, 2.22%
Current Opinion in Electrochemistry	Current Opinion in Electrochemistry, 1, 2.22% Current Opinion in Electrochemistry 1 publication, 2.22%
Energy & Fuels	Energy & Fuels, 1, 2.22% Energy & Fuels 1 publication, 2.22%
Advanced Functional Materials	Advanced Functional Materials, 1, 2.22% Advanced Functional Materials 1 publication, 2.22%
Energy Technology	Energy Technology, 1, 2.22% Energy Technology 1 publication, 2.22%
Advanced Engineering Materials	Advanced Engineering Materials, 1, 2.22% Advanced Engineering Materials 1 publication, 2.22%
ACS Sustainable Chemistry and Engineering	ACS Sustainable Chemistry and Engineering, 1, 2.22% ACS Sustainable Chemistry and Engineering 1 publication, 2.22%
Nano Research Energy	Nano Research Energy, 1, 2.22% Nano Research Energy 1 publication, 2.22%
Advanced Energy Materials	Advanced Energy Materials, 1, 2.22% Advanced Energy Materials 1 publication, 2.22%
ChemSusChem	ChemSusChem, 1, 2.22% ChemSusChem 1 publication, 2.22%
Chemical Reviews	Chemical Reviews, 1, 2.22% Chemical Reviews 1 publication, 2.22%
Ceramics International	Ceramics International, 1, 2.22% Ceramics International 1 publication, 2.22%
The Materials Research Society Series	The Materials Research Society Series, 1, 2.22% The Materials Research Society Series 1 publication, 2.22%
Electrochimica Acta	Electrochimica Acta, 1, 2.22% Electrochimica Acta 1 publication, 2.22%
Advanced Science	Advanced Science, 1, 2.22% Advanced Science 1 publication, 2.22%
Journal of Electroanalytical Chemistry	Journal of Electroanalytical Chemistry, 1, 2.22% Journal of Electroanalytical Chemistry 1 publication, 2.22%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 2.22% Russian Chemical Reviews 1 publication, 2.22%
	1 2 3 4

Citations by publishers

	5 10 15 20
Elsevier	Elsevier, 20, 44.44% Elsevier 20 publications, 44.44%
Wiley	Wiley, 9, 20% Wiley 9 publications, 20%
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 15.56% American Chemical Society (ACS) 7 publications, 15.56%
Springer Nature	Springer Nature, 3, 6.67% Springer Nature 3 publications, 6.67%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 3, 6.67% Multidisciplinary Digital Publishing Institute (MDPI) 3 publications, 6.67%
Nonferrous Metals Society of China	Nonferrous Metals Society of China, 1, 2.22% Nonferrous Metals Society of China 1 publication, 2.22%
Tsinghua University Press	Tsinghua University Press, 1, 2.22% Tsinghua University Press 1 publication, 2.22%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.22% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.22%
	5 10 15 20

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Jin Y. et al. Interface regulation enabling three-dimensional Li1.3Al0.3Ti1.7(PO4)3-reinforced composite solid electrolyte for high-performance lithium batteries // Journal of Power Sources. 2021. Vol. 501. p. 230027.

GOST all authors (up to 50) Copy

Jin Y., Zong X., Zhang X., Liu C., Li D., Jia Z., Gen Li G. L., Zhou X., Wei J., Xiong Y. Interface regulation enabling three-dimensional Li1.3Al0.3Ti1.7(PO4)3-reinforced composite solid electrolyte for high-performance lithium batteries // Journal of Power Sources. 2021. Vol. 501. p. 230027.

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2021.230027

UR - https://doi.org/10.1016/j.jpowsour.2021.230027

TI - Interface regulation enabling three-dimensional Li1.3Al0.3Ti1.7(PO4)3-reinforced composite solid electrolyte for high-performance lithium batteries

T2 - Journal of Power Sources

AU - Jin, Yingmin

AU - Zong, Xin

AU - Zhang, Xuebai

AU - Liu, Chaojun

AU - Li, Dong

AU - Jia, Zhenggang

AU - Gen Li, Gen Li

AU - Zhou, Xuanguang

AU - Wei, Junhua

AU - Xiong, Yueping

PY - 2021

DA - 2021/07/01 00:00:00

PB - Elsevier

SP - 230027

VL - 501

SN - 0378-7753

ER -

BibTex

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BibTex Copy

@article{2021_Jin,

author = {Yingmin Jin and Xin Zong and Xuebai Zhang and Chaojun Liu and Dong Li and Zhenggang Jia and Gen Li Gen Li and Xuanguang Zhou and Junhua Wei and Yueping Xiong},

title = {Interface regulation enabling three-dimensional Li1.3Al0.3Ti1.7(PO4)3-reinforced composite solid electrolyte for high-performance lithium batteries},

journal = {Journal of Power Sources},

year = {2021},

volume = {501},

publisher = {Elsevier},

month = {jul},

url = {https://doi.org/10.1016/j.jpowsour.2021.230027},

pages = {230027},

doi = {10.1016/j.jpowsour.2021.230027}

}

Found error?

Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)