Journal of Power Sources, volume 516, pages 230686

Fluorine-containing triblock copolymers as solid-state polymer electrolytes for lithium metal batteries

Yuxue Sun ¹

Xiaorong Zhang ¹

Chun-hui Ma ¹

Nan Guo ¹

Yulong Liu ¹

Jun Liu ¹

Haiming Xie ¹

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National and Local United Engineering Laboratory for Power Battery Department of Chemistry Northeast Normal University Changchun 130024 China |

Publication type: Journal Article

Publication date: 2021-12-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2021.230686

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Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Block copolymer electrolytes (BCPEs) are promising candidates for solid-state lithium battery applications because they can achieve improved mechanical performance and conductivity simultaneously. In this report, we report on fluorine-containing ABA triblock copolymer electrolytes (FBCPEs) with A blocks of perfluoroalkyl pendants and B blocks of poly(ethylene oxide) (PEO). It is found that fluorine-containing blocks endows considerable mechanical strength, high lithium ion transference number of t Li+ = 0.41, and wide electrochemical stability window up to 4.9 V to FBCPEs. In addition, FBCPEs can also participate in forming fluorinated solid electrolyte interphase (SEI), and thus serves to enhance the cycle stability of batteries. Combination of these excellent properties leads to the LiFePO 4 /FBCPEs/Li cells with excellent cycling performance and rate capability. The cycle results of the assembled LiNi 0.6 Co 0.2 Mn 0.2 O 2 /FBCPEs/Li cells indicate that FBCPEs have potential for application in high-voltage battery systems. • Solid-state fluorine-containing triblock copolymer electrolytes were developed. • High lithium ion transference number and wide electrochemical stability window. • LiFePO 4 cells assembled with FBCPEs exhibit excellent cycling performances.

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Citations by journals

	1 2 3 4
Chemical Engineering Journal	Chemical Engineering Journal, 4, 11.43% Chemical Engineering Journal 4 publications, 11.43%
Advanced Energy Materials	Advanced Energy Materials, 3, 8.57% Advanced Energy Materials 3 publications, 8.57%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 2, 5.71% Journal of Solid State Electrochemistry 2 publications, 5.71%
Materials	Materials, 1, 2.86% Materials 1 publication, 2.86%
Solid State Ionics	Solid State Ionics, 1, 2.86% Solid State Ionics 1 publication, 2.86%
Sustainable Materials and Technologies	Sustainable Materials and Technologies, 1, 2.86% Sustainable Materials and Technologies 1 publication, 2.86%
Small Structures	Small Structures, 1, 2.86% Small Structures 1 publication, 2.86%
ChemSusChem	ChemSusChem, 1, 2.86% ChemSusChem 1 publication, 2.86%
Advanced Engineering Materials	Advanced Engineering Materials, 1, 2.86% Advanced Engineering Materials 1 publication, 2.86%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 1, 2.86% Materials Chemistry Frontiers 1 publication, 2.86%
Batteries	Batteries, 1, 2.86% Batteries 1 publication, 2.86%
Progress in Polymer Science	Progress in Polymer Science, 1, 2.86% Progress in Polymer Science 1 publication, 2.86%
Energy Storage Materials	Energy Storage Materials, 1, 2.86% Energy Storage Materials 1 publication, 2.86%
Journal of Power Sources	Journal of Power Sources, 1, 2.86% Journal of Power Sources 1 publication, 2.86%
Nature Reviews Materials	Nature Reviews Materials, 1, 2.86% Nature Reviews Materials 1 publication, 2.86%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 2.86% Journal of Colloid and Interface Science 1 publication, 2.86%
Small	Small, 1, 2.86% Small 1 publication, 2.86%
Chemical Reviews	Chemical Reviews, 1, 2.86% Chemical Reviews 1 publication, 2.86%
Nanoscale	Nanoscale, 1, 2.86% Nanoscale 1 publication, 2.86%
Industrial & Engineering Chemistry Research	Industrial & Engineering Chemistry Research, 1, 2.86% Industrial & Engineering Chemistry Research 1 publication, 2.86%
Advanced Functional Materials	Advanced Functional Materials, 1, 2.86% Advanced Functional Materials 1 publication, 2.86%
Chemistry of Materials	Chemistry of Materials, 1, 2.86% Chemistry of Materials 1 publication, 2.86%
Polymer Bulletin	Polymer Bulletin, 1, 2.86% Polymer Bulletin 1 publication, 2.86%
Soft Matter	Soft Matter, 1, 2.86% Soft Matter 1 publication, 2.86%
SusMat	SusMat, 1, 2.86% SusMat 1 publication, 2.86%
European Polymer Journal	European Polymer Journal, 1, 2.86% European Polymer Journal 1 publication, 2.86%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 2.86% Russian Chemical Reviews 1 publication, 2.86%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 2.86% ACS applied materials & interfaces 1 publication, 2.86%
Energy & Fuels	Energy & Fuels, 1, 2.86% Energy & Fuels 1 publication, 2.86%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12
Elsevier	Elsevier, 11, 31.43% Elsevier 11 publications, 31.43%
Wiley	Wiley, 9, 25.71% Wiley 9 publications, 25.71%
American Chemical Society (ACS)	American Chemical Society (ACS), 5, 14.29% American Chemical Society (ACS) 5 publications, 14.29%
Springer Nature	Springer Nature, 4, 11.43% Springer Nature 4 publications, 11.43%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 8.57% Royal Society of Chemistry (RSC) 3 publications, 8.57%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 5.71% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 5.71%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.86% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.86%
	2 4 6 8 10 12

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Sun Y. et al. Fluorine-containing triblock copolymers as solid-state polymer electrolytes for lithium metal batteries // Journal of Power Sources. 2021. Vol. 516. p. 230686.

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Sun Y., Zhang X., Ma C., Guo N., Liu Y., Liu J., Xie H. Fluorine-containing triblock copolymers as solid-state polymer electrolytes for lithium metal batteries // Journal of Power Sources. 2021. Vol. 516. p. 230686.

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2021.230686

UR - https://doi.org/10.1016/j.jpowsour.2021.230686

TI - Fluorine-containing triblock copolymers as solid-state polymer electrolytes for lithium metal batteries

T2 - Journal of Power Sources

AU - Sun, Yuxue

AU - Zhang, Xiaorong

AU - Ma, Chun-hui

AU - Guo, Nan

AU - Liu, Yulong

AU - Liu, Jun

AU - Xie, Haiming

PY - 2021

DA - 2021/12/01 00:00:00

PB - Elsevier

SP - 230686

VL - 516

SN - 0378-7753

ER -

BibTex

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BibTex Copy

@article{2021_Sun,

author = {Yuxue Sun and Xiaorong Zhang and Chun-hui Ma and Nan Guo and Yulong Liu and Jun Liu and Haiming Xie},

title = {Fluorine-containing triblock copolymers as solid-state polymer electrolytes for lithium metal batteries},

journal = {Journal of Power Sources},

year = {2021},

volume = {516},

publisher = {Elsevier},

month = {dec},

url = {https://doi.org/10.1016/j.jpowsour.2021.230686},

pages = {230686},

doi = {10.1016/j.jpowsour.2021.230686}

}

Found error?

Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)