Journal of Power Sources, volume 518, pages 230739

In situ modified sulfide solid electrolyte enabling stable lithium metal batteries

Jianwei Li ¹

Yuanyuan Li ²

Jun Cheng ²

Qing Sun ¹

Linna Dai ¹

Naixuan Ci ¹

Lijie Ci ³

Hide authors affiliations Show authors affiliations: 3 affiliations

Key Laboratory for Liquid‐Solid Structural Evolution & Processing of Materials (Ministry of Education) Research Center for Carbon Nanomaterials School of Materials Science and Engineering Shandong University Jinan 250061 China |

State Key Laboratory of Advanced Welding and Joining, School of Materials Science and Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, China |

Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), Research Center for Carbon Nanomaterials, School of Materials Science and Engineering, Shandong University, Jinan, 250061, China |

Publication type: Journal Article

Publication date: 2022-01-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2021.230739

Copy DOI

Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

With the advantages of high ionic conductivity and wide electrochemical window, sulfide-based solid electrolyte becomes a current research hotspot of all-solid-state lithium batteries. Nevertheless, severe interfacial problem between the sulfide electrolyte and lithium metal remains a great challenge, which can render a high interfacial resistance and hinder the transfer of lithium ions through interface, ultimately degrading the cycling performance. Furthermore, lithium dendrites easily form inside the electrolyte, thus accelerating the dendrite-induced shorting behavior of the battery. In this work, Li 2 S layer is in-situ coated on the surface of the sulfide solid electrolyte Li 7 P 3 S 11 for highly stable lithium metal battery. The Li 2 S layer can effectively prevent Li 7 P 3 S 11 from reacting with lithium metal. Meanwhile, the incorporation of the lithium sulfide can inhibit the generation and growth of internal lithium dendrites, thereby improving the cycling stability. The all-solid-state batteries based on the new designed electrolyte exhibit remarkably enhanced cycling stability. This work provides a simple and effective strategy to suppress lithium dendrite and promotes the practical application of sulfide-based all-solid-state batteries. • A hybrid solid electrolyte of Li 2 S coated Li 7 P 3 S 11 is synthetized via a facile method. • The increased ionic conductivity and enhanced compatibility against lithium are achieved. • The symmetrical cell based on Li 2 S@LPS can be stably charge/discharged for 400 h. • All solid-state batteries show superior electrochemical performance.

By date By citations

Top-30

Citations by journals

	1 2 3
Small	Small, 3, 10% Small 3 publications, 10%
Journal of Power Sources	Journal of Power Sources, 2, 6.67% Journal of Power Sources 2 publications, 6.67%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 2, 6.67% Journal of Alloys and Compounds 2 publications, 6.67%
Chemical Engineering Journal	Chemical Engineering Journal, 2, 6.67% Chemical Engineering Journal 2 publications, 6.67%
Energy & Environmental Materials	Energy & Environmental Materials, 2, 6.67% Energy & Environmental Materials 2 publications, 6.67%
Advanced Science	Advanced Science, 2, 6.67% Advanced Science 2 publications, 6.67%
eTransportation	eTransportation, 1, 3.33% eTransportation 1 publication, 3.33%
Energy Storage Materials	Energy Storage Materials, 1, 3.33% Energy Storage Materials 1 publication, 3.33%
Materials Chemistry and Physics	Materials Chemistry and Physics, 1, 3.33% Materials Chemistry and Physics 1 publication, 3.33%
Energy Technology	Energy Technology, 1, 3.33% Energy Technology 1 publication, 3.33%
ACS Energy Letters	ACS Energy Letters, 1, 3.33% ACS Energy Letters 1 publication, 3.33%
EcoMat	EcoMat, 1, 3.33% EcoMat 1 publication, 3.33%
Energy Storage	Energy Storage, 1, 3.33% Energy Storage 1 publication, 3.33%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 3.33% ACS applied materials & interfaces 1 publication, 3.33%
Progress in Materials Science	Progress in Materials Science, 1, 3.33% Progress in Materials Science 1 publication, 3.33%
Advanced Materials	Advanced Materials, 1, 3.33% Advanced Materials 1 publication, 3.33%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 1, 3.33% Materials Chemistry Frontiers 1 publication, 3.33%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 3.33% Electrochemical Energy Reviews 1 publication, 3.33%
Science China Chemistry	Science China Chemistry, 1, 3.33% Science China Chemistry 1 publication, 3.33%
Journal of Energy Storage	Journal of Energy Storage, 1, 3.33% Journal of Energy Storage 1 publication, 3.33%
ECS Journal of Solid State Science and Technology	ECS Journal of Solid State Science and Technology, 1, 3.33% ECS Journal of Solid State Science and Technology 1 publication, 3.33%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 3.33% Russian Chemical Reviews 1 publication, 3.33%
	1 2 3

Citations by publishers

	2 4 6 8 10 12
Elsevier	Elsevier, 11, 36.67% Elsevier 11 publications, 36.67%
Wiley	Wiley, 11, 36.67% Wiley 11 publications, 36.67%
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 6.67% American Chemical Society (ACS) 2 publications, 6.67%
Springer Nature	Springer Nature, 2, 6.67% Springer Nature 2 publications, 6.67%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 3.33% Royal Society of Chemistry (RSC) 1 publication, 3.33%
The Electrochemical Society	The Electrochemical Society, 1, 3.33% The Electrochemical Society 1 publication, 3.33%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.33% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.33%
	2 4 6 8 10 12

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

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Li J. et al. In situ modified sulfide solid electrolyte enabling stable lithium metal batteries // Journal of Power Sources. 2022. Vol. 518. p. 230739.

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Li J., Li Y., Cheng J., Sun Q., Dai L., Ci N., Ci L. In situ modified sulfide solid electrolyte enabling stable lithium metal batteries // Journal of Power Sources. 2022. Vol. 518. p. 230739.

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2021.230739

UR - https://doi.org/10.1016/j.jpowsour.2021.230739

TI - In situ modified sulfide solid electrolyte enabling stable lithium metal batteries

T2 - Journal of Power Sources

AU - Li, Jianwei

AU - Li, Yuanyuan

AU - Cheng, Jun

AU - Sun, Qing

AU - Dai, Linna

AU - Ci, Naixuan

AU - Ci, Lijie

PY - 2022

DA - 2022/01/01 00:00:00

PB - Elsevier

SP - 230739

VL - 518

SN - 0378-7753

ER -

BibTex

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BibTex Copy

@article{2022_Li,

author = {Jianwei Li and Yuanyuan Li and Jun Cheng and Qing Sun and Linna Dai and Naixuan Ci and Lijie Ci},

title = {In situ modified sulfide solid electrolyte enabling stable lithium metal batteries},

journal = {Journal of Power Sources},

year = {2022},

volume = {518},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.jpowsour.2021.230739},

pages = {230739},

doi = {10.1016/j.jpowsour.2021.230739}

}

Found error?

Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)