Open Access
Journal of Science: Advanced Materials and Devices, volume 3, issue 1, pages 1-17
A conceptual review on polymer electrolytes and ion transport models
3
Publication type: Journal Article
Publication date: 2018-03-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8
ISSN: 24682284, 24682179, 24682179
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Materials Science (miscellaneous)
Biomaterials
Abstract
This review article provides a deep insight into the ion conduction mechanism in polymer electrolytes (PEs). The concepts of different categories of polymer electrolytes are discussed. The significance of the existence of functional (polar) groups on the backbone of host polymers, which are used in polymer electrolytes, is well explained. The working principle of electrical impedance spectroscopy (EIS) is overviewed. The relationship between impedance plots and equivalent circuits, which are crucial for electrical characterization, is extensively interpreted. Based on the patterns of dc conductivity (σdc) versus 1000/T, the ion transport models of Arrhenius and Vogel–Tammann–Fulcher (VTF) are discussed. Effects of coupling and decoupling between ionic motion and polymer segmental relaxation are analyzed. The important role of dielectric constant on cationic transport in PEs is also explained. The relationships existing between electrical and dielectric parameters are elucidated, which help interpret and understand the ion conduction mechanism. From the reported empirical curves of dc conductivity vs. dielectric constant, the reformulated Arrhenius [ σ d c ( T ) = σ 0 exp ( − E a k B T e ′ ) ] equation is proposed. Finally, other important phenomena, occurring in polymer electrolytes, are shown to be understandable from the dielectric constant studies.
Top-30
Citations by journals
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Electrochimica Acta
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ACS Omega
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High Performance Polymers
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5 publications, 1.21%
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Advanced Functional Materials
5 publications, 1.21%
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Chemical Reviews
5 publications, 1.21%
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Nanomaterials
4 publications, 0.97%
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4 publications, 0.97%
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Scientific Reports
4 publications, 0.97%
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4 publications, 0.97%
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Journal of Molecular Liquids
4 publications, 0.97%
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Advanced Science
3 publications, 0.72%
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Citations by publishers
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120
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Elsevier
114 publications, 27.54%
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Multidisciplinary Digital Publishing Institute (MDPI)
66 publications, 15.94%
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American Chemical Society (ACS)
60 publications, 14.49%
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Springer Nature
47 publications, 11.35%
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Wiley
44 publications, 10.63%
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IOP Publishing
13 publications, 3.14%
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The Electrochemical Society
11 publications, 2.66%
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Taylor & Francis
10 publications, 2.42%
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SAGE
6 publications, 1.45%
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Royal Society of Chemistry (RSC)
6 publications, 1.45%
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American Institute of Physics (AIP)
5 publications, 1.21%
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Trans Tech Publications
4 publications, 0.97%
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Frontiers Media S.A.
3 publications, 0.72%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 0.48%
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Thomas Telford
2 publications, 0.48%
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OAE Publishing Inc.
2 publications, 0.48%
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Bentham Science
1 publication, 0.24%
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IEEE
1 publication, 0.24%
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Shanghai Institute of Ceramics
1 publication, 0.24%
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Chinese Physical Society
1 publication, 0.24%
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American Institute of Mathematical Sciences (AIMS)
1 publication, 0.24%
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Annual Reviews
1 publication, 0.24%
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Asian Journal of Chemistry
1 publication, 0.24%
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ITMO University
1 publication, 0.24%
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Oriental Scientific Publishing Company
1 publication, 0.24%
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Alexandria University
1 publication, 0.24%
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Korean Society of Industrial Engineering Chemistry
1 publication, 0.24%
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120
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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AZIZ S. B. et al. A conceptual review on polymer electrolytes and ion transport models // Journal of Science: Advanced Materials and Devices. 2018. Vol. 3. No. 1. pp. 1-17.
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AZIZ S. B., Woo T. J., Kadir M. F. Z., Ahmed H. M. A conceptual review on polymer electrolytes and ion transport models // Journal of Science: Advanced Materials and Devices. 2018. Vol. 3. No. 1. pp. 1-17.
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TY - JOUR
DO - 10.1016/j.jsamd.2018.01.002
UR - https://doi.org/10.1016/j.jsamd.2018.01.002
TI - A conceptual review on polymer electrolytes and ion transport models
T2 - Journal of Science: Advanced Materials and Devices
AU - AZIZ, Shujahadeen B.
AU - Woo, Thompson J
AU - Kadir, M F Z
AU - Ahmed, Hameed M
PY - 2018
DA - 2018/03/01 00:00:00
PB - Elsevier
SP - 1-17
IS - 1
VL - 3
SN - 2468-2284
SN - 2468-2179
SN - 2468-2179
ER -
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@article{2018_AZIZ,
author = {Shujahadeen B. AZIZ and Thompson J Woo and M F Z Kadir and Hameed M Ahmed},
title = {A conceptual review on polymer electrolytes and ion transport models},
journal = {Journal of Science: Advanced Materials and Devices},
year = {2018},
volume = {3},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.jsamd.2018.01.002},
number = {1},
pages = {1--17},
doi = {10.1016/j.jsamd.2018.01.002}
}
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AZIZ, Shujahadeen B., et al. “A conceptual review on polymer electrolytes and ion transport models.” Journal of Science: Advanced Materials and Devices, vol. 3, no. 1, Mar. 2018, pp. 1-17. https://doi.org/10.1016/j.jsamd.2018.01.002.