Open Access
Open access
volume 25 issue 10 pages 101326

Removal of pesticide chlorobenzene by anodic degradation: Variable effects and mechanism

Publication typeJournal Article
Publication date2021-10-01
scimago Q1
wos Q1
SJR0.939
CiteScore10.0
Impact factor5.8
ISSN13196103, 22124640
General Chemistry
Abstract
The oxidation of chlorobenzene (CB) was studied by electrochemical electrolysis using boron-doped diamond (BDD), PbO 2 or platine (Pt) as anode and graphite bar as cathode. The effect of applied current density, supporting electrolyte and initial pH value were also studied. The results demonstrated that BDD anode had the best effectiveness and accomplishment of electrochemical degradation of CB compared to PbO 2 and Pt anodes. For a current density of 20 mA/cm 2 and at pH = 3, the elimination of COD and TOC were about 97% and 98%, respectively, after 360 min of electrolysis with the BDD anode. Pseudo-first order kinetics appears to be the most appropriate to describe the degradation of chlorobenzene. The electrochemical mechanism of chlorobenzene on BDD was proposed based on the identified intermediates.
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GOST |
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GOST Copy
Ouni A. et al. Removal of pesticide chlorobenzene by anodic degradation: Variable effects and mechanism // Journal of Saudi Chemical Society. 2021. Vol. 25. No. 10. p. 101326.
GOST all authors (up to 50) Copy
Ouni A., Rabaaoui N., Mechi L., Enaceur N., Alsukaibi A. K. D., Azzam E., Alenezi K. M., Moussaoui Y. Removal of pesticide chlorobenzene by anodic degradation: Variable effects and mechanism // Journal of Saudi Chemical Society. 2021. Vol. 25. No. 10. p. 101326.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.jscs.2021.101326
UR - https://doi.org/10.1016/j.jscs.2021.101326
TI - Removal of pesticide chlorobenzene by anodic degradation: Variable effects and mechanism
T2 - Journal of Saudi Chemical Society
AU - Ouni, Amel
AU - Rabaaoui, Nejmeddine
AU - Mechi, Lassaad
AU - Enaceur, Nasreddine
AU - Alsukaibi, Abdulmohsen K D
AU - Azzam, E.M.S.
AU - Alenezi, Khalaf M
AU - Moussaoui, Y.
PY - 2021
DA - 2021/10/01
PB - King Saud University
SP - 101326
IS - 10
VL - 25
SN - 1319-6103
SN - 2212-4640
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Ouni,
author = {Amel Ouni and Nejmeddine Rabaaoui and Lassaad Mechi and Nasreddine Enaceur and Abdulmohsen K D Alsukaibi and E.M.S. Azzam and Khalaf M Alenezi and Y. Moussaoui},
title = {Removal of pesticide chlorobenzene by anodic degradation: Variable effects and mechanism},
journal = {Journal of Saudi Chemical Society},
year = {2021},
volume = {25},
publisher = {King Saud University},
month = {oct},
url = {https://doi.org/10.1016/j.jscs.2021.101326},
number = {10},
pages = {101326},
doi = {10.1016/j.jscs.2021.101326}
}
MLA
Cite this
MLA Copy
Ouni, Amel, et al. “Removal of pesticide chlorobenzene by anodic degradation: Variable effects and mechanism.” Journal of Saudi Chemical Society, vol. 25, no. 10, Oct. 2021, p. 101326. https://doi.org/10.1016/j.jscs.2021.101326.