The disordered cubic structure of Ca7 Co3 Ga 5 O18
Publication type: Journal Article
Publication date: 2005-07-01
scimago Q2
wos Q1
SJR: 0.629
CiteScore: 6.8
Impact factor: 3.5
ISSN: 00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
The new mixed oxide having composition close to Ca{sub 7}Co{sub 3}Ga{sub 5}O{sub 18} was synthesized from CaCO{sub 3}, Co{sub 3}O{sub 4} and Ga{sub 2}O{sub 3} at 1150{sup o}C in air and studied by neutron and synchrotron X-ray powder diffraction, selected-area electron diffraction and high-resolution electron microscopy. The structure was refined, using time-of-flight (TOF) neutron powder diffraction data, in space group F432, with a=15.0487(4)A and Z=8, to R{sub F}=0.7%. It is considerably disordered, with four different tetrahedral sites randomly occupied by Co and Ga atoms at a ratio of 1:2. The tetrahedra form a disordered (Co{sub 1/3}Ga{sub 2/3})O{sub 2} 3D-framework inside which isolated CoO{sub 6} octahedra, surrounded by 8 Ca atoms, are located. The structure is related to the ordered structure of Ca{sub 14}Al{sub 10}Zn{sub 6}O{sub 35}. Electron diffraction patterns confirmed the symmetry and unit cell and revealed no diffuse scattering. High-resolution electron microscopy images showed the absence of extended structural defects.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Journal of Solid State Chemistry
2 publications, 18.18%
|
|
|
Russian Chemical Bulletin
1 publication, 9.09%
|
|
|
Mineralogy and Petrology
1 publication, 9.09%
|
|
|
Physical Chemistry Chemical Physics
1 publication, 9.09%
|
|
|
Dalton Transactions
1 publication, 9.09%
|
|
|
Journal of Structural Chemistry
1 publication, 9.09%
|
|
|
Russian Journal of Applied Chemistry
1 publication, 9.09%
|
|
|
Zeitschrift fur Kristallographie - Crystalline Materials
1 publication, 9.09%
|
|
|
Chemistry of Materials
1 publication, 9.09%
|
|
|
RSC Advances
1 publication, 9.09%
|
|
|
1
2
|
Publishers
|
1
2
3
|
|
|
Royal Society of Chemistry (RSC)
3 publications, 27.27%
|
|
|
Springer Nature
2 publications, 18.18%
|
|
|
Elsevier
2 publications, 18.18%
|
|
|
Pleiades Publishing
2 publications, 18.18%
|
|
|
Walter de Gruyter
1 publication, 9.09%
|
|
|
American Chemical Society (ACS)
1 publication, 9.09%
|
|
|
1
2
3
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
11
Total citations:
11
Citations from 2024:
2
(18%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Grins J. et al. The disordered cubic structure of Ca7Co3Ga 5O18 // Journal of Solid State Chemistry. 2005. Vol. 178. No. 7. pp. 2197-2204.
GOST all authors (up to 50)
Copy
Grins J., Istomin S. Y., Svensson G., Attfield J. P., Antipov E. V. The disordered cubic structure of Ca7Co3Ga 5O18 // Journal of Solid State Chemistry. 2005. Vol. 178. No. 7. pp. 2197-2204.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jssc.2005.04.029
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022459605001532
TI - The disordered cubic structure of Ca7Co3Ga 5O18
T2 - Journal of Solid State Chemistry
AU - Grins, J.
AU - Istomin, Sergey Ya.
AU - Svensson, Gunnar
AU - Attfield, J. Paul
AU - Antipov, Evgeny V.
PY - 2005
DA - 2005/07/01
PB - Elsevier
SP - 2197-2204
IS - 7
VL - 178
SN - 0022-4596
SN - 1095-726X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2005_Grins,
author = {J. Grins and Sergey Ya. Istomin and Gunnar Svensson and J. Paul Attfield and Evgeny V. Antipov},
title = {The disordered cubic structure of Ca7Co3Ga 5O18},
journal = {Journal of Solid State Chemistry},
year = {2005},
volume = {178},
publisher = {Elsevier},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022459605001532},
number = {7},
pages = {2197--2204},
doi = {10.1016/j.jssc.2005.04.029}
}
Cite this
MLA
Copy
Grins, J., et al. “The disordered cubic structure of Ca7Co3Ga 5O18.” Journal of Solid State Chemistry, vol. 178, no. 7, Jul. 2005, pp. 2197-2204. https://linkinghub.elsevier.com/retrieve/pii/S0022459605001532.
Profiles