Journal of Solid State Chemistry

, том 183 , издание 5 , страницы 1186-1193

Synthesis and crystal structure of Ln2M2+Ge4O12, Ln=rare-earth element or Y; M=Ca, Mn, Zn

Тип публикации: Journal Article

Дата публикации: 2010-05-01

Elsevier

Journal of Solid State Chemistry

scimago Q2

wos Q1

БС2

SJR: 0.629

CiteScore: 6.8

Impact factor: 3.5

ISSN: 00224596, 1095726X

DOI: 10.1016/j.jssc.2010.03.027

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Materials Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Inorganic Chemistry

Physical and Theoretical Chemistry

Condensed Matter Physics

Краткое описание

The crystal structure of the promising optical materials Ln{sub 2}M{sup 2+}Ge{sub 4}O{sub 12}, where Ln=rare-earth element or Y; M=Ca, Mn, Zn and their solid solutions has been studied in detail. The tendency of rare-earth elements to occupy six- or eight-coordinated sites upon iso- and heterovalent substitution has been studied for the Y{sub 2-x}Er{sub x}CaGe{sub 4}O{sub 12} (x=0-2), Y{sub 2-2x}Ce{sub x}Ca{sub 1+x}Ge{sub 4}O{sub 12} (x=0-1), Y{sub 2}Ca{sub 1-x}Mn{sub x}Ge{sub 4}O{sub 12} (x=0-1) and Y{sub 2-x}Pr{sub x}MnGe{sub 4}O{sub 12} (x=0-0.5) solid solutions. A complex heterovalent state of Eu and Mn in Eu{sub 2}MnGe{sub 4}O{sub 12} has been found. - Graphical abstract: Crystal structure of Ln{sub 2}MGe{sub 4}O{sub 12}, where Ln=rare-earth element or Y; M=Ca, Mn, Zn.

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Zubkov V. et al. Synthesis and crystal structure of Ln2M2+Ge4O12, Ln=rare-earth element or Y; M=Ca, Mn, Zn // Journal of Solid State Chemistry. 2010. Vol. 183. No. 5. pp. 1186-1193.

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Zubkov V., Tarakina N. V., Leonidov I. I., Tyutyunnik A. P., Surat L. L., Melkozerova M. A., Zabolotskaya E. V., Kellerman D. Synthesis and crystal structure of Ln2M2+Ge4O12, Ln=rare-earth element or Y; M=Ca, Mn, Zn // Journal of Solid State Chemistry. 2010. Vol. 183. No. 5. pp. 1186-1193.

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TY - JOUR

DO - 10.1016/j.jssc.2010.03.027

UR - https://doi.org/10.1016/j.jssc.2010.03.027

TI - Synthesis and crystal structure of Ln2M2+Ge4O12, Ln=rare-earth element or Y; M=Ca, Mn, Zn

T2 - Journal of Solid State Chemistry

AU - Zubkov, Vladimir

AU - Tarakina, Nadezda V

AU - Leonidov, Ivan I.

AU - Tyutyunnik, A. P.

AU - Surat, Ludmila L

AU - Melkozerova, Marina A

AU - Zabolotskaya, Elena V

AU - Kellerman, Dina

PY - 2010

DA - 2010/05/01

PB - Elsevier

SP - 1186-1193

IS - 5

VL - 183

SN - 0022-4596

SN - 1095-726X

ER -

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@article{2010_Zubkov,

author = {Vladimir Zubkov and Nadezda V Tarakina and Ivan I. Leonidov and A. P. Tyutyunnik and Ludmila L Surat and Marina A Melkozerova and Elena V Zabolotskaya and Dina Kellerman},

title = {Synthesis and crystal structure of Ln2M2+Ge4O12, Ln=rare-earth element or Y; M=Ca, Mn, Zn},

journal = {Journal of Solid State Chemistry},

year = {2010},

volume = {183},

publisher = {Elsevier},

month = {may},

url = {https://doi.org/10.1016/j.jssc.2010.03.027},

number = {5},

pages = {1186--1193},

doi = {10.1016/j.jssc.2010.03.027}

}

MLA

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MLA Скопировать

Zubkov, Vladimir, et al. “Synthesis and crystal structure of Ln2M2+Ge4O12, Ln=rare-earth element or Y; M=Ca, Mn, Zn.” Journal of Solid State Chemistry, vol. 183, no. 5, May. 2010, pp. 1186-1193. https://doi.org/10.1016/j.jssc.2010.03.027.

Издатель

Elsevier

Журнал

Journal of Solid State Chemistry

scimago Q2

wos Q1

БС2

SJR

0.629

CiteScore

6.8

Impact factor

3.5

ISSN

00224596 (Print)

1095726X (Electronic)