Pb5Fe3TiO11Cl: A rare example of Ti(IV) in a square pyramidal oxygen coordination
Publication type: Journal Article
Publication date: 2014-07-01
scimago Q2
wos Q1
SJR: 0.629
CiteScore: 6.8
Impact factor: 3.5
ISSN: 00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
Abstract A new oxychloride Pb5Fe3TiO11Cl has been synthesized using the solid state method. Its crystal and magnetic structure was investigated in the 1.5–550 K temperature range using electron diffraction, high angle annular dark field scanning transmission electron microscopy, atomic resolution energy dispersive X-ray spectroscopy, neutron and X-ray powder diffraction. At room temperature Pb5Fe3TiO11Cl crystallizes in the P4/mmm space group with the unit cell parameters a=3.91803(3) A and c=19.3345(2) A. Pb5Fe3TiO11Cl is a new n=4 member of the oxychloride perovskite-based homologous series An+1BnO3n−1Cl. The structure is built of truncated Pb3Fe3TiO11 quadruple perovskite blocks separated by CsCl-type Pb2Cl slabs. The perovskite blocks consist of two layers of (Fe,Ti)O6 octahedra sandwiched between two layers of (Fe,Ti)O5 square pyramids. The Ti4+ cations are preferentially located in the octahedral layers, however, the presence of a noticeable amount of Ti4+ in a five-fold coordination environment has been undoubtedly proven using neutron powder diffraction and atomic resolution compositional mapping. Pb5Fe3TiO11Cl is antiferromagnetically ordered below 450(10) K. The ordered Fe magnetic moments at 1.5 K are 4.06(4) μB and 3.86(5) μB on the octahedral and square-pyramidal sites, respectively.
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Batuk M. et al. Pb5Fe3TiO11Cl: A rare example of Ti(IV) in a square pyramidal oxygen coordination // Journal of Solid State Chemistry. 2014. Vol. 215. pp. 245-252.
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Batuk M., Batuk D., Abakumov A. M., Hadermann J. Pb5Fe3TiO11Cl: A rare example of Ti(IV) in a square pyramidal oxygen coordination // Journal of Solid State Chemistry. 2014. Vol. 215. pp. 245-252.
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TY - JOUR
DO - 10.1016/j.jssc.2014.04.002
UR - https://doi.org/10.1016/j.jssc.2014.04.002
TI - Pb5Fe3TiO11Cl: A rare example of Ti(IV) in a square pyramidal oxygen coordination
T2 - Journal of Solid State Chemistry
AU - Batuk, M.
AU - Batuk, Dmitry
AU - Abakumov, Artem M.
AU - Hadermann, Joke
PY - 2014
DA - 2014/07/01
PB - Elsevier
SP - 245-252
VL - 215
SN - 0022-4596
SN - 1095-726X
ER -
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@article{2014_Batuk,
author = {M. Batuk and Dmitry Batuk and Artem M. Abakumov and Joke Hadermann},
title = {Pb5Fe3TiO11Cl: A rare example of Ti(IV) in a square pyramidal oxygen coordination},
journal = {Journal of Solid State Chemistry},
year = {2014},
volume = {215},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.jssc.2014.04.002},
pages = {245--252},
doi = {10.1016/j.jssc.2014.04.002}
}
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