Five chiral Cd(II) complexes with dual chiral components: Effect of positional isomerism, luminescence and SHG response
Publication type: Journal Article
Publication date: 2015-01-01
scimago Q2
wos Q1
SJR: 0.629
CiteScore: 6.8
Impact factor: 3.5
ISSN: 00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
Five chiral Cd(II) complexes with dual chiral components have been synthesized by using a series of (1R,2R)–N{sup 1},N{sup 2}-bis(pyridinylmethyl)cyclohexane-1,2-diamine ligands with different N-positions of pyridyl rings and Cd(NO{sub 3}){sub 2}. The circular dichroism (CD) spectra and second-harmonic generation (SHG) efficiency measurements confirmed that they are of structural chirality in the bulk samples. The luminescent properties indicated that they may have potential applications as optical materials. The formation of discrete mononuclear and binuclear complexes, and one-dimensional chains may be attributed to positional isomerism of the ligands. - Graphical abstract: Five chiral Cd(II) complexes with dual chiral components have been synthesized by using a series of chiral ligands with different N-positions of pyridyl rings. - Highlights: • Five chiral Cd(II) complexes with dual chiral components have been synthesized. • CD spectra and SHG efficiency of the bulk samples have been measured. • The complexes display luminescent properties.
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Total citations:
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Citations from 2024:
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(10.53%)
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Cheng L. et al. Five chiral Cd(II) complexes with dual chiral components: Effect of positional isomerism, luminescence and SHG response // Journal of Solid State Chemistry. 2015. Vol. 221. pp. 85-94.
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Cheng L., Wang J., Hai-Yan Yu., Zhang X., Gou S., Fang L. Five chiral Cd(II) complexes with dual chiral components: Effect of positional isomerism, luminescence and SHG response // Journal of Solid State Chemistry. 2015. Vol. 221. pp. 85-94.
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TY - JOUR
DO - 10.1016/j.jssc.2014.09.020
UR - https://doi.org/10.1016/j.jssc.2014.09.020
TI - Five chiral Cd(II) complexes with dual chiral components: Effect of positional isomerism, luminescence and SHG response
T2 - Journal of Solid State Chemistry
AU - Cheng, Lin
AU - Wang, Jun
AU - Hai-Yan, Yu
AU - Zhang, Xiu-Ying
AU - Gou, Shaohua
AU - Fang, Lei
PY - 2015
DA - 2015/01/01
PB - Elsevier
SP - 85-94
VL - 221
SN - 0022-4596
SN - 1095-726X
ER -
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BibTex (up to 50 authors)
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@article{2015_Cheng,
author = {Lin Cheng and Jun Wang and Yu Hai-Yan and Xiu-Ying Zhang and Shaohua Gou and Lei Fang},
title = {Five chiral Cd(II) complexes with dual chiral components: Effect of positional isomerism, luminescence and SHG response},
journal = {Journal of Solid State Chemistry},
year = {2015},
volume = {221},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.jssc.2014.09.020},
pages = {85--94},
doi = {10.1016/j.jssc.2014.09.020}
}