Journal of Solid State Chemistry

, volume 225 , pages 97-104

New complex bismuth oxides in the Bi2O3-NiO-Sb2O5 system and their properties

Anna Egorysheva ¹

O.G Ellert ¹

Y V Zubavichus ²

O M Gajtko ¹

Nikolay N. Efimov ¹

Roman Svetogorov ²

V Yu Murzin ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr.31, Moscow 119991, Russia |

National Research Center “Kurchatov Institute”, Acad. Kurchatov Sq., 1, Moscow 123182, Russia |

Publication type: Journal Article

Publication date: 2015-05-01

Elsevier

Journal of Solid State Chemistry

scimago Q2

wos Q1

SJR: 0.629

CiteScore: 6.8

Impact factor: 3.5

ISSN: 00224596, 1095726X

DOI: 10.1016/j.jssc.2014.12.001

Copy DOI

Materials Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Inorganic Chemistry

Physical and Theoretical Chemistry

Condensed Matter Physics

Abstract

Phase equilibria in the Bi2O3–NiO–Sb2O5 system have been investigated. The isothermal section of the system (650°) has been constructed. For the first time the existence of the pyrochlore structure solid solution, (Bi2−xNix)Ni2/3−ySb4/3+yO7±δ, x=0.1−0.35, y=0−0.1, and a new compound Bi3Ni2/3Sb7/3O11 of KSbO3 structure type have been discovered. The structures and properties of these compounds were studied by XRD, XAFS, diffuse reflection spectroscopy and magnetic methods. Rietveld refinement of synchrotron radiation-based powder XRD data for pyrochlore sample of 38.43Bi2O3–33.0NiO–28.57Sb2O5 composition and Bi3Ni2/3Sb7/3O11 compound was performed. The best possible refinement of the positional parameters for both pyrochlore and Bi3Ni2/3Sb7/3O11 structures was achieved for disordered models. Magnetic, diffuse reflection and an X-ray absorption spectroscopy study confirmed that in both compounds nickel ions are mainly in a 2+ oxidation state. According to magnetic data, Bi1.84Ni0.16(Ni0.63Sb1.37)O7 pyrochlore and Bi3Ni2/3Sb7/3O11 are overall paramagnetic in nature.

Found

3 citations

Gajtko Olga

PhD in Chemistry

50 publications, 366 citations

h-index: 12

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

2 citations

Svetogorov Roman

🤝

PhD in Physics and Mathematics

144 publications, 1 292 citations, 37 reviews

h-index: 16

National Research Centre "Kurchatov Institute"

Research interests

Crystallography

X-ray structural methods

2 citations

Minnikova Tatiana

🥼 🤝

PhD in Biological/biomedical sciences

76 publications, 447 citations, 106 reviews

h-index: 12

Southern Federal University

Research interests

Heavy metals

Pollution

2 citations

Golodukhina Svetlana

PhD in Chemistry

38 publications, 167 citations

h-index: 7

Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry of the Russian Academy of Sciences

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Catalysis

Materials Science

1 citation

Razvorotneva Lada

11 publications, 17 citations

h-index: 3

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

National Research University Higher School of Economics

Research interests

Antibiotic resistance

Coordination Chemistry

Heterogeneous catalysis

Top-30

Journals

	1 2
Journal of Molecular Liquids	Journal of Molecular Liquids, 2, 11.11% Journal of Molecular Liquids 2 publications, 11.11%
Glass and Ceramics (English translation of Steklo i Keramika)	Glass and Ceramics (English translation of Steklo i Keramika), 2, 11.11% Glass and Ceramics (English translation of Steklo i Keramika) 2 publications, 11.11%
Journal of Magnetism and Magnetic Materials	Journal of Magnetism and Magnetic Materials, 1, 5.56% Journal of Magnetism and Magnetic Materials 1 publication, 5.56%
Journal of Solid State Chemistry	Journal of Solid State Chemistry, 1, 5.56% Journal of Solid State Chemistry 1 publication, 5.56%
Inorganic Chemistry	Inorganic Chemistry, 1, 5.56% Inorganic Chemistry 1 publication, 5.56%
E3S Web of Conferences	E3S Web of Conferences, 1, 5.56% E3S Web of Conferences 1 publication, 5.56%
Crystals	Crystals, 1, 5.56% Crystals 1 publication, 5.56%
Groundwater for Sustainable Development	Groundwater for Sustainable Development, 1, 5.56% Groundwater for Sustainable Development 1 publication, 5.56%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 5.56% Journal of Alloys and Compounds 1 publication, 5.56%
ChemInform	ChemInform, 1, 5.56% ChemInform 1 publication, 5.56%
Eurasian Journal of Soil Science	Eurasian Journal of Soil Science, 1, 5.56% Eurasian Journal of Soil Science 1 publication, 5.56%
Mendeleev Communications	Mendeleev Communications, 1, 5.56% Mendeleev Communications 1 publication, 5.56%
Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 1, 5.56% Russian Journal of Inorganic Chemistry 1 publication, 5.56%
Ceramics International	Ceramics International, 1, 5.56% Ceramics International 1 publication, 5.56%
Chemistry	Chemistry, 1, 5.56% Chemistry 1 publication, 5.56%
	1 2

Publishers

	1 2 3 4 5 6 7 8
Elsevier	Elsevier, 8, 44.44% Elsevier 8 publications, 44.44%
MDPI	MDPI, 2, 11.11% MDPI 2 publications, 11.11%
Springer Nature	Springer Nature, 2, 11.11% Springer Nature 2 publications, 11.11%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 5.56% American Chemical Society (ACS) 1 publication, 5.56%
EDP Sciences	EDP Sciences, 1, 5.56% EDP Sciences 1 publication, 5.56%
Wiley	Wiley, 1, 5.56% Wiley 1 publication, 5.56%
Eurasian Journal of Soil Sciences	Eurasian Journal of Soil Sciences, 1, 5.56% Eurasian Journal of Soil Sciences 1 publication, 5.56%
OOO Zhurnal "Mendeleevskie Soobshcheniya"	OOO Zhurnal "Mendeleevskie Soobshcheniya", 1, 5.56% OOO Zhurnal "Mendeleevskie Soobshcheniya" 1 publication, 5.56%
Pleiades Publishing	Pleiades Publishing, 1, 5.56% Pleiades Publishing 1 publication, 5.56%
	1 2 3 4 5 6 7 8

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Egorysheva A. et al. New complex bismuth oxides in the Bi2O3-NiO-Sb2O5 system and their properties // Journal of Solid State Chemistry. 2015. Vol. 225. pp. 97-104.

GOST all authors (up to 50) Copy

Egorysheva A., Ellert O., Zubavichus Y. V., Gajtko O. M., Efimov N. N., Svetogorov R., Murzin V. Yu. New complex bismuth oxides in the Bi2O3-NiO-Sb2O5 system and their properties // Journal of Solid State Chemistry. 2015. Vol. 225. pp. 97-104.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.jssc.2014.12.001

UR - https://doi.org/10.1016/j.jssc.2014.12.001

TI - New complex bismuth oxides in the Bi2O3-NiO-Sb2O5 system and their properties

T2 - Journal of Solid State Chemistry

AU - Egorysheva, Anna

AU - Ellert, O.G

AU - Zubavichus, Y V

AU - Gajtko, O M

AU - Efimov, Nikolay N.

AU - Svetogorov, Roman

AU - Murzin, V Yu

PY - 2015

DA - 2015/05/01

PB - Elsevier

SP - 97-104

VL - 225

SN - 0022-4596

SN - 1095-726X

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2015_Egorysheva,

author = {Anna Egorysheva and O.G Ellert and Y V Zubavichus and O M Gajtko and Nikolay N. Efimov and Roman Svetogorov and V Yu Murzin},

title = {New complex bismuth oxides in the Bi2O3-NiO-Sb2O5 system and their properties},

journal = {Journal of Solid State Chemistry},

year = {2015},

volume = {225},

publisher = {Elsevier},

month = {may},

url = {https://doi.org/10.1016/j.jssc.2014.12.001},

pages = {97--104},

doi = {10.1016/j.jssc.2014.12.001}

}

Publisher

Elsevier

Journal

Journal of Solid State Chemistry

scimago Q2

wos Q1

SJR

0.629

CiteScore

6.8

Impact factor

3.5

ISSN

00224596 (Print)

1095726X (Electronic)

Profiles